Abstract: The modeling and simulation of all vanadium redox flow battery（VRB）is the foundation for design, scale-up, control and optimization. According to the complexity of the VRB models, progresses of empirical and semi-empirical models are introduced. The developing theoretical models are analyzed.  Compared with the advantages and the disadvantages of each model, it indicates that future modeling and simulation research should focus on building much more exact and authentic model and incorporating in the control system for practical applications. Meanwhile, the VRB models should also develop from single cell to stack, module and system.

Key words: all vanadium redox flow battery, modeling, simulation, model

摘要： 全钒液流电池(VRB)的模拟和仿真是电池系统设计、放大、控制和优化的基础。根据VRB模型的复杂程度，本文详细介绍了VRB经验和半经验模型的研究内容，重点分析了近年来发展迅速的机理模型研究，对比分析了每个模型的优缺点，指出了VRB模拟和仿真未来的研究方向主要是建立接近真实的模型以及与实际运行控制系统联合，同时模拟仿真的实体也应从单电池向电堆、模块和电池系统发展。

关键词: 全钒液流电池, 模拟, 仿真, 模型