Abstract: On the basis of vapor pressures, volumes of saturated vapor and liquid, both parameters "a" and "b" in Soave equation of state are treated as temperature dependent and an extended Soave equation is proposed in this work. The VLE for 38 pure components including polar substances have been calculated. The comparison of calculated results with experimental data shows the prediction of liquid density is improved over Soave equation without losing the accuracy of prediction in vapor pressure and vapor density.

Key words: equation of state, liquid density, vapor-liquid equilibrium

摘要： On the basis of vapor pressures, volumes of saturated vapor and liquid, both parameters "a" and "b" in Soave equation of state are treated as temperature dependent and an extended Soave equation is proposed in this work. The VLE for 38 pure components including polar substances have been calculated. The comparison of calculated results with experimental data shows the prediction of liquid density is improved over Soave equation without losing the accuracy of prediction in vapor pressure and vapor density.

关键词: equation of state;liquid density;vapor-liquid equilibrium