Abstract: A new theory of electrolyte solutions is presented. The nonideal behaviors of electrolyte solutions are interpreted from the energy effects of the particle interactions and the entropy effects of the microstructures of the solutions. A new primitive model of electrolyte solutions is developed. The model containing the contribution of the entropy effect gets significant improvement in the prediction of the nonideal behaviors of various electrolyte solutions.

摘要： 提出一个新的电解质溶液理论,从粒子相互作用的能量效应和溶液微观结构的熵效应两个方面解释电解质溶液的非理想性行为,并建立一个新的电解质溶液原始模型。新模型考虑了溶液微观结构的熵效应,显著提高了对各种电解质溶液的非理想性行为的预测。