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MASS TRANSFER CHARACTERISTICS OF INTERFACIAL LAYER MECHANICALLY ACTIVATED IN LIQUID-LIQUID SYSTEM

Zhang Dongxiang,Xue Rongshu and Tan Shiyu (Department of Chemical Engineering, Chongqing University, Chongqing 400044)Tarasov V V (D.Mendeleyev University of Chemical Technology of Russia,Moscow 125190)   

  • Online:2000-02-25 Published:2000-02-25

周期性机械激励液液体系相界面层的传质特性

张东翔,薛荣书,谭世语,Tarasov VV   

  1. 重庆大学化学工程系!重庆400044,重庆大学化学工程系!重庆400044,重庆大学化学工程系!重庆400044,俄罗斯门捷列夫化工大学!莫斯科125190

Abstract: The response of differential coefficient of mass transfer and differential rate of mass transfer in dynamic interface layers to the controlled mechanical interface activation has been investigated for inorganic acid (salt) liquid liquid extracting (reverse extracting) systems in the modified Lewis cell It can be seen from the results that periodic mechanical activation in interface layers not only affects the diffused penetrability in phase interfaces, enhances the process of mass transfer between phases, and improve the conditions of mass transfer in phases of liquid liquid systems, but also reduces the error of experiments The formation and development of differential polyphase layers determine the momentum and mass transfer characteristics in phases The result that the activation in phase interfaces is helpful for the formation of Marangoni spontaneous surface convection and other experimental phenomena in literatures are interpreted by using the idea of differential polyphase layers

摘要: 在改装的恒界面池中采用微分传质系数研究了无机酸和金属盐液液萃取 (反萃 )体系动态相界面的传质速度对可控界面机械激励的响应 .作用于液液体系相界面区域的机械激励不仅显著影响相间区域的扩散渗透性 ,而且明显稳定了液液体系相间区域的传质条件 ,减小了实验误差 .微多相层的形成和发展决定相间动量与物质的传输特性 .用微多相层的概念解释了对相界面区域的激励有助于引发Marangoni表面对流及其他实验现象 .

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