Ni-mediated Liquid Phase Reduction of Carbonyl Compounds in the Presence of Atmospheric Hydrogen

Abstract

Key words: reduction, nickel oxide, benzaldehyde, recyclable catalyst

摘要： An efficient reduction system of benzaldehyde with hydrogen under ambient pressure was developed using facile NiO catalyst. The non-aromatic solvents such as cyclohexane, tetrahydrofuran (THF) and n-hexane, and the addi-tive with strong basicity e.g. KOH, were necessary for smooth conversion of the substrate. That the catalyst can be recov-ered and reused for nine times without loss of catalytic activity indicates that this catalyst is a recyclable one for benzal-dehyde reduction.

关键词: reduction;nickel oxide;benzaldehyde;recyclable catalyst

JIHongbing(纪红兵),HUANGYueying(黄月英),QIANYu(钱宇),WANGTingting(王婷婷)andZHANGMeiying(张美英). Ni-mediated Liquid Phase Reduction of Carbonyl Compounds in the Presence of Atmospheric Hydrogen[J]. .

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