Influence of inorganic salts on sodium dodecyl benzene sulfonate microemulsion system

doi:10.3969/j.issn.0438-1157.2014.10.036

CIESC Journal ›› 2014, Vol. 65 ›› Issue (10): 4025-4031.DOI: 10.3969/j.issn.0438-1157.2014.10.036

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Influence of inorganic salts on sodium dodecyl benzene sulfonate microemulsion system

YUAN Ying¹, LIU Hui'e¹, XU Mingming², DING Chuanqin¹, CHEN Shuang¹, QI Xuanliang¹

1 State Key Laboratory of Heavy Oil Processing, China University of Petroleum (East China), Qingdao 266580, Shandong, China;
2 Sinopec Shengli Oil Field Technology Inspection Center, Dongying 257000, Shandong, China

Received:2014-03-17 Revised:2014-05-06 Online:2014-10-05 Published:2014-10-05
Supported by:
supported by the National Natural Science Foundation of China(21106187), the Promotive Research Funds for Excellent Young and Middle-aged Scientists of Shandong Province (BS2011NJ021) and the Fundamental Research Funds for the Central Universities (11CX05016A).

十二烷基苯磺酸钠微乳液体系中无机盐的作用规律

袁迎¹, 刘会娥¹, 徐明明², 丁传芹¹, 陈爽¹, 齐选良¹

1 中国石油大学重质油国家重点实验室, 山东青岛 266580;
2 中国石化胜利油田技术检测中心, 山东东营 257000

通讯作者: 刘会娥
基金资助:
国家自然科学基金青年基金项目（21106187）；山东省优秀中青年科学家奖励基金项目（BS2011NJ021）；中央高校基本科研业务费专项资金（11CX05016A）。

Abstract

Abstract: The influence of inorganic salts on sodium dodecyl benzene sulfonate (SDBS)/butanol/octane/water microemulsion system was investigated by changing the type of salts. Increasing cationic charge concentration of various salts in an anionic surfactant microemulsion system promoted changes in the microemulsion phase behavior from lower phase (Winsor Ⅰ) microemulsion through middle phase (Winsor Ⅲ) toward upper phase (Winsor Ⅱ) microemulsion. While for different inorganic salts, optimum salinities were different. Six groups of salt mixture systems were investigated. There was a linear relationship between efficiency parameter of salt mixtures and their composition, in other words, the influence of salt mixtures could be predicted by studying efficiency parameter of single inorganic salts. By using efficiency parameter as the medium, the relationship between optimum salinity of single salts and their mixtures was deduced, and could be used to predict the influence of salt mixtures. The prediction results coincided well with the experimental results.

Key words: microemulsion, phase behavior, optimum salinities, salt mixtures, efficiency parameter, prediction

摘要： 通过改变无机盐的种类，研究无机盐及其混合盐对十二烷基苯磺酸钠（SDBS）/正丁醇/正辛烷/水微乳液体系的影响。微乳体系随着各种盐类浓度的增加，均发生WinsorⅠ Winsor Ⅲ Winsor Ⅱ的相变，但对不同的无机盐其最佳盐度不同。通过对6组混合无机盐体系的研究，表明混合无机盐的效率参数与混合盐组成之间存在线性关系，可以用单一无机盐的效率参数预测出混合盐的情况。以效率参数为桥梁推导出了单一无机盐与混合无机盐之间最佳盐度的关系式，可用于预测混合盐效应，发现预测结果与实验结果吻合良好。

关键词: 微乳液, 相变, 最佳盐度, 混合无机盐, 效率参数, 预测

CLC Number:

O648

YUAN Ying, LIU Hui'e, XU Mingming, DING Chuanqin, CHEN Shuang, QI Xuanliang. Influence of inorganic salts on sodium dodecyl benzene sulfonate microemulsion system[J]. CIESC Journal, 2014, 65(10): 4025-4031.

袁迎, 刘会娥, 徐明明, 丁传芹, 陈爽, 齐选良. 十二烷基苯磺酸钠微乳液体系中无机盐的作用规律[J]. 化工学报, 2014, 65(10): 4025-4031.

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Influence of inorganic salts on sodium dodecyl benzene sulfonate microemulsion system

十二烷基苯磺酸钠微乳液体系中无机盐的作用规律

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