CIESC Journal ›› 2019, Vol. 70 ›› Issue (7): 2786-2794.DOI: 10.11949/0438-1157.20190060
• Material science and engineering, nanotechnology • Previous Articles Next Articles
Xiaolin ZHU1(),Cunying XU1,2(),Jie TANG1,Yixin HUA1,2,Qibo ZHANG1,2,Hai LIU1,Xiang WANG1,Mengting HUANG1
Received:
2019-01-21
Revised:
2019-04-28
Online:
2019-07-05
Published:
2019-07-05
Contact:
Cunying XU
朱啸林1(),徐存英1,2(),唐杰1,华一新1,2,张启波1,2,刘海1,王祥1,黄梦婷1
通讯作者:
徐存英
作者简介:
朱啸林(1990—),男,硕士研究生,<email>zhuxiaolinzxl@163.com</email>
基金资助:
CLC Number:
Xiaolin ZHU, Cunying XU, Jie TANG, Yixin HUA, Qibo ZHANG, Hai LIU, Xiang WANG, Mengting HUANG. Effects of existence form and concentrations of NiCl2•6H2O and CrCl3•6H2O on conductivity of ChCl-EG deep eutectic solvent[J]. CIESC Journal, 2019, 70(7): 2786-2794.
朱啸林, 徐存英, 唐杰, 华一新, 张启波, 刘海, 王祥, 黄梦婷. 氯化铬和氯化镍浓度及其存在形式对ChCl-EG低共熔溶剂电导率的影响[J]. 化工学报, 2019, 70(7): 2786-2794.
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Fig.1 ESI-MS spectra of ChCl-EG DES (a) and ChCl-EG-NiCl2·6H2O-CrCl3·6H2O DES in negative ion mode(b),and ESI-MS spectra of ChCl-EG-NiCl2·6H2O-CrCl3·6H2O DES (c) in positive ion mode
Fig.6 Electrical conductivity of ChCl-EG-NiCl2·6H2O-CrCl3·6H2O DES as function of total metal ion concentration at different temperature(a), (b) is linear fitting of data shown in (a)
ctotal/(mmol/L) | Eκ/(kJ/mol) |
---|---|
0 | 10.91 |
100 | 11.26 |
200 | 12.16 |
300 | 12.38 |
400 | 12.74 |
500 | 13.60 |
Table 1 Relationship between conductance activation energy and total metal ion concentration of ChCl-EG-NiCl2·6H2O-CrCl3·6H2O DES
ctotal/(mmol/L) | Eκ/(kJ/mol) |
---|---|
0 | 10.91 |
100 | 11.26 |
200 | 12.16 |
300 | 12.38 |
400 | 12.74 |
500 | 13.60 |
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