Measurement of vapor-liquid equilibrium for R32+R1234yf+R1234ze(E)

doi:10.11949/0438-1157.20211314

Abstract

Abstract:

In this work, the vapor-liquid equilibrium data of two binary mixtures R32+R1234yf and R1234yf+R1234ze(E), and ternary mixture R32+R1234yf+R1234ze(E) were experimentally studied by using a liquid-recirculating analytical apparatus at temperatures from 263.15 K to 323.15 K. A set of temperature independent parameters was correlated for three binary mixtures with the PRSV+WS+NRTL model. The average absolute relative deviation(AARD) of pressure between experimental data and calculated results for R32+R1234yf and R1234yf+R1234ze(E) were 0.71% and 0.20%, respectively. The average absolute deviation(AAD) of vapor-phase mole fractions were both around 0.0016. This model was also employed to predict the ternary VLE properties. The AARD of pressure for R32+R1234yf+R1234ze(E) was 0.82%. The AAD of vapor-phase mole fractions of the system components R32 and R1234yf were both about 0.007.

Key words: mixed refrigerants, vapor liquid equilibrium, experimental measurement, correlation

摘要：

基于液相循环法搭建的气液相平衡实验装置，在263.15~323.15 K温度范围内，实验测量了R32+R1234yf和R1234yf+R1234ze（E）二元混合物以及R32+R1234yf+R1234ze（E）三元混合物的气液相平衡数据，利用PRSV状态方程结合WS混合法则和NRTL活度系数模型进行关联拟合，获得二元混合工质的交互参数，并在其基础上预测了三元混合工质气液相平衡性质。计算结果与实验数据对比表明，二元体系R32+R1234yf和R1234yf+R1234ze（E）的压力平均绝对偏差分别为0.71%和0.20%，气相摩尔分数平均绝对偏差均约为0.0016，三元体系R32+R1234yf+R1234ze（E）的压力平均绝对偏差为0.82%，系统组分R32和R1234yf的气相摩尔分数平均绝对偏差均约为0.007。

关键词: 混合制冷剂, 气液相平衡, 实验测量, 方程拟合

CLC Number:

TK 121

Yukun SUN, Tao YANG, Jiangtao WU. Measurement of vapor-liquid equilibrium for R32+R1234yf+R1234ze(E)[J]. CIESC Journal, 2022, 73(3): 1063-1071.

孙裕坤, 杨焘, 吴江涛. R32+R1234yf+R1234ze（E）混合制冷剂气液相平衡实验研究[J]. 化工学报, 2022, 73(3): 1063-1071.

Figures/Tables 1

References 33

1	Tsai W T. Environmental risks of new-generation fluorocarbons in replacement of potent greenhouse gases[J]. International Journal of Global Warming, 2013, 5(1): 84-95.
2	Abas N, Kalair A R, Khan N, et al. Natural and synthetic refrigerants, global warming: a review[J]. Renewable and Sustainable Energy Reviews, 2018, 90: 557-569.
3	王亚东, 于志浩, Eric Y, 等. 第五章制冷剂产品市场分析[J]. 制冷技术, 2017, 37(S1):36-49.
	Wang Y D, Yu Z H, Eric Y, et al. Refrigerants market analysis[J]. Chinese Journal of Refrigeration Technology, 2017, 37(S1): 36-49.
4	高恩元, 韩美顺. 2020年度中国制冷剂产品市场分析[J]. 制冷技术, 2021, 41(S1): 51-59.
	Gao E Y, Han M S. Analysis on refrigerant products market of China in 2020[J]. Chinese Journal of Refrigeration Technology, 2021, 41(S1): 51-59.
5	邹冠星, 苏阳. 第5章制冷剂产品市场分析[J]. 制冷技术,2018, 38(S1): 36-47.
	Zou G X, Su Y. Market analysis of the refrigerant products[J]. Chinese Journal of Refrigeration Technology, 2018, 38(S1): 36-47.
6	Hodnebrog Ø, Etminan M, Fuglestvedt J S, et al. Global warming potentials and radiative efficiencies of halocarbons and related compounds: a comprehensive review[J]. Reviews of Geophysics, 2013, 51(2): 300-378.
7	孟照峰, 张华, 秦延斌, 等. R1234yf/R134a混合物在汽车空调中替代R134a的实验研究[J]. 化工学报, 2018, 69(6): 2396-2403.
	Meng Z F, Zhang H, Qin Y B, et al. Experimental study on R1234yf/R134a mixture as alternative to R134a in automobile air conditioner[J]. CIESC Journal, 2018, 69(6): 2396-2403.
8	张青, 胡云鹏, 陈焕新, 等. 制冷剂R1234yf替代R22的理论分析和试验研究[J]. 制冷与空调, 2015, 15(1): 54-57.
	Zhang Q, Hu Y P, Chen H X, et al. Theoretical analysis and experiment study on substitution of refrigerant R1234yf for R22[J]. Refrigeration and Air-conditioning, 2015, 15(1): 54-57.
9	Mota-Babiloni A, Navarro-Esbrí J, Barragán-Cervera Á, et al. Commercial refrigeration—an overview of current status[J]. International Journal of Refrigeration, 2015, 57: 186-196.
10	杨申音, 王勤, 唐黎明, 等. 常规空调热泵系统的R32替代研究述评[J]. 制冷学报, 2013, 34(6): 59-68.
	Yang S Y, Wang Q, Tang L M, et al. Review of the application of R32 on air conditioners and heat pump systems[J]. Journal of Refrigeration, 2013, 34(6): 59-68.
11	韩晓红, 徐英杰, 仇宇, 等. 制冷剂R32的循环性能实验研究[J]. 制冷与空调, 2010, 10(2): 68-70, 83.
	Han X H, Xu Y J, Qiu Y, et al. Experimental study on the cycle performance of refrigerant R32[J]. Refrigeration and Air-conditioning, 2010, 10(2): 68-70, 83.
12	Kamiaka T, Dang C, Hihara E. Vapor-liquid equilibrium measurements for binary mixtures of R1234yf with R32, R125, and R134a[J]. International Journal of Refrigeration, 2013, 36(3): 965-971.
13	Koyama S, Takada N, Matsuo Y, et al. Possibility to introduce HFO-1234ze(E) and its mixture with HFC-32 as low-GWP alternatives for heat pump/refrigeration systems[C]//2010 International Symposium on Next-Generation Air Conditioning and Refrigeration Technology. Tokyo, Japan, 2010.
14	Madani H, Valtz A, Zhang F, et al. Isothermal vapor-liquid equilibrium data for the trifluoromethane (R23)+2,3,3,3-tetrafluoroprop-1-ene (R1234yf) system at temperatures from 254 to 348 K[J]. Fluid Phase Equilibria, 2016, 415: 158-165.
15	Juntarachat N, Valtz A, Coquelet C, et al. Experimental measurements and correlation of vapor-liquid equilibrium and critical data for the CO₂ + R1234yf and CO₂ + R1234ze(E) binary mixtures[J]. International Journal of Refrigeration, 2014, 47:141-152.
16	Liu Y, Valtz A, El Abbadi J, et al. Isothermal vapor-liquid equilibrium measurements for the (R1234ze(E) + ethane) system at temperatures from 272.27 to 347.52 K[J]. Journal of Chemical & Engineering Data, 2018, 63(11): 4185-4192.
17	Dong X Q, Guo H, Gong M Q, et al. Measurements of isothermal (vapour+liquid) equilibria data for {1,1,2,2-tetrafluoroethane (R134)+trans-1,3,3,3-tetrafluoropropene (R1234ze(E))} at T = (258.150 to 288.150) K[J]. The Journal of Chemical Thermodynamics, 2013, 60: 25-28.
18	Yang Z, Gong M Q, Guo H, et al. Phase equilibrium for the binary mixture of {1,1-difluoroethane (R152a)+trans-1,3,3,3-tetrafluoropropene (R1234ze (E))} at various temperatures from 258.150 to 288.150 K[J]. Fluid Phase Equilibria, 2013, 355: 99-103.
19	Zhong Q, Dong X Q, Zhao Y X, et al. Measurements of isothermal vapour-liquid equilibrium for the 2,3,3,3-tetrafluoroprop-1-ene + propane system at temperatures from 253.150 to 293.150 K[J]. International Journal of Refrigeration, 2017, 81: 26-32.
20	Chen L X, Hu P, Zhu W B, et al. Vapor-liquid equilibria of fluoroethane (HFC-161)+2,3,3,3-tetrafluoroprop-1-ene (HFO-1234yf)[J]. Fluid Phase Equilibria, 2015, 392: 19-23.
21	Hu P, Zhu W B, Chen L X, et al. Vapor-liquid equilibria measurements of 1,1,1,2-tetrafluoroethane (HFC-134a)+2,3,3,3-tetrafluoroprop-1-ene (HFO-1234yf)+isobutane (HC-600a) ternary system[J]. Fluid Phase Equilibria, 2016, 414: 111-116.
22	Han X H, Gao Z J, Lei J, et al. Isothermal vapor-liquid equilibrium of the ternary mixture of 1,1,1,2-tetrafluoroethane + 2,3,3,3-tetrafluoroprop-1-ene + dimethyl ether at temperatures from 253.15 K to 323.15 K[J]. Journal of Chemical & Engineering Data, 2015, 60(8): 2219-2225.
23	Hu X Z, Yang T, Meng X Y, et al. Vapor liquid equilibrium measurements for difluoromethane (R32)+2,3,3,3-tetrafluoroprop-1-ene (R1234yf) and fluoroethane (R161)+2,3,3,3-tetrafluoroprop-1-ene (R1234yf)[J]. Fluid Phase Equilibria, 2017, 438: 10-17.
24	Hu X Z, Yang T, Meng X Y, et al. Isothermal vapor liquid equilibrium measurements for difluoromethane (R32) + fluoroethane (R161) + trans-1,3,3,3-tetrafluoropropene (R1234ze(E)) ternary mixtures[J]. International Journal of Refrigeration, 2017, 79: 49-56.
25	Yang T, Hu X Z, Meng X Y, et al. Vapor–liquid equilibria for the binary and ternary systems of difluoromethane (R32), 1,1-difluoroethane (R152a), and 2,3,3,3-tetrafluoroprop-1-ene (R1234yf)[J]. Journal of Chemical & Engineering Data, 2018, 63(3): 771-780.
26	Yang T, Hu X Z, Meng X Y, et al. Vapour-liquid equilibria for the binary systems of pentafluoroethane {(R125) + 2,3,3,3-tetrafluoroprop-1-ene (R1234yf)} and {trans-1,3,3,3-tetrafluoropropene R1234ze(E)}[J]. The Journal of Chemical Thermodynamics, 2020, 150: 106222.
27	杨焘, 胡晓振, 孟现阳, 等. 三元混合制冷剂R32+R161+R1234yf气液相平衡实验研究[J]. 制冷学报, 2018, 39(6): 17-23.
	Yang T, Hu X Z, Meng X Y, et al. Measurement of vapor liquid equilibrium for difluoromethane (R32)+fluoroethane (R161) + 2,3,3,3-tetrafluoroprop-1-ene (R1234yf)[J]. Journal of Refrigeration, 2018, 39(6): 17-23.
28	Lemmon E W, Bell I H, Huber M L, et al. NIST reference fluid thermodynamic and transport properties database (Refprop V 10.0), Standard Reference Data Program[DB]. National Institute of Standards and Technology. 2018.
29	Yang T, Siepmann J I, Wu J T. Phase equilibria of difluoromethane (R32), 1, 1, 1, 2-tetrafluoroethane (R134a), and trans-1, 3, 3, 3-tetrafluoro-1-propene (R1234ze(E)) probed by experimental measurements and Monte Carlo simulations[J]. Industrial & Engineering Chemistry Research, 2021, 60(1): 739-752.
30	Stryjek R, Vera J H. PRSV: an improved Peng-Robinson equation of state for pure compounds and mixtures[J]. The Canadian Journal of Chemical Engineering, 1986, 64(2): 323-333.
31	Wong D S H, Sandler S I. A theoretically correct mixing rule for cubic equations of state[J]. AIChE Journal, 1992, 38(5): 671-680.
32	Renon H, Prausnitz J M. Local compositions in thermodynamic excess functions for liquid mixtures[J]. AIChE Journal, 1968, 14(1): 135-144.
33	Ye G R, Fang Y B, Guo Z K, et al. Experimental investigation of vapor-liquid equilibrium for 2,3,3,3-tetrafluoropropene (HFO-1234yf) + trans-1,3,3,3-tetrafluoropropene (HFO-1234ze(E)) at temperatures from 284 to 334 K[J]. Journal of Chemical & Engineering Data, 2021, 66(4): 1741-1753.

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