SYNTHESIS OF CYANOANILINE DERIVATIVES AND INVESTIGATION OF SHG ACTIVITY

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SYNTHESIS OF CYANOANILINE DERIVATIVES AND INVESTIGATION OF SHG ACTIVITY

Chen Xing;Zhao Xiaoming;Cheng Lubai（Department of Fine Chemicals,Da1ian University of Technology,Dalian 116012）

Online:1996-08-25 Published:1996-08-25

对氰基苯胺衍生物的合成及SHG效应

陈兴,赵晓明,程侣柏

大连理工大学化工学院精细化工系!大连116012,大连理工大学化工学院精细化工系!大连116012,大连理工大学化工学院精细化工系!大连116012

Abstract

Abstract: Eighteen cyanoaniline derivatives were synthesized and there were 13 compounds having a chiral atom in them.The optical rotation and absorption curves were measured and it was found that the compounds having a chiral atom showed optical activity and the maximum absorption wavelengths of 18 synthesized compounds were between 400 and 415nm.Second harmonic generation(SHG)of synthesized compounds were measured by the powder method and it was found that 8 samples were revealed to possess SHU activity.The influence of the molecular structure on SHG was examined by X-ray crystal analysis.

摘要： 合成了18个对氰基苯胺衍生物，其中13个化合物含有手性原子.测试了它们的旋光度和吸收光谱，含手性原子的化合物均有旋光值，合成产品的最高吸收波长在400～415nm之间．采用固体粉末方法测试了合成化合物的SHG效应，其中8个品种具有SHG活性.经X光衍射分析，探讨了影响SHG效应的有关因素.

CLC Number:

O625

Chen Xing;Zhao Xiaoming;Cheng Lubai（Department of Fine Chemicals,Da1ian University of Technology,Dalian 116012）. SYNTHESIS OF CYANOANILINE DERIVATIVES AND INVESTIGATION OF SHG ACTIVITY[J]. .

陈兴,赵晓明,程侣柏. 对氰基苯胺衍生物的合成及SHG效应 [J]. CIESC Journal.

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