激光诱导荧光技术在液体混合可视化研究中的应用

doi:10.3969/j.issn.0438-1157.2013.03.001

化工学报 ›› 2013, Vol. 64 ›› Issue (3): 771-778.DOI: 10.3969/j.issn.0438-1157.2013.03.001

• 综述与专论 • 下一篇

激光诱导荧光技术在液体混合可视化研究中的应用

王文坦, 张梦雪, 赵述芳, 刘喆, 金涌, 程易

清华大学化学工程系,北京100084

收稿日期:2012-05-17 修回日期:2012-07-09 出版日期:2013-03-05 发布日期:2013-03-05
通讯作者: 程易
作者简介:王文坦(1986—),男,博士研究生。
基金资助:
国家自然科学基金项目(20776074);高等学校博士学科点专项科研基金项目(20090002110069)。

Application of laser-induced fluorescence technique in visualization of liquid mixing process

WANG Wentan, ZHANG Mengxue, ZHAO Shufang, LIU Zhe, JIN Yong, CHENG Yi

Department of Chemical Engineering, Tsinghua University, Beijing 100084, China

Received:2012-05-17 Revised:2012-07-09 Online:2013-03-05 Published:2013-03-05
Supported by:
supported by the National Natural Science Foundation of China(20776074)and the Specialized Research Fund for the Doctoral Program of Higher Education(20090002110069).

摘要/Abstract

摘要： 在研究混合过程的多种实验方法中,定量的可视化测量技术不仅可同时显示流场中各位置混合效果的差异,还可直观地反映混合过程随时间的变化规律。其中,激光诱导荧光技术具有测量精度高、无干扰流场、实现方式简单等优势,是用于检测化工过程流动-混合行为的先进测试技术。对该技术的测试原理、实现方式进行了详细的介绍,探讨该技术在可视化液体混合过程以及反应流混合过程的研究进展。

关键词: 液液混合, 反应流混合, 可视化技术, 激光诱导荧光, 无干扰流场

Abstract: Among a variety of experimental methods to study the liquid-liquid mixing process,quantitative visualization techniques can display the mixing effects at different locations in the flow field simultaneously,as well as the evolution of the mixing process with time.The laser-induced fluorescence technique,a non-intrusive,highly accurate,easy-to-implement quantitative visualization technique,is widely used to study liquid-liquid mixing behavior in the chemical processes.This review introduces the principles and implementation methods of laser-induced fluorescence technique and discusses the progress of its applications in the investigation of both non-reactive and reactive mixing behavior.The outlook of some potential areas of this technique is also presented.

Key words: liquid-liquid mixing, reactive mixing, visualization technique, laser-induced fluorescence, non-intrusive technique

中图分类号:

TQ016.5

王文坦, 张梦雪, 赵述芳, 刘喆, 金涌, 程易. 激光诱导荧光技术在液体混合可视化研究中的应用[J]. 化工学报, 2013, 64(3): 771-778.

WANG Wentan, ZHANG Mengxue, ZHAO Shufang, LIU Zhe, JIN Yong, CHENG Yi. Application of laser-induced fluorescence technique in visualization of liquid mixing process[J]. CIESC Journal, 2013, 64(3): 771-778.

参考文献 38

[1]	Reynolds O.An experimental investigation of the circumstances which determine whether the motion of water in parallel channels shall be direct or sinuous and of the law of resistance in parallel channels[J].Philos. Trans. R.Soc.,1883,174:935-982
[2]	Liu Zhe(刘喆).Experimental study and numerical simulation of liquid-liquid mixing intensification in mini-/micro-scale reactors.Beijing:Tsinghua University,2010
[3]	Crimaldi J P.Planar laser induced fluorescence in aqueous flows[J].Exp.Fluids,2008,44:851-863
[4]	Law A W K,Wang H W.Measurement of mixing processes with combined digital particle image velocimetry and planar laser induced fluorescence[J].Exp.Therm.Fluid Sci.,2000,22:213-229
[5]	Karasso P S,Mungal M G.PLIF measurements in aqueous flows using the Nd:YAG laser[J].Exp.Fluids,1997,23:382-387
[6]	Arcoumanis C,McGuirk J J,Palma J.On the use of fluorescent dyes for concentration measurements in water flows[J].Exp.Fluids,1990,10:177-180
[7]	Walker D.A fluorescence technique for measurement of concentration in mixing liquids[J].J. Phys. E. Sci.Instrum.,1987,20:217-224
[8]	Crimaldi J P.The effect of photobleaching and velocity fluctuations on single-point LIF measurements[J].Exp. Fluids,1997,23:325-330
[9]	Larsen L G,Crimaldi J P.The effect of photobleaching on PLIF[J].Exp.Fluids,2006,41:803-812
[10]	Arbeloa I L,Rohatgi-Mukherjee K K.Solvent effect on photophysics of the molecular forms of Rhodamine B solvation models and spectroscopic parameters[J].Chem. Phys. Lett.,1986,128:474-479
[11]	Schaefer F P.Dye Lasers[M].Berlin:Springer,1973
[12]	Distelhoff M F W,Marquis A J,Nouri J M,Whitelaw J H.Scalar mixing measurements in batch operated stirred tanks[J].Canadian Journal of Chemical Engineering,1997,75:641-652
[13]	Guillard F,Trägardh C,Fuchs L.A study on the instability of coherent mixing structures in a continuously stirred tank[J].Chem.Eng.Sci.,2000,55:5657-5670
[14]	Fall A,Lecoq O,David R.Characterization of mixing in a stirred tank by planar laser induced fluorescence(P.L.I.F.)[J].Chem.Eng.Res.& Des.,2001,79:876-882
[15]	Hall J F,Barigou M,Simmons M J H,Stitt E H.Mixing in unbaffled high-throughput experimentation reactors[J].Ind.Eng.Chem.Res.,2004,43:4149-4158
[16]	Kling K,Mewes D.Two-colour laser induced fluorescence for the quantification of micro- and macromixing in stirred vessels[J].Chem.Eng.Sci.,2004,59:1523-1528
[17]	Hu Yinyu(胡银玉),Liu Zhe(刘喆),Yang Jichu(杨基础),Cheng Yi(程易).Liquid mixing in eccentric stirred tank[J].CIESC Journal(化工学报),2010,61:2517-2522
[18]	Luo P C,Cheng Y,Zhao Y Z,Jin Y,Yang W H. Millisecond mixing of two liquid streams in a mixer model[J].Chem.Eng.Sci.,2007,62 :5688-5695
[19]	Luo Peicheng(骆培成),Cheng Yi(程易),Wang Zhanwen(汪展文),Jin Yong(金涌),Yang Wanhong(杨万宏).Study of fast liquid-liquid micromixing using PLIF technique[J].Journal of Chemical Industry and Engineering(China)(化工学报),2005,56:2288-2293
[20]	Liu Z,Cheng Y,Jin Y.Fast liquid jet mixing in millimeter channels with various multislits designs[J].Ind. Eng. Chem.Res.,2008,47:9744-9753
[21]	Liu Z,Huang Y B,Jin Y,Cheng Y.Mixing intensification by chaotic advection inside droplets for controlled nanoparticle preparation[J].Microfluid Nanofluid,2010,9:773-786
[22]	Mühlfriedel K,Baumann K H.Concentration measurements during mass transfer across liquid-phase boundaries using planar laser induced fluorescence(PLIF)[J].Exp.Fluids,2000,28:279-281
[23]	Dani A,Guiraud P,Cockx A.Local measurement of oxygen transfer around a single bubble by planar laser-induced fluorescence[J].Chem.Eng.Sci.,2007,62:7245-7252
[24]	Stroock A D,Dertinger S K W,Ajdari A,Mezic I,Stone H A,Whitesides G M.Chaotic mixer for microchannels[J].Science,2002,295:647-651
[25]	Stroock A D,Dertinger S K,Whitesides G M,Ajdari A. Patterning flows using grooved surfaces[J].Anal. Chem.,2002,74:5306-5312
[26]	Wong S H,Ward M C L,Wharton C W.Micro T-mixer as a rapid mixing micromixer[J].Sensors Actuators B,2004,100:359-379
[27]	Hoffmann M,Schlüter M,Rbiger N.Experimental investigation of liquid-liquid mixing in T-shaped micro-mixers using μ-LIF and μ-PIV[J].Chem.Eng.Sci.,2006,61:2968-2976
[28]	Wang W T,Zhao S F,Shao T,Jin Y,Cheng Y. Visualization of micro-scale mixing in miscible liquids using μ-LIF technique and drug nano-particle preparation in T-shaped micro-channels[J].Chem.Eng.J.,2012,192:251-262
[29]	Ito Y,Komori S.A vibration technique for promoting liquid mixing and reaction in a microchannel[J].AIChE J.,2006,52:3011-3017
[30]	Shinohara K,Sugii Y,Okamoto K,Madarame H,Hibara A,Tokeshi M,Kitamori T.Measurement of pH field of chemically reacting flow in microfluidic devices by laser-induced fluorescence[J].Meas.Sci.Technol.,2004,15:955-960
[31]	Hu Y Y,Liu Z,Yang J C,Jin Y,Cheng Y.Study on the reactive mixing process in an unbaffled stirred tank using planar laser-induced fluorescence(PLIF)technique[J].Chem.Eng.Sci.,2010,65:4511-4518
[32]	Hu Y Y,Wang W T,Shao T,Yang J C,Cheng Y. Visualization of reactive and non-reactive mixing processes in a stirred tank using planar laser induced fluorescence(PLIF)technique[J].Chem.Eng.Res.& Des.,2012,90:524-533
[33]	Liu Z,Cheng Y,Jin Y.Experimental study of reactive mixing in a mini-scale mixer by laser-induced fluorescence technique[J].Chem.Eng.J.,2009,150:536-543
[34]	Shao Ting(邵婷),Hu Yinyu(胡银玉),Wang Wentan(王文坦),Jin Yong(金涌),Cheng Yi(程易).Visualization of gas-liquid mass transfer and reaction using laser induced fluorescence(LIF)technique[J].CIESC Journal(化工学报),2011,62:2422-2426
[35]	Shao T,Feng X L,Wang W T,Jin Y,Cheng Y. Visualization of gas-liquid mass transfer and reaction within droplets using a novel reactive-PLIF technique and PIV[J].Chem.Eng.J.,2012,200/201/202:549-558
[36]	Deusch S,Dracos T.Time resolved 3D passive scalar concentration-field imaging by laser induced fluorescence(LIF)in moving liquids[J].Meas.Sci.Technol.,2001,12:188-200
[37]	Tian X D,Roberts P J W.A 3D LIF system for turbulent buoyant jet flows[J].Exp.Fluids,2003,35:636-647
[38]	van Vliet E,van Bergen S M,Derksen J J,Portela L M,van den Akker HEA.Time-resolved,3D,laser-induced fluorescence measurements of fine-structure passive scalar mixing in a tubular reactor[J].Exp.Fluids,2004,37:1-21

激光诱导荧光技术在液体混合可视化研究中的应用

Application of laser-induced fluorescence technique in visualization of liquid mixing process

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献 38

相关文章 15

编辑推荐

Metrics

本文评价

[1]	王芳,贾胜坤,张会书,袁希钢,余国琮. 基于实验数据的湍流扩散POD模态分析[J]. 化工学报, 2021, 72(9): 4531-4543.
[2]	刘洁妤, 龚岩, 吴晓翔, 郭庆华, 于广锁, 王辅臣. 多喷嘴对置式气化炉内颗粒挥发分火焰可视化研究[J]. 化工学报, 2021, 72(3): 1275-1282.
[3]	张航,张巍,李伟锋,刘海峰,王辅臣. T型反应器内流动、混合及界面反应特征[J]. 化工学报, 2021, 72(10): 5064-5073.
[4]	杨锋苓, 张翠勋, 李美婷. 柔性Rushton搅拌桨混合性能的实验研究[J]. 化工学报, 2020, 71(2): 626-632.
[5]	程晨, 薛志村, 郭庆华, 龚岩, 于广锁. 撞击气流床气化炉内雾化过程中颗粒运动特性[J]. 化工学报, 2019, 70(12): 4536-4545.
[6]	傅强, 张会书, 胡楠, 袁希钢, 余国琮. 水溶解CO₂过程界面对流现象的PIV/LIF测量及传质系数预测[J]. 化工学报, 2018, 69(2): 586-594.
[7]	刘海龙, 曹宇, 丁学翀, 毛宝东, 王悦柔, 王军锋. 搅拌槽内液相层流荧光可视化及高效混合技术[J]. 化工学报, 2018, 69(12): 5042-5048.
[8]	胡楠, 张会书, 傅强, 李陆星, 袁希钢. 气相第2组分对水溶解CO₂过程界面对流影响的LIF观测[J]. 化工学报, 2017, 68(2): 584-593.
[9]	李陆星, 胡楠, 袁希钢. 水吸收CO₂过程界面对流的激光诱导荧光观测[J]. 化工学报, 2016, 67(10): 4055-4063.
[10]	杜柯江, 李伟锋, 单志昊, 刘海峰, 王辅臣. 小型受限撞击流反应器内混合特征及激励强化[J]. 化工学报, 2015, 66(7): 2395-2401.
[11]	张建伟, 马红越, 董鑫, 冯颖. 水平对置双向液体撞击流的振荡特性[J]. 化工学报, 2015, 66(4): 1310-1317.
[12]	张会书, 袁希钢, Kalbassi Mohammad Ali. 激光诱导荧光技术测量规整填料内的液体分布[J]. 化工学报, 2014, 65(9): 3331-3339.
[13]	张会书, 袁希钢, Kalbassi Mohammad Ali. 激光诱导荧光技术测量规整填料内的液体分布[J]. 化工学报, 2014, 65(9): 0-0.
[14]	骆培成, 吴俊, 辛传贤, 贾海燕. 多孔错流喷射混合器内液体射流轨迹线[J]. 化工学报, 2014, 65(7): 2733-2740.
[15]	赵述芳, 王文坦, 胡银玉, 邵婷, 金涌, 程易. 搅拌釜内液-液混合溶析沉淀法制备纳米姜黄素颗粒[J]. 化工学报, 2013, 64(3): 841-848.