集成模糊安全评价的反应路径综合

doi:10.3969/j.issn.0438-1157.2013.12.032

化工学报 ›› 2013, Vol. 64 ›› Issue (12): 4484-4490.DOI: 10.3969/j.issn.0438-1157.2013.12.032

集成模糊安全评价的反应路径综合

项曙光, 焦巍, 孙晓岩, 夏力

青岛科技大学炼油化工高新技术研究所, 山东青岛 266042

收稿日期:2013-06-26 修回日期:2013-07-02 出版日期:2013-12-05 发布日期:2013-12-05
通讯作者: 项曙光
作者简介:项曙光（1963- ），男，教授。
基金资助:
山东省自然科学基金项目（ZR2011BL011）。

Reaction path synthesis integrated fuzzy safety evaluation

XIANG Shuguang, JIAO Wei, SUN Xiaoyan, XIA Li

The Hi-Tech Institute for Petroleum and Chemical Industry, Qingdao University of Science and Technology, Qingdao 266042, Shandong, China

Received:2013-06-26 Revised:2013-07-02 Online:2013-12-05 Published:2013-12-05
Supported by:
supported by the Natural Science Foundation of Shandong Province (ZR2011BL011).

摘要/Abstract

摘要： 为在过程早期获取本质安全性较好的反应路径，将模糊安全评价集成于反应路径综合形成有效方法。根据反应路径综合阶段信息选择指标，通过设定指标的隶属度函数，建立模糊推理系统，且应用层次分析法（analytic hierarchy process，AHP）求得指标的权重因子，形成了模糊评价方法。为消除中间变量的影响，分别建立单、双输入变量的模糊推理系统。将它集成于反应路径综合，通过原料筛选规则，模糊安全评价，建立以安全为目标的优化模型，求解得到优良的反应路径组合。应用于萘甲胺反应路径综合实例，定量得到了反应路径及其目标函数值，并对两种模糊系统的综合结果进行了比较。

关键词: 反应路径综合, 模糊评价, 本质安全, AHP

Abstract: Aimed to obtain inherently safer chemical reaction path during early phase of chemical process,fuzzy safety assessment is integrated to reaction path synthesis to provide effective method.Indices are selected based on process information in the reaction path synthesis phase.Through setting membership function of each index,establishing fuzzy inference system,and determining the weighting vector by AHP,the fuzzy assessment method is proposed.To eliminate the impact of medium variable,the fuzzy inference system of single input variable and double input variables are provided respectively.Integrating the method to reaction path synthesis,the benign reaction path will be obtained through material screening rules,fuzzy safety assessment,and optimization treating safety as objective function.By analyzing the application of reaction path synthesis for carbaryl production,reaction paths with their objective function value is obtained.The results for two kinds of fuzzy system are compared finally.

Key words: reaction path synthesis, fuzzy assessment, inherent safety, AHP

中图分类号:

X937

项曙光, 焦巍, 孙晓岩, 夏力. 集成模糊安全评价的反应路径综合[J]. 化工学报, 2013, 64(12): 4484-4490.

XIANG Shuguang, JIAO Wei, SUN Xiaoyan, XIA Li. Reaction path synthesis integrated fuzzy safety evaluation[J]. CIESC Journal, 2013, 64(12): 4484-4490.

参考文献 21

[1]	Alexandre C D, Costin S B. Chemical Process Design:Computer-Aided Case Studies[M].Weinheim:WILEY-VCH Verlag GmbH & Co.KGaA, 2008
[2]	Scott D B, Jeffrey J S. Process synthesis prospective[J]. Computers and Chemical Engineering, 2004, 28:441-446
[3]	Cernot G, Michael N. Sustainable processes—the challenge of the 21st century for chemical engineering[J].Process Safety and Environment Protection, 2008, 86:321-327
[4]	Klatt K U, Marquardt W.Perspectives for process systems engineering—personal views from academia and industry[J].Computers & Chemical Engineering, 2009, 33:536-550
[5]	Al-Mutairi E M. An optimization approach to the integration of inherently-safer design and process scheduling[J].Journal of Loss Prevention in the Process Industries, 2008, 21 (5):543-549
[6]	Crabtree E M, EI-Halwagi M M. Synthesis of environmentally acceptable reactions[J].AIChE Symposium Series, 1994, 90 (303):117-127
[7]	Rotstein E Resasco D, Stephanopoulos G.Studies on the synthesis of chemical reaction paths (Ⅰ):Reaction characteristics in the (ΔG, T) space and a primitive synthesis procedure[J].Chemical Engineering Science, 1982, 37 (9):1337-1352
[8]	Fornari T, Rotstein E, Stephanopoulos G.Studies on the synthesis of chemical reaction paths (Ⅱ):Reaction schemes with two degrees of freedom[J].Chemical Engineering Science, 1989, 44 (7):1569-1579
[9]	Fornari T, Stephanopoulos G.Synthesis of chemical reaction paths:the scope of group contribution methods[J].Chemical Engineering Communications, 1994, 129:135-137
[10]	Fornari T, Stephanopoulos G.Synthesis of chemical reaction paths:economic and specification constraints[J].Chemical Engineering Communications, 1994b, 129:159-182
[11]	Stefanis S K, Buxton A, Livingston A G, Pistikopoulos E N.A methodology for environmental impact minimization:solvent design and reaction path synthesis issues[J].Computers & Chemical Engineering, 1996, 20:1419-1424
[12]	Buxton A, Livingston A G, Pistikopoulos E N.Reaction path synthesis for environmental impact minimization[J].Computers & Chemical Engineering, 1997, 21:959-964
[13]	Hu Shanying (胡山鹰), Li Mingheng (李明恒), Li Yourun (李有润), Shen Jingzhu (沈静珠).Simple stoichiometric reaction[J].The Chinese Journal of Process Engineering (过程工程学报), 2004, 4 (6):544-548
[14]	Heikkil A M, Hurme M, Jrvelinen M. Safety considerations in process synthesis[J].Computers & Chemical Engineering, 1996, 20:115-120
[15]	Heikkila A M.Inherent safety in process plant design.An index-based approach[D].Espoo, Finland:Helsinki University of Technology, 1999
[16]	Koller G, Fischer U, Hungerbuhler K.Comparison of methods suitable for assessing the hazard potential of chemical processes during early design phases[J].IChemE, 2001, 79:157-166
[17]	Gentile M, Rogers W J, Mannan M S. Development of a fuzzy logic-based inherent safety index[J].IChemE, 2003, 81:444-456
[18]	Palaniappan C, Srinivasan R, Tan R.Selection of inherently safer process routes:a case study[J].Chemical Engineering and Processing, 2004, 43:647-653
[19]	Khan F I, Amyotte P R.I2SI:a comprehensive quantitative tool for inherent safety and cost evaluation[J].Journal of Loss Prevention in the Process Industries, 2005, 18:310-326
[20]	Srinivasan R, Nhan N T. A statistical approach for evaluating inherent benignness of chemical process routes in early design stages[J]. Process Safety and Environment Protection, 2008, 86:163-174
[21]	Chan T L, Shariff A M.Process route index (PRI) to assess level of explosiveness for inherent safety quantification[J].Journal of Loss Prevention in the Process Industries, 2009, 22:216-221

集成模糊安全评价的反应路径综合

Reaction path synthesis integrated fuzzy safety evaluation

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