CIESC Journal

• 化工学报 •    下一篇

表面活性剂液膜萃取过程的乳液溶胀(Ⅰ)——载体对乳液溶胀的影响

王子镐,傅举孚   

  1. 北京化工大学化学工程系!北京100029,北京化工大学化学工程系!北京100029
  • 出版日期:1995-06-25 发布日期:1995-06-25

EMULSION SWELLING OF LIQUID SURFACTANT MEMBRANE EXTRACTION PROCESS (Ⅰ) EFFECTS OF CARRIERS ON EMULSION SWELLING

Wang Zihao and Fu Jufu(Department of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029)   

  • Online:1995-06-25 Published:1995-06-25

摘要: 研究了载体对乳液溶胀的影响。发现膜相中存在载体时使界面张力降低,说明载体能吸附于界面。表面活性剂和载体在界面的竞争吸附是影响乳液溶胀的关键因素。本研究表明,液膜的夹带溶胀随膜相中载体浓度的增大而减小,而渗透溶胀则随之而加剧。提出了估算溶胀率的修正方程,用修正方程对膜相存在载体时的乳液夹带溶胀率进行了估算,计算值与实验数据吻合良好。

Abstract: The effects of carriers on emulsion swelling were studied. The interfacial tension between the membrane phase and the external aqueous phase was measured. The existence of carrier in the membrane phase decreased the interfacial tension. This phenomenon shows that carrier is adsorbed on the interface. The adsorption behavior and a monomolecular film of surfactant and carrier are vital in emulsion swelling. The results indicate that water entrainment is lowered as carrier concentration increases and an increase in carrier concentration increases the rate of water permeation through the liquid membrane Two modified models for estimating entrainment swelling and permeation swelling are proposed, which give excellent fit to the experimental data.

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