生物油淀粉胶黏剂固化特性研究

doi:10.11949/j.issn.0438-1157.20180529

化工学报 ›› 2018, Vol. 69 ›› Issue (12): 5309-5315.DOI: 10.11949/j.issn.0438-1157.20180529

• 材料化学工程与纳米技术 • 上一篇下一篇

生物油淀粉胶黏剂固化特性研究

张继宗^1,2, 常厚春², 常建民³, 龙金星¹, 李雪辉¹

1. 华南理工大学化学与化工学院, 制浆造纸国家重点实验室, 广东广州 510641;
2. 广州迪森热能技术股份有限公司, 广东广州 510530;
3. 北京林业大学材料科学与技术学院, 北京 100083

收稿日期:2018-05-22 修回日期:2018-08-10 出版日期:2018-12-05 发布日期:2018-12-05
通讯作者: 李雪辉
基金资助:
国家自然科学基金项目（21336002，21736003，21690083）；广东省自然科学基金项目（2015A030311048）；广州市科技计划（201804020014）。

Curing characteristics of bio-oil starch adhesive

ZHANG Jizong^1,2, CHANG Houchun², CHANG Jianmin³, LONG Jinxing¹, LI Xuehui¹

1. School of Chemistry and Chemical Engineering, State Key Laboratory of Pulp & Paper Engineering, South China University of Technology, Guangzhou 510641, Guangdong, China;
2. Guangzhou Devotion Thermal Technology Co., Ltd., Guangzhou 510530, Guangdong, China;
3. College of Material Science and Technology, Beijing Forestry University, Beijing 100083, China

Received:2018-05-22 Revised:2018-08-10 Online:2018-12-05 Published:2018-12-05
Supported by:
supported by the National Natural Science Foundation of China (21336002, 21736003, 21690083), the Natural Science Foundation of Guangdong Province (2015A030311048) and the Science and Technology Program of Guangzhou (201804020014).

摘要/Abstract

摘要：

生物基胶黏剂具有环境友好、可再生等特性，具有广阔的应用前景。对生物油淀粉胶黏剂进行差热分析，研究了其固化过程中的热行为、固化反应动力学和固化工艺，为高效地优化、预测和控制其胶接工艺条件提供基础数据支撑；对比采用复合固化剂与单一固化剂的胶黏剂热行为，发现复合固化反应热更大，固化特征温度更低，表明复合固化剂体系固化更充分；不同生物油加入量对胶黏剂的热行为研究表明，随生物油加入量增加，固化反应放热量增加，但固化特征温度逐渐降低，进一步表明生物油有促进胶黏剂固化的作用。

关键词: 生物油, 生物基胶黏剂, 固化特性, 固化动力学

Abstract:

Bio-based adhesives have environmentally friendly, recyclable properties and have broad application prospects. Hence, the thermal behavior, curing kinetics and curing technology of bio-oil starch adhesive were studied by Differential Thermal Analysis (DTA) to provide the data foundation for efficient optimization, forecast and control of bonding technology. Compare to the thermal behavior of single curing agent, that of bio-oil starch adhesive by the composite curing agent had greater heat of curing reaction and lower curing temperature, which indicated that the curing effect of the composite curing agent was better than the single curing agent. With the increase of bio-oil dosage, the curing temperature of bio-oil starch adhesive became lower and the heat of curing reaction became larger, illustrating that bio-oil played a positive role in the curing of starch adhesive.

Key words: bio-oil, bio-based adhesive, curing characteristics, curing kinetics

中图分类号:

TQ028.8

张继宗, 常厚春, 常建民, 龙金星, 李雪辉. 生物油淀粉胶黏剂固化特性研究[J]. 化工学报, 2018, 69(12): 5309-5315.

ZHANG Jizong, CHANG Houchun, CHANG Jianmin, LONG Jinxing, LI Xuehui. Curing characteristics of bio-oil starch adhesive[J]. CIESC Journal, 2018, 69(12): 5309-5315.

参考文献 32

[1]	李清. 全球胶粘剂行业发展现状及研究进展[J]. 中国胶黏剂, 2017,(6):46-50. LI Q. Development status and research progress of global adhesive industry[J]. China Adhesives, 2017,(6):46-50.
[2]	李韵谱, 吴亚西, 徐东群, 等. 室内甲醛污染状况分析[J]. 环境化学, 2005, 24(2):137-139. LI Y P, WU Y X, XU D Q, et al. Analysis of indoor formaldehyde pollution[J]. Environ. Chem., 2005, 24(2):137-139.
[3]	王新, 丁钟. 汽车车室内VOC探讨及胶粘剂解决对策[J]. 化工新型材料, 2013, 41(2):157-159. WANG X, DING Z. Discussion of VOC in the car cabin and adhesive solutions[J]. New Chem. Mater., 2013, 41(2):157-159.
[4]	FEDORUK M J, KERGER B D. Measurement of volatile organic compounds inside automobiles[J]. Journal of Exposure Analysis & Environmental Epidemiology, 2003, 13(1):31.
[5]	GRABBS J S, CORSI R L, TORRES V M, et al. Volatile organic compounds in new automobiles:screening assessment[J]. Journal of Environmental Engineering, 2015, 126(10):974-977.
[6]	翁云宣. 2016生物基材料专刊序言[J]. 生物工程学报, 2016, 32(6):711-714. WENG Y X. Preface for special issue on bio-based materials(2016)[J]. Chin. J. Biotech., 2016, 32(6):711-714.
[7]	方向晨. 生物基化学品及其竞争力分析[J]. 石油化工, 2013, 42(10):1069-1074. FANG X C. Bio-based chemicals and analysis of their competitive edge in chemical industry[J]. Petrochem. Techno., 2013, 42(10):1069-1074.
[8]	FUJITA A, MYAZAKI H, MATSUDA S, et al. Adhesive properties of wood-biomass based epoxy resins[J]. Journal of Adhesion, 2005, 42(8):323-328.
[9]	CUI Y, HOU X, WANG W, et al. Synthesis and characterization of bio-oil phenol formaldehyde resin used to fabricate phenolic based materials[J]. Materials, 2017, 10(6):668.
[10]	张继宗, 张琪, 常建民.生物油淀粉胶黏剂制备工艺研究[J]. 现代化工, 2013, 33(6):62-65. ZHANG J Z, ZHANG Q, CHANG J M. Preparation process of bio-oil starch adhesive[J]. Mod. Chem. Ind., 2013, 33(6):62-65.
[11]	顾继友. 胶黏剂与涂料[M]. 2版. 北京:中国林业出版社, 2012. GU J Y. Adhesives and Coatings[M]. 2nd ed. Beijing:China Forestry Publishing House, 2012.
[12]	范东斌. 尿素、生物油-苯酚-甲醛共缩聚树脂的合成、结构与性能研究[D]. 北京:北京林业大学, 2009. FAN D B. Synthesis, structure, and properties of urea-or biomass oil-phenol-formaldehyde cocondensed resins[D]. Beijing:Beijing Forestry University, 2009.
[13]	POPOVI? M, DJIPOROVI?MOM?ILOVI? M, ŠERNEK M, et al. The influence of wood extracts on the curing kinetics of urea-formaldehyde adhesive studied by iso-conversional method[J]. Pro. Ligno., 2013, 94:153-163.
[14]	李常雄, 戴亚堂, 胡小平, 等. 非等温DSC法研究TiB2/环氧树脂E-44体系固化动力学[J]. 热固性树脂, 2011, 26(3):6-10. LI C X, DAI Y T, HU X P, et al. Curing kinetics of TiB2/epoxyresin E-44 system studied by nor-isothermal DSC[J]. Thermosetting Resin, 2011, 26(3):6-10.
[15]	ZHANG Y, NANDA M, TYMCHYSHYN M, et al. Mechanical, thermal, and curing characteristics of renewable phenol-hydroxymethylfurfural resin for application in bio-composites[J]. J. Mater. Sci., 2016, 51(2):732-738.
[16]	WANG M C, WEI L H, ZHAO T. Cure study of addition-cure-type and condensation-addition-type phenolic resins[J]. Eur. Polym. J., 2005, 41(5):903-912.
[17]	齐亚龙, 徐婷, 张清华. 光热双重固化胶黏剂的热固反应动力学研究[J]. 热固性树脂, 2016, (5):5-9. QI Y L, XU T, ZHANG Q H. Study on thermal curing kinetics of UV and heat dual curing adhesive[J]. Thermosetting Resin, 2016,(5):5-9.
[18]	牛海霞, 周涛, 张爱民, 等. 耐热芴型环氧树脂的非等温固化动力学[J]. 功能高分子学报, 2007, 19(4):358. NIU H X, ZHOU T, ZHANG A M, et al. Non-isothermal curing kinetics of thermal resistance epoxy resin containing fluorene[J]. J. Funct. Polym., 2007, 19(4):358.
[19]	HARSCH M, KARGER-KOCSIS J, HOLST M. Influence of fillers and additives on the cure kinetics of an epoxy/anhydride resin[J]. Eur. Polym. J., 2007, 43(4):1168-1178.
[20]	SUPRIYA N, CATHERINE K B, RAJEEV R. DSC-TG studies on kinetics of curing and thermal decomposition of epoxy-ether amine systems[J]. J. Therm. Anal. Calorim., 2013, 112(1):201-208.
[21]	BERNARD S, WEINMANN M, CORNU D, et al. Preparation of high-temperature stable Si, B, C, N fibers from tailored single source polyborosilazanes[J]. J. Eur. Ceram. Soc., 2005, 25(2):251-256.
[22]	LI L, ZOU H W, LIANG M. Study on the effect of poly(oxypropylene)diamine modified organic montmorillonite on curing kinetics of epoxy nanocomposties[J]. Thermochim Acta, 2014, 59(7):93-100.
[23]	DOMÍNGUEZ J C, GRIVEL J C, MADSEN B. Study on the non-isothermal curing kinetics of a polyfurfuryl alcohol bioresin by DSC using different amounts of catalyst[J]. Thermochim Acta, 2012, 529(3):29-35.
[24]	PARK B D, RIEDL B, BAE H J, et al. Differential scanning calorimetry of phenol-formaldehyde(PF) adhesives[J]. J. Wood Chem. Techn., 1999, 19(3):265-286.
[25]	LEI Y, WU Q, LIAN K. Cure kinetics of aqueous phenol-formaldehyde resins used for oriented strandboard manufacturing:analytical technique[J]. J. Appl. Polym. Sci., 2006, 100(2):1642-1650.
[26]	GABILONDO N, LÓPEZ M, RAMOS J A, et al. Curing kinetics of amine and sodium hydroxide catalyzed phenol-formaldehyde resins[J]. J. Therm. Anal. Calor., 2007, 90(1):229-236.
[27]	李伟东, 张金栋, 刘刚, 等. 高韧性双马来酰亚胺树脂的固化反应动力学和TTT图[J]. 复合材料学报, 2016, 33(7):1475-1483. LI W D, ZHANG J D, LIU G, et al. Curing reaction kinetics and TTT diagram of high toughness bismaleimide resin[J]. Acta Mater. Compos. Sin., 2016, 33(7):1475-1483.
[28]	SOUROUR S, KAMAL M R. Differential scanning calorimetry of epoxy cure:isothermal cure kinetics[J]. Thermochim Acta, 1976, 14(1):41-59.
[29]	黄超, 葛震, 赵本波, 等. DMP-30对环氧/马来酸酐固化行为的影响[J]. 高校化学工程学报, 2017, 31(1):197-204. HUANG C, GE Z, ZHAO B B, et al. Effects of DMP-30 on curing behavior of epoxy resin/maleicanhydride systems[J]. J. Chem. Eng. Chin. Univ., 2017, 31(1):197-204.
[30]	ZHANG D, CHEN Y, JIA D. Toughness and reinforcement of diglycidyl ether of bisphenol-A by hyperbranched poly(trimellitic anhydride-butanediol glycol) ester epoxy resin[J]. Polym. Composite., 2010, 30(7):918-925.
[31]	FRANCIS B, THOMAS S, THOMAS S P. Diglycidyl ether of bisphenol-A epoxy resin-polyether sulfone/polyether sulfone ether ketone blends:phase morphology, fracture toughness and thermo-mechanical properties[J]. Colloid Polym. Sci., 2006, 285(1):83-93.
[32]	张竞, 李全步, 蒋英, 等. 非等温DSC法研究高韧性低收缩环氧体系固化动力学[J]. 高分子材料科学与工程, 2009, 25(6):99-102. ZHANG J, LI Q B, JIANG Y, et al. Nonisothermal cure kinetics of a high toughness and low volume shrinkage ratio epoxy system[J]. Polym. Mater. Sci. Eng., 2006, 285(1):83-93.

生物油淀粉胶黏剂固化特性研究

Curing characteristics of bio-oil starch adhesive

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