Abstract: Based upon the discussion of the diffusion and reaction processes in paper Ⅰ,including general analysis of crystal micro-structure ,substance phase and chemical contents of three kinds of phosphate ores of domestic mine(Jing He,Xiao Feng and Kai Yang),the reaction kinetics process involving phosphoric acid-phosphate ore particles was investigated in an experiment system.As a result,the new negative temperature effect of iron and alumium impurity reaction was discovered.Accompanying these special phenomena in fractal particles ,the self-ordering structrue arising in the diffusion process was demonstrated in the experiments by using scanning electron microscopy and X-ray diffraction analysis.Furthermore,the kinetic process was described by adopting the new model in paper(Ⅰ) ,and satisfactory results were obtained.