化工学报 ›› 2018, Vol. 69 ›› Issue (5): 2250-2254.DOI: 10.11949/j.issn.0438-1157.20171274

• 能源和环境工程 • 上一篇    下一篇

Fe(II)/H2O2体系氧化NO主要活性物质及自由基无效消耗路径

赵海谦1, 刘城昊1, 周伟2, 王忠华1, 齐晗兵1, 高继慧2   

  1. 1. 东北石油大学土木建筑工程学院, 黑龙江 大庆 163318;
    2. 哈尔滨工业大学能源科学与工程学院, 黑龙江 哈尔滨 150001
  • 收稿日期:2017-09-19 修回日期:2017-12-13 出版日期:2018-05-05 发布日期:2018-05-05
  • 通讯作者: 齐晗兵
  • 基金资助:

    国家自然科学基金项目(51606036,91434134);黑龙江省普通本科高等学校青年创新人才培养计划(UNPYSCT-2016085)。

Main active substances and useless consumption path of free radicals in Fe (Ⅱ)/H2O2 system during NO oxidation process

ZHAO Haiqian1, LIU Chenghao1, ZHOU Wei2, WANG Zhonghua1, QI Hanbing1, GAO Jihui2   

  1. 1. Institute of Civil Engineering & Architecture, Northeast Petroleum University, Daqing 163318, Heilongjiang, China;
    2. College of Energy Science and Engineering, Harbin Institute of Technology, Harbin 150001, Heilongjiang, China
  • Received:2017-09-19 Revised:2017-12-13 Online:2018-05-05 Published:2018-05-05
  • Supported by:

    supported by the National Natural Science Foundation of China(51606036, 91434134) and Innovative Talents Training Plan for Youth Scholars in Heilongjiang Province (UNPYSCT-2016085).

摘要:

H2O2利用率低是Fe (Ⅱ)/H2O2氧化体系应用的瓶颈,自由基无效消耗是H2O2利用率低的主要原因之一。本文以烟气中NO氧化为技术背景,实验研究了Fe (Ⅱ)/H2O2体系内H2O2及各种自由基在氧化NO中的作用及自由基无效消耗路径。结果表明:H2O2直接氧化NO能力很弱;虽然·OH及HO2·均可以氧化NO,但·OH的氧化作用大于HO2·。氧化NO同时,绝大多数·OH及HO2·通过两者的快速复合反应而无效消耗,严重影响了H2O2利用率。因此,使用Fe (Ⅱ)/H2O2体系降解污染物过程中,应尽量避免·OH及HO2·两种自由基同时大量存在。

关键词: Fe (Ⅱ)/H2O2体系, NO, 活性物质, 无效消耗, ·OH

Abstract:

Low utilization of H2O2 is a bottleneck in the application of Fe(Ⅱ)/H2O2 oxidation system. Free radicals useless consumption is one of the main reasons for the low utilization of H2O2. In this paper, the effect of H2O2 and various free radicals on oxidation of NO and the useless consumption pathways of the free radicals in Fe(Ⅱ)/H2O2 system were studied based on NO oxidation background. The results showed that the ability of directly oxidize NO by H2O2 was very weak. Although both ·OH and HO2· had the ability to oxidize NO, the oxidation ability of ·OH was greater than that of HO2·. In the process of NO oxidation, the vast majority of ·OH and HO2· was uselessly consumed through the rapid recombination of these two kinds of radicals, which seriously affected the utilization of H2O2. Therefore, simultaneous presence of both ·OH and HO2· radicals should be avoided when Fe(Ⅱ)/H2O2 system was adopted to degrade the pollutants.

Key words: Fe (Ⅱ)/H2O2 system, NO, active substance, useless consumption, ·OH

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