化工学报 ›› 2008, Vol. 59 ›› Issue (9): 2339-2345.

• 能源和环境工程 • 上一篇    下一篇

处理高浓度氨氮废水的阳离子交换树脂筛选

李红艳,李亚新,孙东刚   

  1. 太原理工大学环境科学与工程学院
  • 出版日期:2008-09-05 发布日期:2008-09-05

Screening of cation exchange resins for treating wastewater containing high concentration ammonia

LI Hongyan,LI Yaxin,SUN Donggang   

  • Online:2008-09-05 Published:2008-09-05

摘要:

目前树脂种类繁多,给处理高浓度氨氮废水的树脂选型带来困难。根据离子交换理论,利用001×7、D61和D001三种阳离子交换树脂,模拟研究了氮肥厂废水(氨氮浓度为915 mg·L-1)氨氮的吸附等温式,在30~50 min内三种树脂对氨氮的吸附基本可达到平衡,吸附等温线均符合Freundlich吸附模式;进而研究了这三种树脂对废水中氨氮吸附的选择性系数、工作交换容量和离子交换速率。结果表明,用D61树脂处理含高浓度氨氮的废水效果较为理想,可以相对较少的用量,使处理后水质达到相关排放标准的要求。

关键词:

氨氮废水, 离子交换树脂, 筛选, 吸附等温线

Abstract:

In order to overcome the difficulty in choosing the right type of resin from numerous resins available for treating wastewater containing high concentration ammonia,three cation exchange resins:001×7,D61 and D001 were studied based on ion exchange theory.The ammonia adsorption isotherms of the simulated wastewater(concentration of ammonia 915 mg·L-1)in a fertilizer plant were investigated.Ammonium ion uptake equilibrium on three resins was reached within 30—50 minutes,and all adsorption isotherms were in line with the Freundlich adsorption model.The selectivity factor,practical exchange capacity and ion exchange rate of ammonium ion uptake on these resins were also investigated.D61 resin was the best resin for treating wastewater containing high concentration ammonia.This resin could guarantee effluent water meeting the demand of water quality in《Discharge standard of water pollutants for ammonia industry》(GB 13458—2001)with less resin quantity.

Key words:

氨氮废水, 离子交换树脂, 筛选, 吸附等温线