化工学报 ›› 2011, Vol. 62 ›› Issue (6): 1688-1692.

• 能源和环境工程 • 上一篇    下一篇

低氧条件下生物反硝化过程中N2O的产量

巩有奎,王淑莹,彭永臻,王赛,王莎莎   

  1. 北京工业大学环境与能源工程学院
  • 出版日期:2011-06-05 发布日期:2011-06-05

  • Online:2011-06-05 Published:2011-06-05

摘要:

利用SBR反应器,控制曝气量为0.3 L·min-1,通过改变N2∶O2比例,调节反硝化过程中DO浓度,以连续投加乙醇作为反硝化碳源,考察了低氧条件下NO-3N反硝化过程及N2O的产量。结果表明,DO对反硝化菌的活性具有明显的抑制作用。DO由0增至0.7 mg·L-1,NO-3N还原速率由18.12 mg N·(g MLSS)-1·h-1降至11.37 mg N·( gMLSS)-1·h-1,系统N2O产量由0.23 mg·L-1增至1.74 mg·L-1。其原因为:(1)较高的NO-2N浓度导致系统反硝化速率降低,N2O积累并释放;(2)DO对N2O还原酶活性具有明显的抑制作用。降低缺氧-好氧生物脱氮过程中缺氧反应器内部DO含量,是减少生物脱氮过程中N2O产量的关键因素。

关键词: 生活污水, 溶解氧, N2O, 抑制作用

Abstract:

The effect of dissolved oxygen(DO)and ratio of N2 and O2 on N2O yield during biodenitritation process using nitrate solution as electron acceptor and ethanol as carbon source was investigated in a sequencing batch reactor by controlling gas rate at 0.3 L·min-1 and at low oxygen concentration.The results show that DO could decrease significantly activity of denitritation bacteria.The aeration rate falls off from 18.12 mg N·(g MLSS)-1·h-1to 11.37 mg N·(g MLSS)-1·h-1, while N2O yield increases from 0.23 mg·L-1 to 1.74 mg·L-1.The phenomena can be attributed to:(1)higher concentration of NO-3N leads to decrease of denitritation rate as well as accumulation and emission of N2O;(2)both synthesis and reducing N2O activity of enzymes cause inhibition of DO. A key factor for decreasing N2O emission during biodenitritation process is to lessen the content of DO in bioreactor.

Key words: 生活污水, 溶解氧, N2O, 抑制作用