醇提中药渣与废弃活性焦共燃特性及动力学分析

doi:10.11949/0438-1157.20201333

化工学报 ›› 2021, Vol. 72 ›› Issue (2): 1116-1124.DOI: 10.11949/0438-1157.20201333

醇提中药渣与废弃活性焦共燃特性及动力学分析

朱新宇^1,³(),张光义^2,³(),张建伟¹,温宏炎³,李运甲³,张建岭³,许光文^1,³

^1.沈阳化工大学机械与动力工程学院，辽宁沈阳 110142
^2.北京工商大学生态环境学院，北京 100048
^3.中国科学院过程工程研究所多相复杂系统国家重点实验室，北京 100190

收稿日期:2020-09-18 修回日期:2020-10-30 出版日期:2021-02-05 发布日期:2021-02-05
通讯作者: 张光义
作者简介:朱新宇（1995—），男，硕士研究生，742180655@qq.com
基金资助:
国家重点研发计划项目(2019YFC1906805)

Performances and kinetics analyses of co-combustion of alcohol extracted herb residue and wasted activated coke

ZHU Xinyu^1,³(),ZHANG Guangyi^2,³(),ZHANG Jianwei¹,WEN Hongyan³,LI Yunjia³,ZHANG Jianling³,XU Guangwen^1,³

^1.School of Mechanical and Power Engineering, Shenyang University of Chemical Technology, Shenyang 110142, Liaoning, China
^2.School of Ecological Environment, Beijing Technology and Business University, Beijing 100048, China
^3.State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China

Received:2020-09-18 Revised:2020-10-30 Online:2021-02-05 Published:2021-02-05
Contact: ZHANG Guangyi

摘要/Abstract

摘要：

采用热重分析法研究了不同升温速率下醇提中药渣、废弃活性焦及其不同比例混合物的燃烧特性，并利用Coats-Redfern方法计算其燃烧动力学参数。结果表明，醇提中药渣燃烧是挥发分和少量固定碳连续燃烧过程，而废弃活性焦燃烧主要是固定碳燃烧的过程；醇提中药渣比废弃活性焦具有更好的燃烧特性和更低的活化能。采用TG-MS联用分析仪对比研究醇提中药渣及其混合物的燃烧过程产生的烟气。结果表明，废弃活性焦的加入对醇提中药渣燃烧过程中产生的NO_x有明显的吸附还原作用。动力学分析表明，与废焦相比，混合物反应活化能随着中药渣比例的增加而变小，表明添加中药渣能提高废焦的反应活性，促进其燃烧。利用热重分析预测混合燃料的燃烧性质可靠，对醇提中药渣与废弃活性焦共燃处理的技术开发具有指导作用。

关键词: 醇提中药渣, 废弃活性焦, 热重分析, 燃烧特性, 动力学分析

Abstract:

The combustion characteristics of alcohol extracted herb residue, wasted activated cokes and their mixtures with different proportions at different heating rates were studied by thermogravimetric analysis, and the combustion kinetic parameters were calculated by The Coats-Redfern method. The results showed that the combustion of alcohol extracted herb residues was a continuous process of volatiles and a small amount of fixed carbon, while that of wasted activated cokes was mainly a process of fixed carbon combustion. The alcohol extracted herb residues had better combustion characteristics and lower average activation energy than wasted activated coke. TG-MS analyzer was used to compare the flue gases produced from the combustions of alcohol extracted herb residues and its mixture. The results show that the addition of waste activated coke has a significant adsorption and reduction effect on the NO_x produced during the combustion of alcohol-extracted herb residue. The kinetic analyses showed that the activation energy of the mixture of alcohol extracted herb residues and wasted activated cokes decreased with the increasing addition amount of alcohol extracted herb residues compared to pure wasted activated cokes, which improved the reaction activities of wasted activated cokes to boost their combustion. The use of thermogravimetric analysis to predict the combustion properties of mixed fuels is reliable, and has a guiding role in the development of technology for co-combustion treatment of alcohol-extracted herb residues and waste activated coke.

Key words: alcohol extracted herb residues, wasted activated coke, thermogravimetric analysis, combustion characteristics, kinetic analysis

中图分类号:

TK 6

朱新宇, 张光义, 张建伟, 温宏炎, 李运甲, 张建岭, 许光文. 醇提中药渣与废弃活性焦共燃特性及动力学分析[J]. 化工学报, 2021, 72(2): 1116-1124.

ZHU Xinyu, ZHANG Guangyi, ZHANG Jianwei, WEN Hongyan, LI Yunjia, ZHANG Jianling, XU Guangwen. Performances and kinetics analyses of co-combustion of alcohol extracted herb residue and wasted activated coke[J]. CIESC Journal, 2021, 72(2): 1116-1124.

图/表 9

参考文献 29

1	Jin Z Q, Hou Q W, Niu T Z. Effect of cultivating Pleurotus ostreatus on substrates supplemented with herb residues on yield characteristics, substrates degradation, and fruiting bodies' properties[J]. Journal of the Science of Food and Agriculture, 2020, 100(13): 4901-4910.
2	葛亚昕, 张光义, 崔丽杰, 等. 高含水菌渣流化床燃烧NO_x、SO₂排放特性[J]. 化工学报, 2017, 68(8): 3250-3257.
	Ge Y X, Zhang G Y, Cui L J, et al. Characteristics of NO_x and SO₂ emission from combustion of antibiotic mycelial residue with high water content in fluidized bed reactor[J]. CIESC Journal, 2017, 68(8): 3250-3257.
3	Li Y T, Lin B, Wang S, et al. Carbon consumption of activated coke in the thermal regeneration process for flue gas desulfurization and denitrification[J]. Journal of Cleaner Production, 2019, 228: 1391-1400.
4	于凤芹, 李运甲, 刘周恩, 等. 移动床活性焦烟气净化工艺中废活性焦的形成与特征分析[J]. 过程工程学报, 2020, 20(6): 695-702.
	Yu F Q, Li Y J, Liu Z E, et al. Formation and characteristics of used activated coke from flue gas purification process by activated coke in moving bed[J]. Journal of Process Engineering, 2020, 20(6): 695-702.
5	Li Y J, Zhang X L, Huang F L, et al. The simultaneous removal of SO₂ and NO from flue gas over activated coke in a multi-stage fluidized bed at low temperature[J]. Fuel, 2020, 275: 117862.
6	Chansa O, Luo Z Y, Yu C J. Study of the kinetic behaviour of biomass and coal during oxyfuel co-combustion[J]. Chinese Journal of Chemical Engineering, 2020, 28(7): 1796-1804.
7	温宏炎, 张玉明, 纪德馨, 等. 油泥焦与褐煤共燃特性及动力学[J]. 化工学报, 2020, 71(2): 755-765.
	Wen H Y, Zhang Y M, Ji D X, et al. Co-combustion of oil sludge char and brown coal: characteristics and kinetics[J]. CIESC Journal, 2020, 71(2): 755-765.
8	Kuznetsov G V, Syrodoy S V, Kostoreva A A, et al. Effect of concentration and relative position of wood and coal particles on the characteristics of the mixture ignition process[J]. Fuel, 2020, 274: 117843.
9	Yang J L, Chen H X, Zhao W T, et al. Combustion kinetics and emission characteristics of peat by using TG-FTIR technique[J]. Journal of Thermal Analysis and Calorimetry, 2016, 124(1): 519-528.
10	Xu T, Ning X J, Wang G W, et al. Combustion characteristics and kinetic analysis of co-combustion between bag dust and pulverized coal[J]. International Journal of Minerals Metallurgy and Materials, 2018, 25(12): 1412-1422.
11	Lu K M, Lee W J, Chen W H, et al. Thermogravimetric analysis and kinetics of co-pyrolysis of raw/torrefied wood and coal blends[J]. Applied Energy, 2013, 105: 57-65.
12	Gong Z, Wu W F, Zhao Z, et al. Combination of catalytic combustion and catalytic denitration on semi-coke with Fe₂O₃ and CeO₂[J]. Catalysis Today, 2018, 318: 59-65.
13	Chen Y, Mori S, Pan W. Studying the mechanisms of ignition of coal particles by TG-DTA[J]. Thermochimica Acta, 1996, 275: 149-158.
14	洪晨, 杨强, 王志强, 等. 抗生素菌渣与煤混合燃烧特性及其动力学分析[J]. 化工学报, 2017, 68(1): 360-368.
	Hong C, Yang Q, Wang Z Q, et al. Co-combustion characteristics and kinetic analysis of antibiotic bacterial residue and coal [J]. CIESC Journal, 2017, 68(1): 360-368.
15	辛善志, 黄芳, 刘晓烨, 等. 烘焙中药渣的热解与燃烧特性及其动力学分析[J]. 化工学报, 2019, 70(8): 3142-3150
	Xin S Z, Huang F, Liu X Y, et al. Pyrolysis and combustion characteristics and kinetics of torrefied traditional Chinese medicine waste [J]. CIESC Journal, 2019, 70(8): 3142-3150.
16	Álvarez A, Pizarro C, García R, et al. Determination of kinetic parameters for biomass combustion[J]. Bioresource Technology, 2016, 216: 36-43.
17	Gao W, Li J, Martí-Rossselló, et al. Experimental study on the ignition characteristics of cellulose, hemicellulose, lignin and their mixtures[J]. Journal of the Energy Institute, 2019, 92(5): 1303-1312.
18	夏紫薇, 郑刘根, 周春财, 等. 安徽临涣矿区烟煤与生活污泥共燃的燃烧特性与动力学特征[J]. 过程工程学报, 2020, DOI: 10.12034/j.issn.1009-606x.219375. DOI
	Xia Z W, Zheng L G, Zhou C C, et al. Combustion characteristics and kinetic characteristics of co-combustion of bituminous coal and domestic sludge in Linhuan Mining Area, Anhui [J]. Journal of Process Engineering, 2020, DOI: 10.12034/j.issn.1009-606x.219375. DOI
19	Huang L, Liu J, He Y, et al. Thermodynamics and kinetics parameters of co-combustion between sewage sludge and water hyacinth in CO₂/O₂ atmosphere as biomass to solid biofuel[J]. Bioresource Technology, 2016, 218: 631-642.
20	Coats A W, Redfern J P. Kinetic parameters from thermogravimetric data [J]. Nature, 1964, 201: 68-69.
21	Doyle C D. Estimating isothermal life from thermogravimetric data [J]. Journal of Applied Polymer Science, 1962, 6: 639-642.
22	Kissinger H E. Reaction kinetics in differential thermal analysis [J]. Analytical Chemistry, 1957, 29: 1702-1706.
23	Flynn J H, Wall L A. A quick, direct method for the determination of activation energy from thermogravimetric data[J]. Journal of Polymer Science Part B: Polymer Letters, 1966, 4: 323-328.
24	Miura K. A new and simple method to estimate f(E) and k₀(E) in the distributed activation-energy model from three sets of experimental-data[J]. Energy & Fuels, 1995, 9(2): 302-307.
25	Friedman H L. New methods for evaluating kinetic parameters from thermal analysis data[J]. Journal of Polymer Science Part B: Polymer Letters, 1969, 7: 41-46.
26	折媛, 巨建涛, 刘文果, 等. 长焰煤热解半焦气化反应动力学研究[J]. 冶金能源, 2019, 38(4): 20-24.
	She Y, Ju J T, Liu W G, et al. Study on gasification reaction kinetics of semi-coke derived from pyrolysis of long flame coal [J]. Metallurgical Energy, 2019, 38(4): 20-24.
27	刘亮, 邬海明, 陈明辉, 等. 脱脂餐厨垃圾燃烧特性及几种动力学模型结果比较[J]. 湖北大学学报(自然科学版), 2015, (2): 97-102.
	Liu L, Wu H M, Chen M H, et al. Combustion characteristics and comparison of several dynamic model results of degreased kitchen waste [J]. Journal of Hubei University(Natural Science), 2015, (2): 97-102.
28	马明硕, 朱琳, 徐利, 等. 农业废弃物葵花秆热解过程几种动力学模型结果比较[J]. 化学世界, 2015, (7): 385-388.
	Ma M S, Zhu L, Xu L, et al. Pyrolysis process of sunflower stem and its kinetic parameters with different methods [J]. Chemistry World, 2015, (7): 385-388.
29	周志杰, 范晓雷, 张薇, 等. 非等温热重分析研究煤焦气化动力学[J]. 煤炭学报, 2006, (2): 219-222.
	Zhou Z J, Fan X L, Zhang W, et al. Char gasification kinetics using non-isothermal TGA[J]. Journal of China Coal Society, 2006, (2): 219-222.

Sample	Proximate analysis/% (mass)				Ultimate analysis/% (mass)					HHVs/(MJ/kg)
Sample	Moisture	Ash	VM	FC	C	H	N	S	O	HHVs/(MJ/kg)
HR	4.7	14.2	68.5	12.6	40.6	5.1	3.4	1.5	35.1	15.9
WC	4.1	14.1	15.2	66.6	65.4	1.1	2.8	2.2	10.3	24.5

Sample	Proximate analysis/% (mass)				Ultimate analysis/% (mass)					HHVs/(MJ/kg)
Sample	Moisture	Ash	VM	FC	C	H	N	S	O	HHVs/(MJ/kg)
HR	4.7	14.2	68.5	12.6	40.6	5.1	3.4	1.5	35.1	15.9
WC	4.1	14.1	15.2	66.6	65.4	1.1	2.8	2.2	10.3	24.5

Sample	Component content/%
Sample	SO₃	K₂O	P₂O₅	CaO	MgO	SiO₂	Al₂O₃	Na₂O	Fe₂O₃
HR	29.0	28.8	15.8	14.8	6.1	2.0	1.1	0.9	0.6
WC	20.8	0.6	0.5	13.9	1.0	35.3	18.9	0.8	6.6

Sample	Component content/%
Sample	SO₃	K₂O	P₂O₅	CaO	MgO	SiO₂	Al₂O₃	Na₂O	Fe₂O₃
HR	29.0	28.8	15.8	14.8	6.1	2.0	1.1	0.9	0.6
WC	20.8	0.6	0.5	13.9	1.0	35.3	18.9	0.8	6.6

Sample	β/(℃/min)	T_i/℃	T_max/℃	T_h/℃	K_r×10⁵/(min/℃²)	C_b×10⁴/min^-1	S×10^-8/( min^-2·℃^-3)
HR	10	205	451	559	15.44	18.22	44.23
	20	208	293	586	17.50	34.59	89.98
	40	216	305	655	33.91	54.94	254.78
25WC75HR	10	302	462	568	4.32	24.55	11.77
	20	332	468	615	6.72	57.02	30.60
	40	221	302	688	30.05	95.07	216.06
50WC50HR	10	332	456	548	6.58	30.22	17.89
	20	340	460	606	7.77	58.53	36.64
	40	356	532	706	8.24	90.77	55.98
75WC25HR	10	380	460	612	5.39	21.91	12.52
	20	400	465	613	5.69	48.48	26.24
	40	412	540	739	6.45	76.86	40.46
WC	10	440	485	620	4.47	16.71	10.01
	20	448	500	630	5.03	30.11	21.94
	40	450	575	779	5.44	34.27	30.04

醇提中药渣与废弃活性焦共燃特性及动力学分析

Performances and kinetics analyses of co-combustion of alcohol extracted herb residue and wasted activated coke

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