化工学报 ›› 2020, Vol. 71 ›› Issue (5): 2320-2332.DOI: 10.11949/0438-1157.20191419

• 能源和环境工程 • 上一篇    下一篇

城市污泥/褐煤共水热碳化产物的热化学转化特性及规律研究

宋艳培1,3(),庄修政1,3,詹昊2,徐彬1,3,阴秀丽1(),吴创之1,3   

  1. 1.中国科学院广州能源研究所,中国科学院可再生能源重点实验室,广东省新能源和可再生能源重点实验室,广东 广州 510640
    2.中国科学院广州地球化学研究所,有机地球化学国家重点实验室,广东省环境保护与资源利用重点实验室,广东 广州 510640
    3.中国科学院大学,北京 100049
  • 收稿日期:2019-11-25 修回日期:2020-01-16 出版日期:2020-05-05 发布日期:2020-05-05
  • 通讯作者: 阴秀丽
  • 作者简介:宋艳培(1994—),女,硕士研究生,songyp@ms.giec.ac.cn
  • 基金资助:
    国家自然科学基金项目(51676195);广东省自然科学基金项目(2017B030308002);广州市科技计划项目(201904010098)

Investigation on thermochemical conversion characteristics and regularity of co-hydrothermal carbonization solid fuel from sewage sludge and lignite

Yanpei SONG1,3(),Xiuzheng ZHUANG1,3,Hao ZHAN2,Bin XU1,3,Xiuli YIN1(),Chuangzhi WU1,3   

  1. 1.Key Laboratory of Renewable Energy, CAS, Guangdong Key Laboratory of New and Renewable Energy Research and Development, Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, Guangdong, China
    2.State Key Laboratory of Organic Geochemistry, Guangdong Key Laboratory of Environmental Protection and Resource Utilization, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, Guangdong, China
    3.University of Chinese Academy of Sciences, Beijing 100049, China
  • Received:2019-11-25 Revised:2020-01-16 Online:2020-05-05 Published:2020-05-05
  • Contact: Xiuli YIN

摘要:

污泥和褐煤通过共水热碳化预处理以制备高品质固体燃料,为污泥和低阶煤的有效处理提供了一种可行方案。本研究主要考察了城市污泥(SS)和褐煤(LC)在不同温度下(120,180,240和300℃)进行共水热碳化制得的固相产物(水热炭)的热化学转化特性和规律,包括燃烧、热解和半焦CO2气化过程,并分析了这些过程中的协同作用。结果表明,共水热碳化预处理对城市污泥和褐煤的热利用行为有显著影响。一方面,共水热碳化处理后的水热炭相对其计算值具有更高的产率、煤化程度、热值等,同时具有更低的灰分含量。另一方面,混合物水热炭在燃烧、热解和半焦CO2气化过程均表现出一定的协同作用(促进燃烧和热解行为,降低气化活性),且水热温度在240℃附近时,这种作用最为明显。鉴于热解和气化过程的协同效果均低于燃烧过程,共水热碳化产物被认为更适合用于燃烧。这些发现表明,将共水热碳化改性提质处理与后续热化学工艺相结合,对于能源的产生和有机废弃物的利用都有一定的积极意义。

关键词: 城市污泥, 褐煤, 共水热碳化, 燃烧特性, 热解反应性, 半焦CO2气化, 协同作用

Abstract:

The sludge and lignite are pretreated by co-hydrothermal carbonization to prepare high-quality solid fuel, which provides a feasible solution for the effective treatment of sludge and low-rank coal. This study mainly investigated the thermochemical conversion characteristics and regularity of solid phase products (hydrochars) prepared by Co-HTC of sewage sludge (SS) and lignite (LC) at different temperatures (120, 180, 240 and 300℃). Experiments included combustion, pyrolysis and char CO2-gasification processes, and the synergistic effects in these processes were also analyzed. The results show that Co-HTC pretreatment has some significant effects on the thermal behavior of SS and LC. On the one hand, compared with the calculated value, the hydrochars after co-hydrothermal carbonization have higher yield, fuel rate, coalification degree, calorific value, etc., and they have lower ash content. On the other hand, all hydrochars have a certain synergistic effects in combustion, pyrolysis and char CO2-gasification (promoting combustion and pyrolysis behavior, reducing gasification activity), and when the hydrothermal temperature is around 240℃, these synergistic effects are most obvious. Given that the synergistic effects of the pyrolysis and gasification processes are lower than the combustion process, co-hydrothermal carbonization products are considered to be more suitable for combustion. These findings indicate that the combination of the upgrading of Co-HTC with subsequent thermochemical processes has positive implications for the generation of energy and the utilization of organic wastes.

Key words: sewage sludge, lignite, co-hydrothermal carbonization, combustion characteristics, pyrolysis reactivity, CO2-gasification, synergistic effect

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