十二烷基苯磺酸钠辅助尿素共沉淀制备超细铜铬黑颜料

doi:10.3969/j.issn.0438-1157.2013.05.047

化工学报 ›› 2013, Vol. 64 ›› Issue (5): 1847-1854.DOI: 10.3969/j.issn.0438-1157.2013.05.047

• 材料化学工程与纳米技术 • 上一篇下一篇

十二烷基苯磺酸钠辅助尿素共沉淀制备超细铜铬黑颜料

王伟文¹, 郑晓丹^1,2, 李平², 徐红彬², 张懿²

1. 青岛科技大学化工学院, 山东青岛 266061;
2. 中国科学院过程工程研究所绿色过程与工程重点实验室, 北京 100190

收稿日期:2012-10-10 修回日期:2012-11-16 出版日期:2013-05-05 发布日期:2013-05-05
通讯作者: 李平
作者简介:王伟文(1968-),女,副教授。
基金资助:
国家自然科学基金项目(51204154);国家高技术研究发展计划项目(2011AA060702)。

Synthesis of ultrafine copper chromite black pigment by chemical coprecipitation using SBDS-assisted urea

WANG Weiwen¹, ZHENG Xiaodan^1,2, LI Ping², XU Hongbin², ZHANG Yi²

1. School of Chemical Engineering, Qingdao University of Science&Technology, Qingdao 266061, Shandong, China;
2. Key Laboratory of Green Process, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China

Received:2012-10-10 Revised:2012-11-16 Online:2013-05-05 Published:2013-05-05
Supported by:
supported by the National Natural Science Foundation of China(51204154)and the High-tech Research and Development Program of China(2011AA060702).

摘要/Abstract

摘要： 以十二烷基苯磺酸钠为表面活性剂,采用尿素共沉淀法合成超细尖晶石型铜铬黑颜料。以铬和铜硝酸盐为原料,系统研究了沉淀剂、煅烧温度和表面活性剂等条件对铜铬黑颜料晶型、形貌和粒度的影响;并探讨了合成条件对铜铬黑颜料着色力的影响。研究表明,尿素和十二烷基苯磺酸钠可有效地控制形貌、颗粒大小及均匀性;在尿素用量为理论量4倍、表面活性剂添加量为5%、煅烧温度800℃的条件下制备出了形貌为六面体、平均粒径为300 nm、粒径分布均匀、着色力优异的超细铜铬黑颜料。

关键词: 化学共沉淀法, 尿素, 十二烷基苯磺酸钠, 铜铬黑, 粒径, 着色力

Abstract: The ultrafine copper chromite black pigment(CuCr₂O₄)with spinel structure was prepared from chromium and copper nitrates by the chemical coprecipitation method, using sodium dodecyl benzene sulfonate(SDBS)as surface active agent and urea as precipitation agent.The effect of processing parameters, such as precipitation agent, calcination temperature and surface active agent on crystal structure, grain size and morphology of the CuCr₂O₄ was investigated, and the effect of processing parameters on its tinting strength was discussed.The results showed that urea and SDBS could effectively control grain size, morphology and crystal structure of the pigment.Ultrafine CuCr₂O₄ 300 nm in size and with hexagonal structure was synthesized under the conditions of 400% theoretical amount of urea, 5% SDBS and 800℃ of calcination temperature, and exhibited excellent tinting strength compared with commercial samples.

Key words: chemical coprecipitation method, urea, sodium dodecyl benzene sulfonate(SDBS), copper chromite black, particle size, tinting strength

中图分类号:

TQ621.2

王伟文, 郑晓丹, 李平, 徐红彬, 张懿. 十二烷基苯磺酸钠辅助尿素共沉淀制备超细铜铬黑颜料[J]. 化工学报, 2013, 64(5): 1847-1854.

WANG Weiwen, ZHENG Xiaodan, LI Ping, XU Hongbin, ZHANG Yi. Synthesis of ultrafine copper chromite black pigment by chemical coprecipitation using SBDS-assisted urea[J]. CIESC Journal, 2013, 64(5): 1847-1854.

参考文献 21

[1]	Edwin B Faulkner, Russell J Schwartz.High Performance Pigments[M].2nd ed.Wiley Online Library,2009:49
[2]	Kawamoto A M, Pardini L C, Rezende L C.Synthesis of copper chromite catalyst[J].Aerospace Science and Technology, 2004, 8(7):591-598
[3]	George K, Sugunan S.Nickel substituted copper chromite spinels:preparation, characterization and catalytic activity in the oxidation reaction of ethylbenzene[J].Catalysis Communications, 2008, 9(13):2149-2153
[4]	Wang Qingcheng(王清成), Wang Xuemei(王雪梅), Zhuang Jia(庄稼).Synthesis for powder of nano-MgFe2O4/Fe2O3 by citrate sol-gel and absorbs characteristic of electromagnetic wave[J].Journal of Functional Materials(功能材料)2005, 36(12):1839-1841
[5]	Chemlal S, Larbot A, Persin M, Sarrazin J, Sghyar M, Rafiq M.Cobalt spinel CoAl2O4 via sol-gel process:elaboration and surface properties[J].Materials Research Bulletin, 2000, 35(14/15):2515-2523
[6]	Chen L, Horiuchi T, Mori T, Maeda K.Postsynthesis hydrothermal restructuring of M41S mesoporous molecular sieves in water[J].The Journal of Physical Chemistry B, 1999, 103(8):1216-1222
[7]	Ma Weishuai(马伟帅).Preparation and application research of solid propellant with functional composite particle.Nanjing:Nanjing University of Science and Technology, 2009
[8]	Ma Guanghua(马光华), Wang Yingjun(王迎军), Li Kai(李凯), Shen Zongyang(沈宗洋).The present situation and development of ceramic pigment with wet chemistry preparation[J].China Ceramics(中国陶瓷), 2003, 39(6):15-20
[9]	Robertson C.Process for manufacturing pigments:US, 2361059.1944-10-24
[10]	Zhuang Dejun(庄德均).The approach of improve the tinting strength of titanium dioxide of pigment level[J].Pangang Technology(攀钢日报), 1998(6):50-52
[11]	Nie Suqing(聂素青).Some questions discussion in tinting strength and blackening test of carbon black[J].Carbon Black Industry(炭黑工业), 2004(3):13-14
[12]	Wang Yonghua(王永华).The new synthesis method for increasing the tinting strength of monoazo pigment[J].Dyestuff Industry(染料工业), 1998, 35(3):19-20
[13]	Zhu Jiliang(朱骥良), Wu Shennian(吴申年).Pigment Technology(颜料工艺学)[M].2nd ed.Beijing:Chemical Industry Press, 2001:209-210
[14]	Li Ping(李平), Zheng Xiaodan(郑晓丹),Xu Hongbin(徐红彬),Wang Weiwen(王伟文),Zhang Yi(张懿).Copper chromite black pigment preparation and application:CN,201210369467.4.2012-9-28
[15]	Yang Xiyun(杨喜云), Gong Zhuqing(龚竹青), Chen Baizhen(陈白珍).Synthesis for iron oxide pigment with high tinting strength[J].Paint and Coatings Industry(涂料工业), 2003, 33(7):22-23
[16]	Chen Bin(陈滨), Li Xiaobin(李小斌), Feng Gangtao(冯港涛), Peng Zhihong(彭志宏), Liu Guihua(刘桂华), Zhou Qiusheng(周秋生).Research progress in preparation of mono-dispersed particles by homogeneous precipitation method[J].Inorganic Chemicals Industry(无机盐工业), 2006, 38(3):9-12
[17]	Wang L, Sondi I, Matijevic＇ E.Preparation of uniform needle-like aragonite particles by homogeneous precipitation[J].Journal of Colloid and Interface Science, 1999, 218(2):545-553
[18]	Huang Kai(黄凯).Study on the preparation of ultrafine NiO particles and the control of their size morphology by controlled-release precipitation process combined with calcination.Hunan:Central South University,2003
[19]	Li Xianping(李宪平).Study on the preparation of nano-sized MgO by co-precipitation method[J].Science and Technology Information(科技资讯), 2007(8):27-28
[20]	Ge Mingqiao(葛明桥), Liang Wenyu(梁文玉), Li Yonggui(李永贵).Dispersion of nano-sized CaCO3 in water[J].Journal of Textile Research(纺织学报), 2007, 28(1):63-67
[21]	Chen S H, Huang J S, Tartaglia P.Structure and Dynamics of Strongly Interacting Colloids and Supramolecular Aggregates in Solution[M].USA:Kluwer Academic, 1992

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十二烷基苯磺酸钠辅助尿素共沉淀制备超细铜铬黑颜料

Synthesis of ultrafine copper chromite black pigment by chemical coprecipitation using SBDS-assisted urea

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