粒径对餐厨沼渣热解制备生物炭中磷和重金属的影响

doi:10.11949/0438-1157.20210502

化工学报 ›› 2021, Vol. 72 ›› Issue (10): 5344-5353.DOI: 10.11949/0438-1157.20210502

粒径对餐厨沼渣热解制备生物炭中磷和重金属的影响

王玉^1,²(),余广炜^1,³(),江汝清^1,²,林佳佳^1,²,汪印¹

^1.中国科学院城市环境研究所，中国科学院城市污染物转化重点实验室，福建厦门 361021
^2.中国科学院大学，北京 100049
^3.福建省城市固体废弃物资源化工程技术研究中心，福建厦门 361021

收稿日期:2021-04-13 修回日期:2021-07-02 出版日期:2021-10-05 发布日期:2021-10-05
通讯作者: 余广炜
作者简介:王玉(1996—)，男，硕士研究生，yuwang@iue.ac.cn
基金资助:
国家重点研发计划项目(2020YFC1908904);中国科学院A类战略性先导科技专项(XDA23020504);福建省自然科学基金项目(2019J01135)

Effect of particle size on phosphorus and heavy metals during the preparation of biochar from food waste biogas residue

Yu WANG^1,²(),Guangwei YU^1,³(),Ruqing JIANG^1,²,Jiajia LIN^1,²,Yin WANG¹

^1.CAS Key Laboratory of Urban Pollutant Conversion, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, Fujian, China
^2.University of Chinese Academy of Sciences, Beijing 100049, China
^3.Fujian Municipal Solid Waste Resource Recovery Technology Research Center, Xiamen 361021, Fujian, China

Received:2021-04-13 Revised:2021-07-02 Online:2021-10-05 Published:2021-10-05
Contact: Guangwei YU

摘要/Abstract

摘要：

以3种粒径餐厨沼渣为原料，在600℃下热解制备生物炭，研究粒径对沼渣（BR）及生物炭（BRC）中磷和重金属的影响，并采用TCLP浸出毒性和重金属潜在生态风险评估对其安全性进行系统研究。结果表明：BR及BRC中的磷主要以酸溶态磷（HCl-P）为主，残渣态磷（Res-P）次之，其余磷形态含量较低，总磷含量均呈现出随粒径增大而降低的趋势。热解促进H₂O-P、NaHCO₃-P和NaOH-P向HCl-P和Res-P转化。随着粒径的增大，BR中Cu、Zn总量增加，Cr减少，BRC中的Cr、As总量增加，Zn、Pb减少。并且BR中Cr、Zn、Pb和As中可氧化态和残渣态F3+F4随粒径增大而减少；BRC中Cr、Pb、As中F3+F4随粒径增大而减少，而Cu、Zn、Cd与之相反。TCLP浸出毒性和重金属潜在生态风险评估结果表明BR及BRC中重金属均属于低风险水平。

关键词: 粒径, 餐厨沼渣, 生物炭, 热解, 磷, 重金属, 生态风险评估, 废物处置

Abstract:

In this paper, biochar (BRC) produced from biogas residue (BR) with three particle sizes (d≤0.15 mm, 0.15 mm <d≤0.25 mm, d>0.25 mm) were obtained by pyrolysis at 600℃. The effects of different particle sizes on the migration and transformation of phosphorus and heavy metals between BR and BRC were systematically studied. And toxicity characteristic leaching procedure (TCLP) leaching toxicity test and potential ecological risk assessment were used to evaluate the safety risk of BR and BRC. The results showed that the phosphorus in BR and BRC were mainly acid-soluble phosphorus (HCl-P), followed by residual phosphorus (Res-P), and the contents of other phosphorus forms were low. TP content showed a decreasing trend with increase of particle size in BR and BRC. Pyrolysis can promote the conversion of H₂O-P, NaHCO₃-P and NaOH-P to HCl-P and Res-P. As the particle size increases, the total amount of Cu and Zn in BR increases, while the amount of Cr decreases, the total amount of Cr and As in BRC increases, and the total amount of Zn and Pb decreases. Meanwhile, the F3+F4 fractions (oxidizable and residue fraction) of Cr, Zn, Pb, As in BR and that of Cr, Pb, As in BRC decreased with the increase of particle size, while Cu, Zn and Cd of BRC showed an opposite trend. The assessment results of TCLP leaching toxicity and potential ecological risk of heavy metals indicate that the heavy metals in BR and BRC are at low risk levels.

Key words: particle size, biogas residue, biochar, pyrolysis, phosphorus, heavy metals, ecological risk assessment, waste treatment

中图分类号:

X 705

王玉,余广炜,江汝清,林佳佳,汪印. 粒径对餐厨沼渣热解制备生物炭中磷和重金属的影响[J]. 化工学报, 2021, 72(10): 5344-5353.

Yu WANG,Guangwei YU,Ruqing JIANG,Jiajia LIN,Yin WANG. Effect of particle size on phosphorus and heavy metals during the preparation of biochar from food waste biogas residue[J]. CIESC Journal, 2021, 72(10): 5344-5353.

图/表 11

参考文献 39

1	Li Y Y, Manandhar A, Li G X, et al. Life cycle assessment of integrated solid state anaerobic digestion and composting for on-farm organic residues treatment[J]. Waste Management, 2018, 76: 294-305.
2	何品晶, 周琪, 吴铎, 等. 餐厨垃圾和厨余垃圾厌氧消化产生沼渣的脱水性能分析[J]. 化工学报, 2013, 64(10): 3775-3781.
	He P J, Zhou Q, Wu D, et al. Dewaterability of digestate produced from restaurant food waste and household kitchen waste anaerobic digestion[J]. CIESC Journal, 2013, 64(10): 3775-3781.
3	Li C X, Li J, Pan L J, et al. Treatment of digestate residues for energy recovery and biochar production: from lab to pilot-scale verification[J]. Journal of Cleaner Production, 2020, 265: 121852.
4	李杰, 潘兰佳, 余广炜, 等. 污泥中抗生素热解特性及动力学分析[J]. 环境工程学报, 2017, 11(9): 5213-5219.
	Li J, Pan L J, Yu G W, et al. Pyrolysis characteristics and kinetics analysis of several antibiotics in sludge[J]. Chinese Journal of Environmental Engineering, 2017, 11(9): 5213-5219.
5	Zeng Z W, Tan X F, Liu Y G, et al. Comprehensive adsorption studies of doxycycline and ciprofloxacin antibiotics by biochars prepared at different temperatures[J]. Frontiers in Chemistry, 2018, 6: 80.
6	Berge N D, Ro K S, Mao J D, et al. Hydrothermal carbonization of municipal waste streams[J]. Environmental Science & Technology, 2011, 45(13): 5696-5703.
7	王亮才, 马欢欢, 周建斌. 炭化工艺对脱水沼渣炭理化性质的影响[J]. 化工进展, 2019, 38(3): 1545-1551.
	Wang L C, Ma H H, Zhou J B. Effect of carbonization process on physiochemical properties of digestate[J]. Chemical Industry and Engineering Progress, 2019, 38(3): 1545-1551.
8	Hung C Y, Tsai W T, Chen J W, et al. Characterization of biochar prepared from biogas digestate[J]. Waste Management, 2017, 66: 53-60.
9	葛振, 魏源送, 刘建伟, 等. 沼渣特性及其资源化利用探究[J]. 中国沼气, 2014, 32(3): 74-82.
	Ge Z, Wei Y S, Liu J W, et al. Characteristics of digestate and utilization: an overview[J]. China Biogas, 2014, 32(3): 74-82.
10	Manyà J J. Pyrolysis for biochar purposes: a review to establish current knowledge gaps and research needs[J]. Environmental Science & Technology, 2012, 46(15): 7939-7954.
11	Ma Y Q, Yin Y, Liu Y. A holistic approach for food waste management towards zero-solid disposal and energy/resource recovery[J]. Bioresource Technology, 2017, 228: 56-61.
12	Li B, Yin T L, Udugama I A, et al. Food waste and the embedded phosphorus footprint in China[J]. Journal of Cleaner Production, 2020, 252: 119909.
13	燕燕, 徐苏云, 左刘泉, 等. 猪粪沼渣制备生物炭的磷形态转化分析[J]. 浙江农业科学, 2020, 61(4): 772-775.
	Yan Y, Xu S Y, Zuo L Q, et al. Phosphorus form transformation during the production of biochar from digested swine manure[J]. Journal of Zhejiang Agricultural Sciences, 2020, 61(4):772-775.
14	Alghashm Shakib. 餐厨垃圾沼渣炭化及其对磷和毒死蜱的吸附与土壤肥效研究[D]. 上海: 上海交通大学, 2019.
	Shakib A. Preparation of biochar from anaerobically digested food waste and its potential use in phosphorus/chlorpyrifos adsorption and soil amendment[D]. Shanghai: Shanghai Jiao Tong University, 2019.
15	Zuo L Q, Lin R P, Shi Q, et al. Evaluation of the bioavailability of heavy metals and phosphorus in biochar derived from manure and manure digestate[J]. Water, Air, & Soil Pollution, 2020, 231(11): 1-11.
16	Liu J X, Huang S M, Chen K, et al. Preparation of biochar from food waste digestate: pyrolysis behavior and product properties[J]. Bioresource Technology, 2020, 302: 122841.
17	Bruun S, Harmer S L, Bekiaris G, et al. The effect of different pyrolysis temperatures on the speciation and availability in soil of P in biochar produced from the solid fraction of manure[J]. Chemosphere, 2017, 169: 377-386.
18	Jiang B N, Lin Y Q, Mbog J C. Biochar derived from swine manure digestate and applied on the removals of heavy metals and antibiotics[J]. Bioresource Technology, 2018, 270: 603-611.
19	王兴栋, 张斌, 余广炜, 等. 不同粒径污泥热解制备生物炭及其特性分析[J]. 化工学报, 2016, 67(11): 4808-4816.
	Wang X D, Zhang B, Yu G W, et al. Preparation of biochar with different particle sized sewage sludge and its characteristics[J]. CIESC Journal, 2016, 67(11): 4808-4816.
20	Hedley M J, Stewart J W B, Chauhan B S. Changes in inorganic and organic soil phosphorus fractions induced by cultivation practices and by laboratory incubations[J]. Soil Science Society of America Journal, 1982, 46(5): 970-976.
21	李国华, 张福锁, 李海港. 畜禽粪便中磷不同组份的测定方法研究进展[J]. 土壤通报, 2013, 44(3): 760-768.
	Li G H, Zhang F S, Li H G. Research progress on methods for determination of phosphorus components in animal manure[J]. Chinese Journal of Soil Science, 2013, 44(3): 760-768.
22	Wang X D, Li C X, Zhang B, et al. Migration and risk assessment of heavy metals in sewage sludge during hydrothermal treatment combined with pyrolysis[J]. Bioresource Technology, 2016, 221: 560-567.
23	Wang X D, Chang V W C, Li Z W, et al. Co-pyrolysis of sewage sludge and organic fractions of municipal solid waste: synergistic effects on biochar properties and the environmental risk of heavy metals[J]. Journal of Hazardous Materials, 2021, 412: 125200.
24	Jin J W, Li Y N, Zhang J Y, et al. Influence of pyrolysis temperature on properties and environmental safety of heavy metals in biochars derived from municipal sewage sludge[J]. Journal of Hazardous Materials, 2016, 320: 417-426.
25	Demirbaş A. Gaseous products from biomass by pyrolysis and gasification: effects of catalyst on hydrogen yield[J]. Energy Conversion and Management, 2002, 43(7): 897-909.
26	田爽爽. 生物炭制备过程中养分元素迁移转化机制研究[D]. 武汉: 华中农业大学, 2016.
	Tian S S. Study on the transformation mechanism of nutrient element buring the preparation of biochar[D]. Wuhan: Huazhong Agricultural University, 2016.
27	Liu D S, Zhu H Z, Wu K M, et al. Understanding the effect of particle size of waste concrete powder on phosphorus removal efficiency[J]. Construction and Building Materials, 2020, 236: 117526.
28	Zhang H L, Sheng G P, Fang W, et al. Calcium effect on the metabolic pathway of phosphorus accumulating organisms in enhanced biological phosphorus removal systems[J]. Water Research, 2015, 84: 171-180.
29	孟详东, 黄群星, 严建华, 等. 磷在污泥热解过程中的迁移转化[J]. 化工学报, 2018, 69(7): 3208-3215.
	Meng X D, Huang Q X, Yan J H, et al. Migration and transformation of phosphorus during pyrolysis process of sewage sludge[J]. CIESC Journal, 2018, 69(7):3208-3215.
30	Andrieux F, Aminot A. A two-year survey of phosphorus speciation in the sediments of the Bay of Seine (France)[J]. Continental Shelf Research, 1997, 17(10): 1229-1245.
31	Qian T T, Li D C, Jiang H. Thermochemical behavior of tris(2-butoxyethyl) phosphate (TBEP) during Co-pyrolysis with biomass[J]. Environmental Science & Technology, 2014, 48(18): 10734-10742.
32	Huang R X, Fang C, Zhang B, et al. Transformations of phosphorus speciation during (hydro)thermal treatments of animal manures[J]. Environmental Science & Technology, 2018, 52(5): 3016-3026.
33	van Wesenbeeck S, Prins W, Ronsse F, et al. Sewage sludge carbonization for biochar applications. fate of heavy metals[J]. Energy & Fuels, 2014, 28(8): 5318-5326.
34	Wang X D, Li C X, Li Z W, et al. Effect of pyrolysis temperature on characteristics, chemical speciation and risk evaluation of heavy metals in biochar derived from textile dyeing sludge[J]. Ecotoxicology and Environmental Safety, 2019, 168: 45-52.
35	Jin H M, Arazo R O, Gao J, et al. Leaching of heavy metals from fast pyrolysis residues produced from different particle sizes of sewage sludge[J]. Journal of Analytical and Applied Pyrolysis, 2014, 109: 168-175.
36	Mizutani S, Watanabe N, Sakai S, et al. Influence of particle size preparation of MSW incineration residues on heavy metal leaching behavior in leaching tests[J]. Environmental Sciences: an International Journal of Environmental Physiology and Toxicology, 2006, 13(6): 363-370.
37	Devi P, Saroha A K. Risk analysis of pyrolyzed biochar made from paper mill effluent treatment plant sludge for bioavailability and eco-toxicity of heavy metals[J]. Bioresource Technology, 2014, 162: 308-315.
38	Wong J W C, Li K, Fang M, et al. Toxicity evaluation of sewage sludges in Hong Kong[J]. Environment International, 2001, 27(5): 373-380.
39	Zhang Z Y, Ju R, Zhou H T, et al. Migration characteristics of heavy metals during sludge pyrolysis[J]. Waste Management, 2021, 120: 25-32.

C_f	单一重金属污染程度	E_r	单项潜在生态风险程度	RI	重金属潜在风险程度
C_f≤1	极低	E_r≤40	低	RI≤150	低
1<C_f≤3	低	40<E_r≤80	中	150<RI≤300	中
3<C_f≤6	中	80<E_r≤160	较高	300<RI≤600	较高
6<C_f≤9	较高	160<E_r≤320	高	RI>600	高
C_f>9	高	E_r>320	很高

C_f	单一重金属污染程度	E_r	单项潜在生态风险程度	RI	重金属潜在风险程度
C_f≤1	极低	E_r≤40	低	RI≤150	低
1<C_f≤3	低	40<E_r≤80	中	150<RI≤300	中
3<C_f≤6	中	80<E_r≤160	较高	300<RI≤600	较高
6<C_f≤9	较高	160<E_r≤320	高	RI>600	高
C_f>9	高	E_r>320	很高

样品	产率/%	工业分析/% (质量)			元素分析/% (质量)
样品	产率/%	灰分(Ash)	挥发分(VM)	固定碳(FC)	C	H	N	S	H/C	C/N
BR1	—	62.67	32.11	5.22	18.55	2.67	1.8	0.73	0.14	10.31
BR2	—	56.48	41.18	2.34	20.00	2.53	2.06	0.81	0.13	9.73
BR3	—	52.55	43.01	4.43	21.29	3.04	2.28	0.76	0.14	9.33
BRC1	74.78	81.71	14.73	3.56	12.01	2.08	0.55	0.48	0.17	21.95
BRC2	72.59	79.34	17.08	3.58	12.29	2.05	0.63	0.64	0.17	19.49
BRC3	65.47	76.98	20.83	2.19	13.23	1.47	0.70	0.54	0.11	18.95

样品	产率/%	工业分析/% (质量)			元素分析/% (质量)
样品	产率/%	灰分(Ash)	挥发分(VM)	固定碳(FC)	C	H	N	S	H/C	C/N
BR1	—	62.67	32.11	5.22	18.55	2.67	1.8	0.73	0.14	10.31
BR2	—	56.48	41.18	2.34	20.00	2.53	2.06	0.81	0.13	9.73
BR3	—	52.55	43.01	4.43	21.29	3.04	2.28	0.76	0.14	9.33
BRC1	74.78	81.71	14.73	3.56	12.01	2.08	0.55	0.48	0.17	21.95
BRC2	72.59	79.34	17.08	3.58	12.29	2.05	0.63	0.64	0.17	19.49
BRC3	65.47	76.98	20.83	2.19	13.23	1.47	0.70	0.54	0.11	18.95

样品	含量/(mg/kg)
样品	Na	Mg	Al	Si	S	Cl	K	Ca	Fe
BR1	7.33	6.67	11.91	15.27	6.15	23.90	3.95	338.4	10.81
BR2	7.44	5.58	10.85	13.89	6.58	24.57	3.97	306.5	10.59
BR3	8.68	4.92	9.12	11.32	5.18	28.15	4.10	266.5	10.60
BRC1	10.70	8.01	14.12	17.66	7.36	33.78	5.58	389.5	11.70
BRC2	10.68	7.78	12.97	17.50	6.66	45.03	6.84	377.1	12.45
BRC3	9.70	4.94	7.58	10.03	3.60	33.87	5.63	297.7	11.37

粒径对餐厨沼渣热解制备生物炭中磷和重金属的影响

Effect of particle size on phosphorus and heavy metals during the preparation of biochar from food waste biogas residue

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

图/表 11

参考文献 39

相关文章 15

编辑推荐

Metrics

本文评价

样品	总磷TP/(mg/g)	无机磷IP/(mg/g)	有机磷OP/(mg/g)
BR1	19.484±0.443	18.437±0.469	0.932±0.012
BR2	18.544±0.221	17.120±0.379	0.908±0.020
BR3	16.349±0.384	15.526±0.358	0.881±0.017
BRC1	26.225±0.768	25.337±0.704	0.416±0.033
BRC2	25.754±0.384	25.128±0.191	0.316±0.006
BRC3	24.814±0.394	24.560±0.307	0.281±0.010

样品		重金属总量/(mg/kg)
样品		Cr	Cu	Zn	Cd	Pb	As
BR1		65.20±2.33	14.36±1.33	38.08±0.81	0.96±0.02	5.04±0.55	7.31±0.14
BR2		72.85±3.03	19.46±0.27	52.47±1.04	1.05±0.01	6.29±0.27	7.26±0.04
BR3		71.72±1.60	20.84±0.47	58.15±4.57	1.03±0.02	6.00±0.26	7.88±0.10
BRC1		78.86±2.84	17.98±0.15	74.92±1.99	0.18±0.01	5.59±0.23	7.44±0.13
BRC2		83.34±0.84	19.53±0.27	74.42±4.24	0.22±0.01	4.98±0.19	9.04±0.10
BRC3		86.46±4.05	17.87±0.82	70.18±2.73	0.19±0.02	4.61±0.26	11.93±0.07
绿化种植土壤标准（CJ/T340—2011（Ⅲ））	pH＜6.5	200	300	400	0.8	350	40
绿化种植土壤标准（CJ/T340—2011（Ⅲ））	pH≥6.5	250	350	450	1.0	400	35

样品	重金属浸出量/(mg/L)
样品	Cr	Cu	Zn	Cd	Pb	As
BR1	0.038±0.001	0.131±0.012	0.036±0.011	0.004±0.000	0.000±0.000	0.090±0.004
BR2	0.059±0.007	0.180±0.007	0.032±0.004	0.004±0.001	0.000±0.000	0.135±0.009
BR3	0.054±0.002	0.279±0.037	0.038±0.005	0.003±0.000	0.000±0.000	0.159±0.001
BRC1	0.078±0.008	0.006±0.002	0.044±0.007	0.002±0.000	0.001±0.000	0.020±0.002
BRC2	0.090±0.008	0.005±0.002	0.039±0.014	0.003±0.000	0.001±0.000	0.033±0.002
BRC3	0.096±0.003	0.004±0.000	0.049±0.017	0.004±0.000	0.001±0.000	0.036±0.001
阈值^①	5	—	5	1	5	5

样品	单一金属污染系数C_f						单项潜在生态风险系数E_r						重金属潜在生态风险指数RI
样品	Cr	Cu	Zn	Cd	Pb	As	Cr	Cu	Zn	Cd	Pb	As	重金属潜在生态风险指数RI
BR1	0.421	1.798	0.375	1.529	0.008	1.434	0.842	8.991	0.375	45.875	0.041	14.338	70.462
BR2	0.473	1.852	0.342	1.825	0.004	2.456	0.947	9.262	0.342	54.743	0.021	24.561	89.875
BR3	0.437	2.297	0.410	2.110	0.005	2.882	0.874	11.486	0.410	63.310	0.026	28.816	104.921
BRC1	0.356	1.512	1.143	1.920	0.022	0.942	0.712	7.561	1.143	57.606	0.108	9.415	76.545
BRC2	0.358	1.394	1.120	1.691	0.024	1.292	0.716	6.968	1.120	50.722	0.120	12.920	72.566
BRC3	0.403	1.098	0.951	1.765	0.029	1.739	0.806	5.488	0.951	52.964	0.143	17.394	77.745

[1]	范孝雄, 郝丽芳, 范垂钢, 李松庚. LaMnO₃/生物炭催化剂低温NH₃-SCR催化脱硝性能研究[J]. 化工学报, 2023, 74(9): 3821-3830.
[2]	吴雷, 刘姣, 李长聪, 周军, 叶干, 刘田田, 朱瑞玉, 张秋利, 宋永辉. 低阶粉煤催化微波热解制备含碳纳米管的高附加值改性兰炭末[J]. 化工学报, 2023, 74(9): 3956-3967.
[3]	仪显亨, 周骛, 蔡小舒, 蔡天意. 光纤后向动态光散射测量纳米颗粒的浓度适用范围研究[J]. 化工学报, 2023, 74(8): 3320-3328.
[4]	杨越, 张丹, 郑巨淦, 涂茂萍, 杨庆忠. NaCl水溶液喷射闪蒸-掺混蒸发的实验研究[J]. 化工学报, 2023, 74(8): 3279-3291.
[5]	杨峥豪, 何臻, 常玉龙, 靳紫恒, 江霞. 生物质快速热解下行式流化床反应器研究进展[J]. 化工学报, 2023, 74(6): 2249-2263.
[6]	张建华, 陈萌萌, 孙雅雯, 彭永臻. 部分短程硝化同步除磷耦合Anammox实现生活污水高效脱氮除磷[J]. 化工学报, 2023, 74(5): 2147-2156.
[7]	衣思敏, 马亚丽, 刘伟强, 张金帅, 岳岩, 郑强, 贾松岩, 李雪. 微晶菱镁矿蒸氨及水化动力学研究[J]. 化工学报, 2023, 74(4): 1578-1586.
[8]	蹇建, 张嘉明, 佘祥, 周虎, 游奎一, 罗和安. V⁴⁺和V⁵⁺比例对钒磷氧催化NO₂氧化环己烷性能的影响[J]. 化工学报, 2023, 74(4): 1570-1577.
[9]	苏晓丹, 朱干宇, 李会泉, 郑光明, 孟子衡, 李防, 杨云瑞, 习本军, 崔玉. 湿法磷酸半水工艺考察与石膏结晶过程研究[J]. 化工学报, 2023, 74(4): 1805-1817.
[10]	刘瑞琪, 周栖桐, 张悦, 贺莹, 高静, 马丽. 基于金纳米颗粒修饰二氧化硅纳米花的生物传感器构建及应用[J]. 化工学报, 2023, 74(3): 1247-1259.
[11]	陈瑞哲, 程磊磊, 顾菁, 袁浩然, 陈勇. 纤维增强树脂复合材料化学回收技术研究进展[J]. 化工学报, 2023, 74(3): 981-994.
[12]	张娜, 潘鹤林, 牛波, 张亚运, 龙东辉. 酚醛树脂热裂解反应机理的密度泛函理论研究[J]. 化工学报, 2023, 74(2): 843-860.
[13]	姜家豪, 黄笑乐, 任纪云, 朱正荣, 邓磊, 车得福. 生物炭吸附溶液中Pb²⁺的定性及定量研究[J]. 化工学报, 2023, 74(2): 830-842.
[14]	郝泽光, 张乾, 高增林, 张宏文, 彭泽宇, 杨凯, 梁丽彤, 黄伟. 生物质与催化裂化油浆共热解协同作用研究[J]. 化工学报, 2022, 73(9): 4070-4078.
[15]	邵健, 冯军宗, 柳凤琦, 姜勇刚, 李良军, 冯坚. 酚醛树脂基炭微球结构调控与功能化制备研究进展[J]. 化工学报, 2022, 73(9): 3787-3801.