预接触温度对聚丙烯DQC球形催化剂聚合性能的影响

doi:10.11949/j.issn.0438-1157.20161119

摘要/Abstract

摘要：

使用甲基环己基二甲氧基硅烷（C-donor）作为外给电子体，对聚丙烯DQC球形催化剂进行了预接触温度液相本体聚合研究。实验结果表明，预接触温度升高，DQC球形催化剂的聚合活性降低，得到聚合物的等规指数升高，熔融指数下降，得到的聚合物细粉含量增加。GPC测试结果表明，预接触温度升高，聚合物的分子量分布变宽，数均分子量和重均分子量降低。DSC测试结果表明，聚合物的熔融温度、熔融焓和结晶焓数值均有不同程度的提高，聚合物的结晶度提高。¹³C NMR测试结果表明，预接触温度升高，得到的聚合物全同立构三单元组mm序列结构和五单元组mmmm序列结构含量均增加。

关键词: 预接触温度, DQC球形催化剂, 聚丙烯, 丙烯聚合

Abstract:

The pre-contact temperature of DQC catalyst system on liquid bulk polymerization of propylene was studied using cyclohexyl methyl dimethoxy silane (C-donor) as external donor. The results indicated that increase of pre-contact temperature caused decrease of polymerization activity of DQC catalyst, which yielded polymers with decreased melt index but increased isotactic index and fine powder content. Gel permeation chromatography (GPC) results showed that increase of pre-contact temperature broadened molecular weight distributions and decreased both number and weight average molecular weights. Differential scanning calorimetry (DSC) results exhibited that melting temperature, melting enthalpy, crystallization enthalpy, and crystallinity of polypropylenes increased to various degrees. ¹³C NMR results showed an increase of stereoregular sequences of triad mm and pentad mmmm with increase of pre-contact temperature.

Key words: pre-contact temperature, DQC spherical catalyst, polypropylene, propylene polymerization

中图分类号:

TQ325.14

张天一, 夏先知, 刘月祥. 预接触温度对聚丙烯DQC球形催化剂聚合性能的影响[J]. 化工学报, 2017, 68(4): 1434-1441.

ZHANG Tianyi, XIA Xianzhi, LIU Yuexiang. Effect of pre-contact temperature on performance of DQC spherical catalyst in propylene polymerization[J]. CIESC Journal, 2017, 68(4): 1434-1441.

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