耦合电解水制氢的绿色有机电合成——电极界面调控策略综述

doi:10.11949/0438-1157.20250058

化工学报 ›› 2025, Vol. 76 ›› Issue (8): 3753-3771.DOI: 10.11949/0438-1157.20250058

• 综述与专论 • 下一篇

耦合电解水制氢的绿色有机电合成——电极界面调控策略综述

王御风¹(), 罗小雪¹(), 范鸿亮¹, 吴白婧¹, 李存璞¹^,²(), 魏子栋¹^,²()

^1.重庆大学化学化工学院，特种化学电源全国重点实验室，重庆 400044
^2.重庆大学锂电及新材料遂宁研究院，四川遂宁 629000

收稿日期:2025-01-14 修回日期:2025-03-11 出版日期:2025-08-25 发布日期:2025-09-17
通讯作者: 李存璞,魏子栋
作者简介:王御风(2000—)，男，硕士研究生，30406870@qq.com
罗小雪（1998—），女，博士研究生，20165463@cqu.edu.cn
基金资助:
国家重点研发计划项目(2022YFC2105904);国家自然科学基金项目(22478043);国家自然科学基金项目(22090030);国家自然科学基金项目(U21A20312);国家自然科学基金项目(22075033)

Green organic electrosynthesis coupled with water electrolysis to produce hydrogen—overview of electrode interface regulation strategies

Yufeng WANG¹(), Xiaoxue LUO¹(), Hongliang FAN¹, Baijing WU¹, Cunpu LI¹^,²(), Zidong WEI¹^,²()

^1.State Key Laboratory of Advanced Chemical Power Sources, School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400044, China
^2.Suining Lithium Battery Research Institute of Chongqing University(SLiBaC), Chongqing University, Suining 629000, Sichuan, China

Received:2025-01-14 Revised:2025-03-11 Online:2025-08-25 Published:2025-09-17
Contact: Cunpu LI, Zidong WEI

摘要/Abstract

摘要：

随着全球能源危机和环境污染问题日益加剧，电解水制氢作为一种清洁、高效的制氢技术备受关注。然而，传统电解水阳极析氧反应存在动力学迟缓、过电位高以及氧气副产物等问题，限制了技术的进一步发展。近年来，研究人员发展了利用电解水阳极生成的活性氧物种（ROS）（*OOH、*OH和*O等）实现有机物选择性氧化的系列策略，可以有效提升电解水的能量、原子利用率，减少能耗，提升生产附加值。电极界面作为电化学反应的场所，电极材料的多尺度结构、反应底物的吸附行为等，都影响着耦合电解水制氢的绿色有机氧化效率和选择性。因此，本文综述了利用活性氧物种氧化有机物耦合电解水制氢的电极表面调控策略，重点讨论了电极强化“界面-底物”过程的作用、电极控制荷质传递过程以及电极调控反应作用机理等三个方面。通过掺杂、构筑应变、引入空位和异质结等手段调控电极电子结构，能够促进ROS生成和反应底物吸附，提升反应选择性与效率；通过采用恒电位和脉冲电解等多种电化学方法，可以调控电极材料的金属价态和电子传递速率，优化反应动力学；通过引入介体或添加剂、开发双效催化剂以及表面插层等手段，可以有效调控电极表面对ROS的吸附与利用，同时调节电极对反应底物的吸附特性。未来研究将集中于电极表面催化形态精准调控、催化剂活性位点优化以及机理研究，推动电解水制氢与绿色有机电化学合成的协同发展，为新能源和绿色化学的应用提供新思路。

关键词: 活性氧物种（ROS）, 有机电合成, 界面调控, 电解水, 电极材料, 电子材料, 电化学, 制氢

Abstract:

With the increasing global energy crisis and environmental pollution, water electrolysis for hydrogen production has attracted much attention as a clean and efficient hydrogen production technology. However, the traditional oxygen evolution reaction (OER) at the anode faces challenges such as slow reaction kinetics, high energy loss, and the generation of low-value oxygen. Recent studies have shown that utilizing reactive oxygen species (ROS) (*OOH, *OH, *O, etc.) generated during electrolysis for selective organic oxidation can improve energy efficiency, reduce costs, and produce valuable chemicals along with hydrogen. The electrode surface plays a key role in controlling the efficiency and selectivity of this process. Factors such as electrode material structure and its interaction with organic molecules strongly influence the reaction. This review discusses strategies to modify electrode surfaces for improving organic oxidation driven by ROS during water electrolysis. Three main aspects are emphasized: improving the interaction between the electrode and organic molecules, controlling charge and mass transfer, and adjusting reaction pathways through electrode design. Modification methods such as doping and strain engineering modulate the electronic properties of electrodes, thereby enhancing ROS generation and organic adsorption, which improves reaction selectivity and efficiency. In addition, electrochemical techniques like constant potential and stepped potential control can adjust metal oxidation states and electron transfer, further optimizing reaction performance. Introducing mediators or additives, using bifunctional catalysts, and applying surface intercalation strategies can also help regulate ROS behavior on the electrode surface and tune organic molecule adsorption. Future efforts should prioritize atomic-level control of electrode surfaces and mechanistic exploration of interfacial dynamics, which are critical for scalable coupling of hydrogen production with organic electrosynthesis. Cross-disciplinary integration of operand characterization and machine learning will accelerate the inverse design of catalysts with tailored ROS-substrate adsorption, ultimately bridging fundamental discoveries to sustainable chemical manufacturing.

Key words: reactive oxygen species (ROS), organic electrosynthesis, interface control, electrolytic water, electrode material, electronic material, electrochemistry, hydrogen production

中图分类号:

O 6-1

王御风, 罗小雪, 范鸿亮, 吴白婧, 李存璞, 魏子栋. 耦合电解水制氢的绿色有机电合成——电极界面调控策略综述[J]. 化工学报, 2025, 76(8): 3753-3771.

Yufeng WANG, Xiaoxue LUO, Hongliang FAN, Baijing WU, Cunpu LI, Zidong WEI. Green organic electrosynthesis coupled with water electrolysis to produce hydrogen—overview of electrode interface regulation strategies[J]. CIESC Journal, 2025, 76(8): 3753-3771.

图/表 11

图1 耦合电解水制氢的绿色有机电合成发展时间轴[4-25]

Fig.1 Timeline of development for green organic electrosynthesis coupled with water electrolysis[4-25]

图2 (a) Fe-Ni3S2和Ni3S2自重构后BA电氧化的反应路径[通过Fe掺杂，决速步骤的ΔG（*Ph—CH2—NH到*Ph—CH2NH）从0.59 eV降低到0.14 eV]；(b) BA电氧化吸附中间体结构（1 Å=0.1 nm）；(c) Ni(OH)2和(d) Cr0.02Ni(OH)2+δ 在不同电位下的原位ATR-FTIR光谱[51-52]

Fig.2 (a) Reaction pathways of BA electro oxidation after Fe-Ni3S2 and Ni3S2 self reconstruction; (b) BA electro oxidation adsorption intermediate structure; In situ ATR-FTIR spectra of (c) Ni (OH)2 and (d) Cr0.02Ni (OH)2+δ at different potentials[51-52]

图3 (a) S-NiCo-LDH LSV曲线；Mn-Co-S/NF和Mn-Co/NF的(b) Co 2p和(c) Mn 2p高分辨率XPS谱；(d) Mn-Co-S/NF的S 2p高分辨率XPS谱；(e) DFT计算Co3N和PW-Co3N表面上 HzOR的自由能分布[53-55]

Fig.3 (a) S-NiCo LDH LSV curve; High resolution XPS spectra of (b) Co 2p and (c) Mn 2p for Mn-Co-S/NF and Mn Co/NF; (d) S 2p high-resolution XPS spectra of Mn-Co-S/NF; (e) DFT calculation of the free energy distribution of HzOR on the surfaces of Co3N and PW-Co3N[53-55]

图4 (a)DP-PdCu（DP:双相）沿BCC [001]区轴的像差校正HAADF-STEM图像；(b) 图(a)中所选矩形区域的原子排列；(c)BCC [110]和FCC [020]平面之间界面的模拟原子模型[56]

Fig.4 (a) Aberration corrected HAADF-STEM image of DP PdCu (DP: biphasic) along the BCC [001] region axis; (b) The atomic arrangement of the selected rectangular region in Fig.(a); (c) Simulated atomic model of the interface between BCC [110] and FCC [020] planes[56]

图5 MoO2-FeP@C和FeP@C的(a)Fe 2p、(b)P 2p、(c)Mo 3d、(d)O 1s XPS谱图; (e)Ni3B/Ni异质结构上发生的MOR Gibbs自由能图以及不同表面上台阶之间Gibbs自由能的变化; (f)Ni3B(001)/Ni(111)异质结构、Ni3B和Ni的Ni活性位点的d投影DOS的部分态密度(PDOS)[59,61]

Fig.5 MoO2-FeP@C and FeP@C XPS spectra of (a) Fe 2p, (b) P 2p, (c) Mo 3d, (d) O 1s; (e) MOR Gibbs free energy diagram on Ni3B/Ni heterostructure (top) and Gibbs free energy variation between steps on different surfaces (bottom); (f) Partial density of states (PDOS) of the d-projection DOS of Ni3B (001)/Ni (111) heterostructures and Ni active sites in Ni3B and Ni[59,61]

图6 (a)MnO2和RuO2分别用于活化苯乙烯乙烯基和产生ROS示意图；(b)MnO2(131)吸附前后MnO2的总DOS和苯乙烯的部分电子态密度[66]

Fig.6 (a) Schematic diagram of MnO2 and RuO2 used for activating styrene vinyl and generating ROS; (b) The total DOS of MnO2 (131) before and after adsorption, as well as the partial electronic density of states of styrene[66]

图7 (a)加底物50 mmol/L HMF的原位EIS谱图；(b)未加底物50 mmol/L HMF的原位EIS谱图；(c) Vo-Co3O4和Co3O4的电极内氧化电阻（Rp）；(d)Vo-Co3O4和Co3O4的电极界面反应电阻（Rct）[70]

Fig.7 (a)In situ EIS spectra with substrate 50 mmol/L HMF added; (b) In situ EIS spectra without 50 mmol/L HMF substrate addition; (c) The electrode internal oxidation resistance (Rp) of Vo-Co3O4 and Co3O4; (d) The electrode interface reaction resistance (Rct) of Vo-Co3O4 and Co3O4

图8 电子催化策略直接将N2固定为偶氮的机理[72]

Fig.8 The mechanism of directly fixing N2 to azo using the electronic catalytic strategy[72]

图9 (a)在含有和不含GLY（甘油）的电解液中Pt@G的CV曲线；(b)0.7 V下以不同时间进行PE3（脉冲电解）和CE（恒电位电解）后的Pt@G原位FTIR光谱[74]

Fig.9 (a) CV curves of Pt@G in electrolytes with and without GLY (glycerol); (b) In situ FTIR spectroscopy of Pt@G with PE3 (pulse electrolysis) and CE (constant potential electrolysis) at different time under 0.7 V[74]

图10 (a)羧酸通过可循环过氧酸介体的方法来实现烯烃可持续环氧化反应的机理示意图；(b)Cl4NHPI作为脱氢剂的反应机理示意图；(c)(bpy)Cu/TEMPO助催化剂系统的反应机理示意图；(d)3种不同催化剂体系与6种不同苄基、脂肪族、伯和仲醇的相对催化活性[80,82-83]

Fig.10 (a)Schematic diagram of the mechanism for achieving sustainable epoxidation of olefins by using carboxylic acid as a recyclable peroxide mediator; (b) Schematic diagram of the reaction mechanism of Cl4NHPI as a dehydrogenation agent; (c) Schematic diagram of the reaction mechanism of (bpy)Cu/TEMPO co-catalyst system; (d) Relative catalytic activity of three different catalyst systems with six different benzyl, aliphatic, primary, and secondary alcohols[80,82-83]

图11 (a)CeO2@PbO2@Ti电极用于Baeyer-Villiger反应的机理示意图；(b)HMFOR的Al(OH)3/Co(OH)2合成及电化学体系示意图；(c)描述串联反应的反应路径的示意图[88-90]

Fig.11 (a)Schematic diagram of the mechanism of Baeyer-Villiger reaction using CeO2@PbO2@Ti electrode; (b) Schematic diagram of Al(OH)3/Co(OH)2 synthesis and electrochemical system of HMFOR; (c) A schematic diagram illustrating the reaction pathway of a series reaction[88-90]

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耦合电解水制氢的绿色有机电合成——电极界面调控策略综述

Green organic electrosynthesis coupled with water electrolysis to produce hydrogen—overview of electrode interface regulation strategies

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