CIESC Journal ›› 2020, Vol. 71 ›› Issue (5): 2118-2127.DOI: 10.11949/0438-1157.20191403
• Process system engineering • Previous Articles Next Articles
Guangjie LIU1(),Xiaoyan SUN1,Rongshan BI1,Jianping WANG2,Shuguang XIANG1()
Received:
2019-11-20
Revised:
2019-12-27
Online:
2020-05-05
Published:
2020-05-05
Contact:
Shuguang XIANG
通讯作者:
项曙光
作者简介:
刘广杰(1994—),男,硕士研究生, 基金资助:
CLC Number:
Guangjie LIU, Xiaoyan SUN, Rongshan BI, Jianping WANG, Shuguang XIANG. Improved equation oriented inside-out method of complex crude distillation column simulation[J]. CIESC Journal, 2020, 71(5): 2118-2127.
刘广杰, 孙晓岩, 毕荣山, 王建平, 项曙光. 复杂炼油塔模拟的改进联立方程内外层算法[J]. 化工学报, 2020, 71(5): 2118-2127.
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Number | Component | Mass flow/ (kg·h-1) | Number | Component | Mass flow/ (kg·h-1) |
---|---|---|---|---|---|
1 | water | 233.3 | 8 | C2H6 | 136.2 |
2 | O2 | 6.4 | 9 | C3H8 | 200.8 |
3 | N2 | 21.2 | 10 | IC4 | 86.3 |
4 | H2S | 2.1 | 11 | NC4 | 104.2 |
5 | CO2 | 29.9 | 12 | C5 | 41.6 |
6 | H2 | 6.2 | 13 | crude | 499209 |
7 | CH4 | 198.1 |
Table 1 Feed composition of preflash tower
Number | Component | Mass flow/ (kg·h-1) | Number | Component | Mass flow/ (kg·h-1) |
---|---|---|---|---|---|
1 | water | 233.3 | 8 | C2H6 | 136.2 |
2 | O2 | 6.4 | 9 | C3H8 | 200.8 |
3 | N2 | 21.2 | 10 | IC4 | 86.3 |
4 | H2S | 2.1 | 11 | NC4 | 104.2 |
5 | CO2 | 29.9 | 12 | C5 | 41.6 |
6 | H2 | 6.2 | 13 | crude | 499209 |
7 | CH4 | 198.1 |
Percent distillate/% | Temperature/℃ |
---|---|
0 | 16.47 |
5 | 92.3 |
10 | 134.1 |
30 | 262.81 |
50 | 374.07 |
70 | 479.99 |
90 | 695.61 |
95 | 806.3 |
100 | 945.75 |
Table 2 TBP distillation data of crude (liquid volume reference, d15.6/15.6 gravity is 0.8523)
Percent distillate/% | Temperature/℃ |
---|---|
0 | 16.47 |
5 | 92.3 |
10 | 134.1 |
30 | 262.81 |
50 | 374.07 |
70 | 479.99 |
90 | 695.61 |
95 | 806.3 |
100 | 945.75 |
Item | Draw stage | Return stage | Flow rate/(kg·h-1) | Return temperature/℃ |
---|---|---|---|---|
pumparound P-1 | 4 | 2 | 163133.1 | 72.2 |
pumparound P-2 | 16 | 14 | 133779.9 | 185 |
pumparound P-3 | 26 | 24 | 160271.6 | 182 |
Table 3 Input parameters of pumparounds
Item | Draw stage | Return stage | Flow rate/(kg·h-1) | Return temperature/℃ |
---|---|---|---|---|
pumparound P-1 | 4 | 2 | 163133.1 | 72.2 |
pumparound P-2 | 16 | 14 | 133779.9 | 185 |
pumparound P-3 | 26 | 24 | 160271.6 | 182 |
Item | Number of stages | Liquid draw stage | Vapor return stage | Bottom product/(kg·h-1) | Stripping steam |
---|---|---|---|---|---|
stripper S-1 | 6 | 13 | 11 | 37741.4 | 385℃,0.35 MPa,425 kg·h-1 |
stripper S-2 | 6 | 38 | 36 | 14853.2 | 385℃,0.35 MPa,168 kg·h-1 |
Table 4 Input parameters of strippers
Item | Number of stages | Liquid draw stage | Vapor return stage | Bottom product/(kg·h-1) | Stripping steam |
---|---|---|---|---|---|
stripper S-1 | 6 | 13 | 11 | 37741.4 | 385℃,0.35 MPa,425 kg·h-1 |
stripper S-2 | 6 | 38 | 36 | 14853.2 | 385℃,0.35 MPa,168 kg·h-1 |
Stage number | IIOM | IOM | Relaxation-SR | ||||||
---|---|---|---|---|---|---|---|---|---|
Temperature/℃ | Liquid flow/(kmol·h-1) | Vapor flow /(kmol·h-1) | Temperature/℃ | Liquid flow/(kmol·h-1) | Vapor flow /(kmol·h-1) | Temperature/℃ | Liquid flow/(kmol·h-1) | Vapor flow /(kmol·h-1) | |
1 | 121.0 | 2066.7 | 800.9 | 121.0 | 2066.7 | 800.9 | 121.4 | 2049.0 | 812.0 |
5 | 158.4 | 995.1 | 1620.6 | 158.4 | 995.1 | 1620.6 | 158.1 | 975.4 | 1616.2 |
10 | 181.8 | 1005.6 | 1526.8 | 181.8 | 1005.6 | 1526.8 | 181.5 | 985.8 | 1513.6 |
15 | 203.5 | 1549.3 | 1484.7 | 203.5 | 1549.3 | 1484.7 | 206.2 | 1520.3 | 1464.1 |
20 | 229.4 | 686.1 | 1410.5 | 229.4 | 686.1 | 1410.5 | 229.4 | 661.1 | 1396.3 |
25 | 275.1 | 1402.6 | 1689.2 | 275.1 | 1402.6 | 1689.2 | 275.8 | 1380.2 | 1673.4 |
30 | 308.0 | 631.2 | 1680.0 | 308.0 | 631.2 | 1680.0 | 308.9 | 627.6 | 1668.6 |
35 | 325.2 | 386.1 | 1530.0 | 325.2 | 386.1 | 1530.0 | 326.5 | 371.8 | 1515.3 |
40 | 345.1 | 590.0 | 291.0 | 345.1 | 590.0 | 291.0 | 344.6 | 581.6 | 287.3 |
41 | 189.8 | 253.8 | 73.9 | 189.8 | 253.8 | 73.9 | 188.9 | 254.3 | 75.2 |
46 | 174.3 | 214.3 | 41.0 | 174.3 | 214.3 | 41.0 | 173.8 | 215.0 | 40.7 |
47 | 335.1 | 50.0 | 20.2 | 335.1 | 50.0 | 20.2 | 335.1 | 48.0 | 21.1 |
53 | 326.4 | 41.1 | 13.0 | 326.4 | 41.1 | 13.0 | 326.1 | 40.3 | 12.8 |
Table 5 Comparison of partial stages result calculated by different algorithms
Stage number | IIOM | IOM | Relaxation-SR | ||||||
---|---|---|---|---|---|---|---|---|---|
Temperature/℃ | Liquid flow/(kmol·h-1) | Vapor flow /(kmol·h-1) | Temperature/℃ | Liquid flow/(kmol·h-1) | Vapor flow /(kmol·h-1) | Temperature/℃ | Liquid flow/(kmol·h-1) | Vapor flow /(kmol·h-1) | |
1 | 121.0 | 2066.7 | 800.9 | 121.0 | 2066.7 | 800.9 | 121.4 | 2049.0 | 812.0 |
5 | 158.4 | 995.1 | 1620.6 | 158.4 | 995.1 | 1620.6 | 158.1 | 975.4 | 1616.2 |
10 | 181.8 | 1005.6 | 1526.8 | 181.8 | 1005.6 | 1526.8 | 181.5 | 985.8 | 1513.6 |
15 | 203.5 | 1549.3 | 1484.7 | 203.5 | 1549.3 | 1484.7 | 206.2 | 1520.3 | 1464.1 |
20 | 229.4 | 686.1 | 1410.5 | 229.4 | 686.1 | 1410.5 | 229.4 | 661.1 | 1396.3 |
25 | 275.1 | 1402.6 | 1689.2 | 275.1 | 1402.6 | 1689.2 | 275.8 | 1380.2 | 1673.4 |
30 | 308.0 | 631.2 | 1680.0 | 308.0 | 631.2 | 1680.0 | 308.9 | 627.6 | 1668.6 |
35 | 325.2 | 386.1 | 1530.0 | 325.2 | 386.1 | 1530.0 | 326.5 | 371.8 | 1515.3 |
40 | 345.1 | 590.0 | 291.0 | 345.1 | 590.0 | 291.0 | 344.6 | 581.6 | 287.3 |
41 | 189.8 | 253.8 | 73.9 | 189.8 | 253.8 | 73.9 | 188.9 | 254.3 | 75.2 |
46 | 174.3 | 214.3 | 41.0 | 174.3 | 214.3 | 41.0 | 173.8 | 215.0 | 40.7 |
47 | 335.1 | 50.0 | 20.2 | 335.1 | 50.0 | 20.2 | 335.1 | 48.0 | 21.1 |
53 | 326.4 | 41.1 | 13.0 | 326.4 | 41.1 | 13.0 | 326.1 | 40.3 | 12.8 |
Item | IIOM | IOM(Russell) | Relaxation(main tower)-SR(strippers) |
---|---|---|---|
condenser | partial vapor liquid,water distillate | partial vapor liquid,water distillate | no condenser |
number of component | 52 | 52 | 52 |
iterates | outer loop iterated 6 times, while inner loop iterated 13.83 times | outer loop iterated 36 times, while inner loop iterated 22.4 times | main tower iterated 83 times, stripper iterated 4 times,tear streams(Wegstein) iterated 7 times |
iterative time/s | 62.2 | 243.4 | 486.1 |
Table 6 Comparison of different method iterating results for atmospheric tower
Item | IIOM | IOM(Russell) | Relaxation(main tower)-SR(strippers) |
---|---|---|---|
condenser | partial vapor liquid,water distillate | partial vapor liquid,water distillate | no condenser |
number of component | 52 | 52 | 52 |
iterates | outer loop iterated 6 times, while inner loop iterated 13.83 times | outer loop iterated 36 times, while inner loop iterated 22.4 times | main tower iterated 83 times, stripper iterated 4 times,tear streams(Wegstein) iterated 7 times |
iterative time/s | 62.2 | 243.4 | 486.1 |
Item | Temperature of top tower/℃ | Temperature of bottom tower/℃ | Distillate of bottom tower/(kg·h-1) |
---|---|---|---|
IIOM | 121 | 345.1 | 288641.8 |
Measured | 122.6 | 346.8 | 287976.6 |
δ/% | -1.31 | -0.49 | 0.23 |
Table 7 Comparison of simulation results
Item | Temperature of top tower/℃ | Temperature of bottom tower/℃ | Distillate of bottom tower/(kg·h-1) |
---|---|---|---|
IIOM | 121 | 345.1 | 288641.8 |
Measured | 122.6 | 346.8 | 287976.6 |
δ/% | -1.31 | -0.49 | 0.23 |
Component | Top tower product composition | Component | Top tower product composition | ||||
---|---|---|---|---|---|---|---|
IIOM | Measured | δ/% | IIOM | Measured | δ/% | ||
water | 0.03625 | 0.03674 | -1.33 | C2H6 | 0.03017 | 0.02989 | 0.94 |
O2 | 0.00050 | 0.00050 | 0.00 | C2H4 | 0.00582 | 0.00581 | 0.17 |
N2 | 0.00138 | 0.00141 | -2.13 | C3H8 | 0.03868 | 0.03752 | 3.09 |
H2S | 0.00129 | 0.00127 | 1.57 | C3H6 | 0.00059 | 0.00057 | 3.51 |
CO2 | 0.02113 | 0.02111 | 0.09 | IC4 | 0.00831 | 0.00836 | -0.60 |
H2 | 0.00166 | 0.00172 | -3.49 | NC4 | 0.01060 | 0.01059 | 0.09 |
CH4 | 0.40942 | 0.41787 | -2.02 | C5 | 0.00090 | 0.00089 | 1.12 |
Table 8 Comparison of conventional components on the top of the tower(mass basis)
Component | Top tower product composition | Component | Top tower product composition | ||||
---|---|---|---|---|---|---|---|
IIOM | Measured | δ/% | IIOM | Measured | δ/% | ||
water | 0.03625 | 0.03674 | -1.33 | C2H6 | 0.03017 | 0.02989 | 0.94 |
O2 | 0.00050 | 0.00050 | 0.00 | C2H4 | 0.00582 | 0.00581 | 0.17 |
N2 | 0.00138 | 0.00141 | -2.13 | C3H8 | 0.03868 | 0.03752 | 3.09 |
H2S | 0.00129 | 0.00127 | 1.57 | C3H6 | 0.00059 | 0.00057 | 3.51 |
CO2 | 0.02113 | 0.02111 | 0.09 | IC4 | 0.00831 | 0.00836 | -0.60 |
H2 | 0.00166 | 0.00172 | -3.49 | NC4 | 0.01060 | 0.01059 | 0.09 |
CH4 | 0.40942 | 0.41787 | -2.02 | C5 | 0.00090 | 0.00089 | 1.12 |
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