CIESC Journal ›› 2025, Vol. 76 ›› Issue (9): 4563-4577.DOI: 10.11949/0438-1157.20250394

• Special Column: Modeling and Simulation in Process Engineering • Previous Articles     Next Articles

Multi-objective optimization of amine-based desulfurization regeneration system integrated with heat pump technology

Xuewen LI1(), Zhihong WANG1(), Yang GAO2, Ming'ou WU3, Wenhao MA1, Renmin TAN1   

  1. 1.School of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, Sichuan, China
    2.Central Sichuan Oil & Gas Field, PetroChina Southwest Oil & Gasfield Company, Suining 629000, Sichuan, China
    3.Natural Gas Research Institute, PetroChina Southwest Oil & Gasfield Company, Chengdu 610000, Sichuan, China
  • Received:2025-04-15 Revised:2025-05-13 Online:2025-10-23 Published:2025-09-25
  • Contact: Zhihong WANG

基于热泵技术的醇胺法脱硫再生系统多目标优化研究

李雪雯1(), 王治红1(), 高阳2, 吴明鸥3, 马文皓1, 谭仁敏1   

  1. 1.西南石油大学化学化工学院,四川 成都 610500
    2.中国石油西南油气田分公司川中油气矿,四川 遂宁 629000
    3.中国石油西南油气田分公司天然气研究院,四川 成都 610000
  • 通讯作者: 王治红
  • 作者简介:李雪雯(2001—),女,硕士研究生,2014432795@qq.com

Abstract:

To tackle high regeneration energy consumption and underused low-grade waste heat in natural gas desulfurization-regeneration units, this study introduces a mechanical vapor recompression (MVR) heat pump distillation retrofit. A closed-loop system is designed where regenerator overhead vapor, pressurized via MVR, directly heats the reboiler, enabling waste heat upgrading and thermal self-balance. Using sensitivity analysis, response surface methodology, and NSGA-Ⅱ, a multi-objective optimization framework targets energy conservation, efficiency, emissions, and costs. Thermodynamic analysis identifies 320.0 kPa compressor pressure as a critical efficiency inflection point where waste heat recovery outweighs compression energy costs. Optimization results show: H2S flow fluctuations ≤0.13%, regeneration energy consumption reduced by 39.86%, and carbon emissions down 30.66%, achieve annual operating cost savings of 546000 CNY, with a static investment payback period of 3 a. This scheme provides an innovative path for the low-carbon transformation of natural gas purification, with both economic and environmental benefits.

Key words: absorption, optimization, steam recompression, response surface methodology, energy saving, genetic algorithm

摘要:

针对天然气净化厂脱硫再生工段现有工艺再生能耗高、塔顶余热利用率低问题,本研究提出了基于机械蒸汽再压缩(MVR)热泵蒸馏改造方案。通过构建吸收-再生模拟系统,创新设计塔顶蒸汽经MVR系统增压升温后供给再沸器热源的闭式循环架构,形成余热品位提升与热能自平衡的新型再生模式。基于能效分析与过程能耗评估,针对压缩机、换热器等建立操作参数优化模型,开发含敏感性分析、响应面法与非支配排序遗传算法(NSGA-Ⅱ)的协同优化框架,构建以节能增效、减排降本为核心的多目标体系,并采用三级递进策略提升能效。结果显示,改造后硫化氢流量波动≤0.13%,再生单元能耗降低39.86%,碳排放强度下降30.66%。该方案为天然气净化低碳改造提供了创新路径,兼具经济与环境效益。

关键词: 吸收, 优化, 蒸汽再压缩, 响应面法, 节能, 遗传算法

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