Characteristics of thermal conductivity and thermal diffusivity of carbon dioxide hydrate

doi:10.11949/j.issn.0438-1157.20160384

CIESC Journal ›› 2016, Vol. 67 ›› Issue (10): 4169-4175.DOI: 10.11949/j.issn.0438-1157.20160384

Previous Articles Next Articles

Characteristics of thermal conductivity and thermal diffusivity of carbon dioxide hydrate

WAN Lihua^1,2, LIANG Deqing^1,2, LI Dongliang^1,2, GUAN Jin'an^1,2

1 Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, Guangdong, China;
2 Key Laboratory of Gas Hydrate, Chinese Academy of Sciences, Guangzhou 510640, Guangdong, China

Received:2016-03-30 Revised:2016-07-25 Online:2016-10-05 Published:2016-10-05
Supported by:
supported by the National Natural Science Foundation of China (51576197, 51106163) and the Knowledge Innovation Program in Chinese Academy of Sciences (KGZD-EW-301).

二氧化碳水合物导热和热扩散特性

万丽华^1,2, 梁德青^1,2, 李栋梁^1,2, 关进安^1,2

1 中国科学院广州能源研究所, 广东广州 510640;
2 中国科学院天然气水合物重点实验室, 广东广州 510640

通讯作者: 梁德青
基金资助:
国家自然科学基金项目（51576197，51106163）；中国科学院知识创新工程（KGZD-EW-301）。

Abstract

Abstract:

Thermal conductivity and thermal diffusivity are two key basic factors of thermal property data that determine gas hydrate resource extraction. In this study, carbon dioxide hydrate sample was formed from a supersaturated carbon dioxide gas solution and layer by layer formed with the equal thickness in the reactor cell lined with fluorine plastics. The thermal conductivity and thermal diffusivity of carbon dioxide hydrate were in-situ measured by means of transient plane source technique. The measurements were performed at 264.68-282.04 K and 1.5-3 MPa. The measurements were also performed during self-preservation effect process at 268.05 K and 0.6 MPa. The characteristics of thermal conductivity and thermal diffusivity of carbon dioxide hydrate were obtained on crystalline state and during self-preservation effect process. The results of this paper can provide basic data and theoretical basis for the development and utilization of natural gas hydrate resources.

Key words: hydrate, thermodynamic properties, heat conduction, thermal diffusivity, transient plane source technique, self-preservation effect

摘要：

热导率和热扩散率是天然气水合物资源开采关键性基础热物性数据，采用反应釜内壁衬有氟塑料材料，低过冷度，让水合物在反应釜内逐层生成的合成方法，获得可直接用于导热测试的二氧化碳水合物样品。采用瞬变平面热源法原位测试了温度264.68～282.04 K、压力1.5～3 MPa二氧化碳水合物热导率、热扩散率，并测试了二氧化碳水合物在268.05 K、0.6 MPa左右发生自保护效应过程中热导率、热扩散率，获得了晶态下和自保护效应过程中的二氧化碳水合物热导率、热扩散率变化特性。测试结果将为天然气水合物资源的开发利用提供基础数据和理论依据。

关键词: 水合物, 热力学性质, 热传导, 热扩散率, 平面热源法, 自保护效应

CLC Number:

TQ028.8

WAN Lihua, LIANG Deqing, LI Dongliang, GUAN Jin'an. Characteristics of thermal conductivity and thermal diffusivity of carbon dioxide hydrate[J]. CIESC Journal, 2016, 67(10): 4169-4175.

万丽华, 梁德青, 李栋梁, 关进安. 二氧化碳水合物导热和热扩散特性[J]. 化工学报, 2016, 67(10): 4169-4175.

References 22

[1]	MAKOGON Y F, HOLDITCH S A, MAKOGON T Y. Natural gas hydrates-a potential energy source for the 21st century[J]. J. Pet. Sci. Eng., 2007, 56:14-31.
[2]	STOLL R D, BRYAN G M. Physical properties of sediments containing gas hydrates[J]. J. Geophys. Res., 1979, 84:1629-1634.
[3]	COOK J G, LEAIST D G. An exploratory study of the thermal conductivity of methane hydrate[J]. Geophys. Res. Lett., 1983, 10:397-399.
[4]	DEMARTIN B J. Laboratory measurements of the thermal conductivity and thermal diffusivity of methane hydrate at simulated in situ conditions[D]. Georgia:Georgia Institute of Technology, 2001.
[5]	WAITE W F, STERN L A, KIRBY S H, et al. Simultaneous determination of thermal conductivity, thermal diffusivity and specific heat in sI methane hydrate[J]. Geophys. J. Int., 2007, 169:767-774.
[6]	HUANG D Z, FAN S S. Thermal conductivity of methane hydrate formed from sodium dodecyl sulfate solution[J]. J. Chem. Eng. Data, 2004, 49:1479-1482.
[7]	ROSENBAUM E J, ENGLISH N J, JOHNSON J K, et al. Thermal conductivity of methane hydrate from experiment and molecular simulation[J]. J. Phys. Chem. B, 2007, 111:13194-13250.
[8]	WAITE W F, GILBERT L Y, WINTERS W J, et al. Estimating thermal diffusivity and specific heat from needle probe thermal conductivity data[J]. Rev. Sci. Instrum., 2006, 77(4):044904-044904-5.
[9]	COOK J G, LEAIST D G. An exploratory study of the thermal conductivity of methane hydrates[J]. Geophys. Res. Lett., 1983, 10:397-399.
[10]	ROSS R G, ANDERSSON P. Clathrate and other solid phases in the tetrahydrofuran-water system:thermal conductivity and heat capacity under pressure[J].Can. J. Chem., 1982, 60:881-892.
[11]	TSE J S, WHITE M A. Origin of glassy crystalline behavior in the thermal properties of clathrate hydrates:a thermal conductivity study of tetrahydrofuran hydrate[J]. J. Phys. Chem., 1988, 92:5006-5011.
[12]	SCHOBER H, ITOH H, KLAPPROTH A, et al. Guest-host coupling and anharmonicity in clathrate hydrates[J]. Eur. Phys. J. E., 2003, 12:41-50.
[13]	TSE J S, KLEIN M L. Dynamical properties of the structure Ⅱ hydrate of krypton[J]. J. Phys. Chem., 1987, 91:5789-5791.
[14]	DHARMA-WARDANA M W C. The thermal conductivity of the ice polymorphs and the ice clathrates[J]. J. Phys. Chem., 1983, 87:4185-4190.
[15]	KIEFTE H, CLOUTER M J, GAGNON R E. Determination of acoustic velocities of clathrate hydrates by brillouin spectroscopy[J]. J. Phys. Chem., 1985, 89:3103-3108.
[16]	TURNER D J, KUMAR P, SLOAN E D. A new technique for hydrate thermal diffusivity measurements[J]. Int. J. Thermophys., 2005, 26(6):1681-1691.
[17]	HUANG D Z, FAN S S. Measuring and modeling thermal conductivity of gas hydrate-bearing sand[J]. J. Geophys. Res., 2005, 110:B01311. doi:10.1029/2004JB003314.
[18]	NIZAEVA I, GALEEV R. In study of cell material influence on the process of hydrate growth of carbon dioxide[C]//Proceedings of the 8th International Conference on Gas Hydrates. Beijing, China, 2014.
[19]	TOHIDI B, ANDERSON R, CLENNELL B, et al. Visual observation of gas hydrate formation and dissociation in synthetic porous media by means of glass micromodels[J]. Geol., 2001, 29:867-870.
[20]	GUSTAFSSON S E, KARAWACKI E, KHAN M N. Transient hotstrip method for simultaneously measuring thermal conductivity and thermal diffusivity of solids and fluids[J]. J. Phys. D:Appl. Phys., 1979, 12:1411-1421.
[21]	GUSTAFSSON S E, KARAWACKI E, CHOHAN M A. Thermal transport studies of electrically conducting materials using the transient hot-strip technique[J]. J. Phys. D:Appl. Phys., 1986, 19:727-735.
[22]	JIANG H, JORDAN K D. Comparison of the properties of xenon, methane and carbon dioxide hydrates from equilibrium and nonequilibrium molecular dynamics simulations[J]. J. Phys. Chem. C, 2010, 114:5555-5564.

Characteristics of thermal conductivity and thermal diffusivity of carbon dioxide hydrate

二氧化碳水合物导热和热扩散特性

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References 22

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Jiahao SONG, Wen WANG. Study on coupling operation characteristics of Stirling engine and high temperature heat pipe [J]. CIESC Journal, 2023, 74(S1): 287-294.
[2]	Yuanchao LIU, Bin GUAN, Jianbin ZHONG, Yifan XU, Xuhao JIANG, Duan LI. Investigation of thermoelectric transport properties of single-layer XSe₂(X=Zr/Hf) [J]. CIESC Journal, 2023, 74(9): 3968-3978.
[3]	Xudong YU, Qi LI, Niancu CHEN, Li DU, Siying REN, Ying ZENG. Phase equilibria and calculation of aqueous ternary system KCl + CaCl₂ + H₂O at 298.2, 323.2, and 348.2 K [J]. CIESC Journal, 2023, 74(8): 3256-3265.
[4]	Zhen LONG, Jinhang WANG, Junjie REN, Yong HE, Xuebing ZHOU, Deqing LIANG. Experimental study on inhibition effect of natural gas hydrate formation by mixing ionic liquid with PVCap [J]. CIESC Journal, 2023, 74(6): 2639-2646.
[5]	Yuanchao LIU, Xuhao JIANG, Ke SHAO, Yifan XU, Jianbin ZHONG, Zhuan LI. Influence of geometrical dimensions and defects on the thermal transport properties of graphyne nanoribbons [J]. CIESC Journal, 2023, 74(6): 2708-2716.
[6]	Zhen LI, Bo ZHANG, Liwei WANG. Development and properties of PEG-EG solid-solid phase change materials [J]. CIESC Journal, 2023, 74(6): 2680-2688.
[7]	Xiaoyu YAO, Jun SHEN, Jian LI, Zhenxing LI, Huifang KANG, Bo TANG, Xueqiang DONG, Maoqiong GONG. Research progress in measurement methods in vapor-liquid critical properties of mixtures [J]. CIESC Journal, 2023, 74(5): 1847-1861.
[8]	Wenchao XU, Zhigao SUN, Cuimin LI, Juan LI, Haifeng HUANG. Effect of surfactant E-1310 on the formation of HCFC-141b hydrate under static conditions [J]. CIESC Journal, 2023, 74(5): 2179-2185.
[9]	Ke CHEN, Li DU, Ying ZENG, Siying REN, Xudong YU. Phase equilibria and calculation of quaternary system LiCl+MgCl₂+CaCl₂+H₂O at 323.2 K [J]. CIESC Journal, 2023, 74(5): 1896-1903.
[10]	Huizhu YANG, Jingling LAN, Yue YANG, Jialin LIANG, Chuanwen LYU, Yonggang ZHU. Experimental study on thermal performance of high power flat heat pipe [J]. CIESC Journal, 2023, 74(4): 1561-1569.
[11]	Mingchuan LI, Shuanshi FAN, Fuhai XU, Huidong LU, Xiaojun LI. Existence and Laplace transform of the solution to Stefan phase change model in thermal dissociation hydrate [J]. CIESC Journal, 2023, 74(4): 1746-1754.
[12]	Xiaodan SU, Ganyu ZHU, Huiquan LI, Guangming ZHENG, Ziheng MENG, Fang LI, Yunrui YANG, Benjun XI, Yu CUI. Optimization of wet process phosphoric acid hemihydrate process and crystallization of gypsum [J]. CIESC Journal, 2023, 74(4): 1805-1817.
[13]	Zhen LONG, Jinhang WANG, Yong HE, Deqing LIANG. Characteristics study on hydrates formation from gas mixture under ionic liquid together with kinetic hydrate inhibitors [J]. CIESC Journal, 2023, 74(4): 1703-1711.
[14]	Han HU, Liang YANG, Chunxiao LI, Daoping LIU. Kinetics of methane storage in the natural tobacco leaching filtrate in the hydrate form [J]. CIESC Journal, 2023, 74(3): 1313-1321.
[15]	Yuanjing MAO, Zhi YANG, Songping MO, Hao GUO, Ying CHEN, Xianglong LUO, Jianyong CHEN, Yingzong LIANG. Estimation of SAFT-VR Mie equation of state parameters and thermodynamic properties of C₆—C₁₀ alcohols [J]. CIESC Journal, 2023, 74(3): 1033-1041.