Research on development of composite phase change humidity-control material in buildings

doi:10.11949/j.issn.0438-1157.20180878

Abstract

Abstract:

Composite phase change humidity-control material is a new type of building material developed in the recent years. Because of its unique property which could adjust the temperature and humidity of the indoor environment by absorbing or releasing the heat and moisture automatically during the phase change process, it has become a research spot in the field of building materials. The applications of composite phase change humidity-control material in buildings could maintain the comfortable indoor temperature and humidity. It not only helps to improve people's work efficiency and health, but also saves energy and reduces carbon dioxide emissions. This paper reviewed the preparative techniques, main hydrothermal properties, the theoretical model and the application effects in buildings of the composite phase change humidity-control material. Then it points out the main issues needed to be addressed in the future development. It is believed that this paper could propose new ideas for the researchers working in the field of building materials in China.

Key words: phase change materials, composite phase change humidity-control material, energy efficiency in buildings

摘要：

相变控温调湿复合材料是近来开发的新型建筑材料，由于这种材料具有发生相变时，自动吸收或者释放热量和湿气，调节室内环境空气的温度和相对湿度的特殊性能，因此，控温调湿材料的开发和在建筑中的应用研究，已经成为国内外建筑和材料领域的研究热点。相变控温调湿复合材料应用在建筑中，可以保持室内舒适的温度和湿度，不仅有利于提高人们的工作效率和身体健康，而且节约能源、减少二氧化碳排放，保护环境。综述了各种控温调湿材料的制备技术以及主要的热湿性能，总结了控温调湿材料的热湿理论模型，概述了控温调湿材料在建筑中的应用成效，提出了未来发展中需要解决的主要问题。对国内外控温调湿相变材料的全面综述和分析将为我国的建筑和材料领域的设计和研究人员提出新的思考。

关键词: 相变材料, 控温调湿材料, 建筑节能

CLC Number:

TU599

CUI Yanqi. Research on development of composite phase change humidity-control material in buildings[J]. CIESC Journal, 2018, 69(S1): 1-7.

崔艳琦. 相变控温调湿建筑复合材料的研究进展[J]. 化工学报, 2018, 69(S1): 1-7.

References 73

[1]	崔艳琦.相变材料热性能及其在室内被动式储能系统的简易计算[J].储能科学与技术, 2017, 6(2):302-306. CUI Y Q. Thermal properties of phase change materials (PCM) and their concise calculations for passive storage[J]. Energy Storage Science and Technology, 2017, 6(2):302-306.
[2]	龚旎. 医院建筑热湿环境舒适与健康影响研究[D]. 重庆:重庆大学, 2011. GONG N. The impacts of indoor thermal parameters on human comfort and health in hospital buildings[D].Chongqing:Chongqing University, 2011.
[3]	REINIKAINEN L M, JAAKKOLA J K. Significance of humidity and temperature on skin and upper airway symptoms[J].Indoor Air, 2004, 13(4):344-352.
[4]	FANG L, CLAUSEN G, FANGER P O. Impact of temperature and humidity on the perception of indoor air quality[J]. Indoor Air, 2004, 8(2):80-90.
[5]	HUYNH C K. Building energy saving techniques and indoor air quality:a dilemma[J].International Journal of Ventilation, 2010, 9(1):93-98.
[6]	ARUNDEL A V, STERLING E M, BIGGIN J H, et al. Indirect health effects of relative humidity in indoor environments[J]. Environmental Health Perspectives, 1986, 65:351-361.
[7]	DENG A Z, LI S B, ZHANG C L, et al. Research on lightweight PCM thermal-storing wall-material[J]. Journal of Building Materials, 2008, 11(5):541-544.
[8]	SONG M J, NIU F X, MAO N, et al. Review on building energy performance improvement using phase change materials[J]. Energy and Buildings, 2017, 158:776-793.
[9]	AKEIBER H J, NEJAT P, MAJID M Z A, et al. A review on phase change material (PCM) for sustainable passive cooling in building envelopes[J]. Renewable and Sustainable Energy Reviews, 2016, 60:1470-1497.
[10]	MAO N, SONG M J, PAN D M, et al. Numerical investigations on the effects of envelope thermal loads on energy utilization potential and thermal non-uniformity in sleeping environments[J]. Building and Environment, 2017, 124:232-244.
[11]	XIANG Y T, ZHOU G B. Thermal performance of a window-based cooling unit using phase change materials combined with night ventilation[J]. Energy and Buildings, 2015, 108:267-278
[12]	PARAMESHWARAN R, KALAISELVAM S. Energy conservative air conditioning system using silver nano-based PCM thermal storage for modern buildings[J]. Energy and Buildings, 2014, 69:202-212.
[13]	SHARIFI N P, SHAIKH A N, SAKULICH A R. Application of phase change materials in gypsum boards to meet building energy conservation goals[J].Energy and Buildings, 2017, 138:455-467.
[14]	MAO N, HAO J Y, PAN D M, et al. Investigations on thermal environment in residential buildings with PCM embedded in external wall[J].Energy Procedia, 2017, 42:1888-1895.
[15]	MAO N, SONG M J, DENG S M, et al. Experimental and numerical study on air flow and moisture transport in sleeping environments with a task/ambient air conditioning (TAC) system[J]. Energy and Buildings, 2016, 133:596-604.
[16]	LIN W Y, M Z J, SOHEL M I, et al. Development and evaluation of a ceiling ventilation system enhanced by solar photovoltaic thermal collectors and phase change materials[J]. Energy Conversion and Management, 2014, 88:218-230.
[17]	SAFFARI M, PISELLI C, GRACIA A D, et al. Thermal stress reduction in cool roof membranes using phase change materials (PCM)[J]. Energy and Buildings, 2018, 158:1097-1105.
[18]	LEI J W, YANG J L, YANG E H. Energy performance of building envelopes integrated with phase change materials for cooling load reduction in tropical Singapore[J]. Applied Energy, 2016, 162:207-217.
[19]	ELARGA H, FANTUCCI S, SERRA V, et al. Experimental and numerical analyses on thermal performance of different typologies of PCMs integrated in the roof space[J]. Energy and Buildings, 2017, 150:546-557.
[20]	LOTFI D, ERREBAI F B, AMARA M. Effect of PCM in improving the thermal comfort in buildings[J]. Energy Procedia, 2017, 107:157-161.
[21]	FIGUEIREDO A, VICENTE R, LAPA J, et al. Indoor thermal comfort assessment using different constructive solutions incorporating PCM[J]. Applied Energy, 2017, 208:1208-1221.
[22]	张睿航, 牛润萍.相变蓄能材料在建筑节能方面的应用研究进展[J].材料导报, 2016, 30(S1):383-386. ZHANG R H, NIU R P. Application research progress of phase change storage materials in building energy conservation[J]. Materials Review, 2016, 30(S1):383-386.
[23]	黄雪, 崔英德, 尹国强, 等.月桂酸-膨胀石墨复合相变材料的制备及性能[J].化工学报, 2015, 66(S1):370-374. HUANG X, CUI Y D, YIN G Q, et al. Preparation and performance of lauric acid-expanded graphite composite phase change materials[J]. CIESC Journal, 2015, 66(S1):370-374.
[24]	SAFFARI M, GRACIA A D, USHAK S, et al. Passive cooling of buildings with phase change materials using whole-building energy simulation tools:a review[J].Renewable and Sustainable Energy Reviews, 2017, 80:1239-1255.
[25]	KÜNZEL H M. Simultaneous heat and moisture transport in building components. One-and two-dimensional calculation using simple parameters[D]. Stuttgart:Fraunhofer IRB Verlag, 1995.
[26]	VRIES D A D. The theory of heat and moisture transfer in porous media revisited[J].International Journal of Heat and Mass Transfer, 1987, 30(7):1343-1350.
[27]	刘炳成. 土壤中的相变传热传质研究及植物根系生长的仿真模拟[D].武汉:华中科技大学, 2004. LIU B C. Study on the heat and mass transfer in soil with phase change and simulation of growing of plant roots system[D]. Wuhan:Huazhong University of Science and Technology, 2004.
[28]	刘希臣. 地下水电站热湿环境形成机理及节能调控策略[D].重庆:重庆大学, 2014. LIU X C. Formation mechanism of heat and moisture environment in underground hydropower station and its energy-saving[D]. Chongqing:Chongqing University, 2014.
[29]	郭兴国, 陈友明.热湿气候地区多层墙体的热湿性能分析[J].湖南大学学报(自然科学版), 2008, (8):1-4. GUO X G, CHEN Y M. Analysis of the hygrothermal performance of multilayer wall exposed to hot and humid climate[J]. Journal of Hunan University (Natural Sciences), 2008, (8):1-4.
[30]	DARKWA K, O'CALLAGHAN P W. Simulation of phase change drywalls in a passive solar building[J]. Applied Thermal Engineering, 2006, 26(8/9):853-858.
[31]	张浩. 建筑相变储湿材料的制备、热湿性能及应用模拟研究[D].西安:西安建筑科技大学, 2016. ZHANG H. Preparation, thermal-humidity property and application simulation of phase change and humidity storage materials[D].Xi'an:Xi'an University of Architecture and Technology, 2016.
[32]	陈智. 复合调热调湿材料的理论、制备及性能研究[D].南京:南京大学, 2017. CHEN Z. Study of the theory, preparation and performance of composite phase change humidity control materials[D].Nanjing:Nanjing University, 2017.
[33]	黄子硕, 于航, 张美玲.建筑调湿材料吸放湿速度变化规律[J].同济大学学报(自然科学版), 2014, 42(2):310-314. HUANG Z S, YU H, ZHANG M L. Humidity-control materials and their humidity absorption and desorption rate variation[J]. Journal of Tongji University (Natural Science), 2014, 42(2):310-314.
[34]	张明杰, 秦孟昊, 陈智.复合相变调湿材料对室内热湿环境影响的研究[J].建筑科学, 2016, 32(12):72-79. ZHANG M J, QIN M H, CHEN Z. Study on impact of composite phase change moisture-controlled materials on indoor thermal and humid[J]. Building Science, 2016, 32(12):72-79.
[35]	HO C J, LIU K C, YAN W M. Melting processes of phase change materials in an enclosure with a free-moving ceiling:an experimental and numerical study[J]. International Journal of Heat and Mass Transfer, 2015, 86:780-786.
[36]	WEINLÄDER H, KÖRNER W, STRIEDER B. A ventilated cooling ceiling with integrated latent heat storage-monitoring results[J]. Energy and Buildings, 2014, 82:65-72.
[37]	TZIVANIDIS C, ANTONOPOULOS K A, KRAVVARITIS E D. Parametric analysis of space cooling systems based on night ceiling cooling with PCM-embedded piping[J]. International Journal of Energy Research, 2012, 36(1):18-35.
[38]	BELMONTE J F, EGUÍA P, MOLINA A E, et al. Thermal simulation and system optimization of a chilled ceiling coupled with a floor containing a phase change material (PCM)[J]. Sustainable Cities and Society, 2015, 14(1):154-170.
[39]	崔艳琦, 龚方方, 张燕妮, 等.相变材料(PCM)在建筑节能中的应用研究进展[J].新型建筑材料, 2016, 43(8):26-29. CUI Y Q, GONG F F, ZHANG Y N, et al. Development of study on the applications of phase change material (PCM) for energy saving in building[J]. New Building Materials, 2016, 43(8):26-29.
[40]	毕胜山, 史琳, 王磊.纳米TiO2颗粒在制冷工质中的分散[J].过程工程学报, 2007, (3):541-545. BI S S, SHI L, WANG L. Dispersion behavior of TiO2 nanoparticles in refrigerant[J]. The Chinese Journal of Process Engineering, 2007, (3):541-545.
[41]	NGUYEN C T, ROY G, GAUTHIER C, et al. Heat transfer enhancement using Al2O3-water nanofluid for an electronic liquid cooling system[J].Applied Thermal Engineering, 2007, 27(8/9):1501-1506.
[42]	尚建丽, 张浩, 董莉.石膏基双壳微纳米相变胶囊复合材料制备及调温调湿性能研究[J].太阳能学报, 2016, 37(6):1481-1487. SHANG J L, ZHANG H, DONG L. Preparation of composite material of gypsum-based double-shell micro-nano phase change capsules and performance research of temperature-humidity control[J]. Acta Energiae Solaris Sinica, 2016, 37(6):1481-1487.
[43]	邓妮. 多孔矿物基复合调湿材料的制备及性能[D].杭州:浙江大学, 2014. DENG N. Preparation and performance of composite humidity-control materials based on porous minerals[D].Hangzhou:Zhejiang University, 2014.
[44]	邓妮, 武双磊, 陈胡星.调湿材料的研究概述[J].材料导报, 2013, 27(S2):368-371. DENG N, WU S L, CHEN H X. Overview on research of humidity-controlling materials[J]. Materials Review, 2013, 27(S2):368-371.
[45]	邓妮, 武双磊, 陈胡星.氯化钙改性硅藻土的调湿性能[J].材料科学与工程学报, 2014, 32(4):493-498. DENG N, WU S L, CHEN H X. Humidity-control performance of diatomite modified by calcium chloride[J]. Journal of Materials Science and Engineering, 2014, 32(4):493-498.
[46]	郑佳宜, 陈振乾.硅藻土基调湿建筑材料的应用仿真模拟[J].东南大学学报(自然科学版), 2013, 43(4):840-844. ZHENG J Y, CHEN Z Q. Application analogue simulation of diatomite-based humidity control building material[J]. Journal of Southeast University (Natural Science Edition), 2013, 43(4):840-844.
[47]	尚建丽, 陈丹, 武斌.生物质多孔相变材料的制备及调温调湿性能研究[J].化工新型材料, 2015, 43(1):107-109, 113. SHANG J L, CHEN D, WU B. Preparation of the biomass porous phase change materials and its thermal and moisture properties[J]. New Chemical Materials, 2015, 43(1):107-109, 113.
[48]	马明明, 张伟.硅藻土基调湿建筑材料的制备与表征[J].新型建筑材料, 2017, 44(12):86-88, 93. MA M M, ZHANG W. Preparation and characterization of diatomite humidity-controlling building material[J]. New Building Materials, 2017, 44(12):86-88, 93.
[49]	洪苑秀, 周斌强, 郭立, 等.海泡石水热合成C-S-H增强调湿建筑材料[J].新型建筑材料, 2015, 42(10):17-21, 28. HONG Y X, ZHOU B Q, GUO L, et al. Hydrothermal synthesis of sepiolite into strengthened and humidity-regulating building material[J]. New Building Materials, 2015, 42(10):17-21, 28.
[50]	LIN H L, EAKASIT S, et al. Synthesis and characterization of pH-and salt-sensitive hydrogel based on chemically modified poultry feather protein isolate[J]. Journal of Applied Polymer Science, 2010, 116(1):602-609.
[51]	田野. 插层法制备相变调温调湿材料及性能试验研究[D].西安:西安建筑科技大学, 2017. TIAN Y. Preparation of phase change temperature and humidity adjusting material and performance test research[D]. Xi'an:Xi'an University of Architecture and Technology, 2017.
[52]	ZHANG B N, CUI Y D, YIN G Q, et al. Synthesis and swelling properties of hydrolyzed cottonseed protein composite superabsorbent hydrogel[J]. International Journal of Polymeric Materials and Polymeric Biomaterials, 2010, 59(12):1018-1032.
[53]	尚建丽, 董莉.双壳微纳胶囊的制备及热湿性能的试验研究[J].建筑材料学报, 2015, 18(3):428-432. SHANG J L, DONG L. Preparation of double-shell micronano-capsule and its thermal and moisture performance[J]. Journal of Building Materials, 2015, 18(3):428-432.
[54]	SHI X, MEMON S A, TANG W C, et al. Experimental assessment of position of macro encapsulated phase change material in concrete walls on indoor temperatures and humidity levels[J].Energy and Buildings, 2014, 71:80-87.
[55]	CHEN Z, QIN M H. Preparation and hygrothermal properties of composite phase change humidity control materials[J].Applied Thermal Engineering, 2016, 98:1150-1157.
[56]	BELEN Z, JOSE M M, LUISA F C, et al, Review on thermal energy storage with phase change:materials, heat transfer analysis and applications[J].Applied Thermal Engineering, 2003, 23:251-283.
[57]	ZHANG M, MEDINA M, KING J B. Development of a thermally enhanced frame wall with phase-change materials for on-peak air conditioning demand reduction and energy savings in residential buildings[J]. International Journal of Energy Research, 2005, 29:795-809.
[58]	FARID M, KHUDHAIR A M, RAZACK S A K, et al. A review on phase change energy storage:materials and applications[J].Energy Conversion and Management, 2004, 45(9/10):1597-1615.
[59]	YAN Q Y, LIANG C, ZHANG L. Experimental study on the thermal storage performance and preparation of paraffin mixtures used in the phase change wall[J]. Solar Energy Materials and Solar Cells, 2008, 92:1526-1532.
[60]	LI X L, ZHANG L, WANG S Q, et al. Inorganic phase change materials in building energy saving[J]. Applied Mechanics and Materials, 2011, 71-78:2606-2609.
[61]	PASUPATHY A, VELRAJ R. Effect of double layer phase change material in building roof for year round thermal management[J].Energy and Buildings, 2008, 40(3):193-203.
[62]	BUDDHI D, MISHRA H S, SHARMA A. Thermal performance studies of a test cell having a PCM-window in south direction[C]//IEA, ECESIA Annex. Indore, India, 2003:54-58.
[63]	PÉREZ-LOMBARD L, ORTIZ J, POUT C. A review on buildings energy consumption information[J].Energy and Buildings, 2008, 40(3):394-398.
[64]	NAGANO K, TAKEDA S, MOCHIDA T, et al. Study of a floor supply air conditioning system using granular phase change material to augment building mass thermal storage-heat response in small scale experiments[J]. Energy and Buildings, 2006, 38(5):436-446.
[65]	ZHOU G B, YANG Y P, XU H. Energy performance of a hybrid space-cooling system in an office building using SSPCM thermal storage and night ventilation[J]. Solar Energy, 2011, 85(3):477-485.
[66]	CUI Y Q. Investigation of phase change material passive cooling system for buildings[D].Nottingham:University of Nottingham, 2014.
[67]	ARKAR C, VIDRIH B, MEDVED S. Efficiency of free cooling using latent heat storage integrated into the ventilation system of a low energy building[J].International Journal of Refrigeration, 2007, 30(1):134-143.
[68]	KASAEIAN A, BAHRAMI L, POURFAYAZ F, et al. Experimental studies on the applications of PCMs and nano-PCMs in buildings:a critical review[J].Energy and Buildings, 2017, 154:96-112.
[69]	谢全安, 郑丹星, 武向红.Na2SO4·10H2O共晶盐的热化学研究[J].太阳能学报, 2002, (1):70-75. XIE Q A, ZHENG D X, WU X H. Thermochemical study on eutectic composed by Na2SO4·10H2O[J]. Acta Energiae Solaris Sinica, 2002, (1):70-75.
[70]	张浩, 黄新杰, 刘秀玉.棕榈醇-棕榈酸-月桂酸/SiO2复合相变调湿材料的制备[J].材料研究学报, 2015, 29(11):867-873. ZHANG H, HUANG X J, LIU X Y. Preparation of hexadecanol-palmitic acid-lauric acid/SiO2 composite as phase change material for humidity control[J]. Chinese Journal of Materials Research, 2015, 29(11):867-873.
[71]	SOLEYMAN R, BARDAJEE G, POURJAVADI A, et al. Hydrolyzed salep/gelatin-g-polyacrylamide as a novel micro/nano-porous superabsorbent hydrogel:synthesis, optimization and investigation on swelling behavior[J]. Scientia Iranica, 2015, 22:903-910.
[72]	SOUAYFANE F, FARDOUN F, BIWOLE P. Phase change materials (PCM) for cooling applications in buildings:a review[J].Energy and Buildings, 2016, 129:396-431.
[73]	杜雅琴. 轻质多孔地聚物基相变调湿材料性能试验研究[D].西安:西安建筑科技大学, 2017. DU Y Q. Performance test research of lightweight porous geological polymer-based phase-wet material[D]. Xi'an:Xi'an University of Architecture and Technology, 2017.