Development of ion-recognition-responsive smart materials based on crown ethers

doi:10.3969/j.issn.0438-1157.2013.01.028

CIESC Journal ›› 2013, Vol. 64 ›› Issue (1): 261-267.DOI: 10.3969/j.issn.0438-1157.2013.01.028

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Development of ion-recognition-responsive smart materials based on crown ethers

JU Xiaojie, XIE Rui, WANG Wei, CHU Liangyin

School of Chemical Engineering, Sichuan University, Chengdu 610065, Sichuan, China

Received:2012-08-06 Revised:2012-09-18 Online:2013-01-05 Published:2013-01-05
Supported by:
supported by the National Basic Research Program of China (2009CB623407),the National Natural Science Foundation of China (20906064) and the Foundation for the Author of National Excellent Doctoral Dissertation of China (201163).

基于冠醚的离子识别响应型智能材料研究新进展

巨晓洁, 谢锐, 汪伟, 褚良银

四川大学化学工程学院,四川成都 610065

通讯作者: 褚良银
作者简介:巨晓洁(1980—),女,博士,副教授。
基金资助:
国家重点基础研究发展计划项目(2009CB623407);国家自然科学基金项目(20906064);全国优秀博士学位论文作者专项资金资助项目(201163)。

Abstract

Abstract: Metal ions play an important role in life activities, but some heavy metal ions (such as Pb²⁺ and Hg²⁺) have high toxicity to the organisms even at alow concentration.It is of important theoretical significance and great practical interest to study smart materials with metal ion-recognition properties. Crown ethers have remarkable recognition ability towards specific mental ions.A series of ion-recognition-responsive smart materials composed of crown ethers and responsive poly (N-isopropylacrylamide) (PNIPAM) polymer have been developed.The development of ion-recognition-responsive smart materials based on 18-crown-6 and 15-crown-5 is reviewed.At present, the ion-recognition-responsive smart materials are still at the basic research stage and need further intensive study and development.

Key words: smart materials, ion-recognition, responsive property

摘要： 金属离子对生物体的生命活动起着核心的作用,而一些重金属离子(如Pb²⁺、Hg²⁺)在很低浓度时就对生物具有极强的毒性;因此,研究具有金属离子识别特性的智能材料具有重要的理论价值和实用意义。冠醚具有选择性地络合金属离子的能力,研究者们将冠醚的离子识别特性与聚(N-异丙基丙烯酰胺)的相变行为特性相结合制备了一系列离子识别响应型智能材料。综述了近年来基于18-冠-6和15-冠-5两种冠醚分子的离子识别响应型智能材料的研究新进展。目前,基于冠醚的离子识别响应型智能材料仍多处于基础研究阶段,还需要进一步系统深入研究和开发完善。

关键词: 智能材料, 离子识别, 响应特性

CLC Number:

TQ317

JU Xiaojie, XIE Rui, WANG Wei, CHU Liangyin. Development of ion-recognition-responsive smart materials based on crown ethers[J]. CIESC Journal, 2013, 64(1): 261-267.

巨晓洁, 谢锐, 汪伟, 褚良银. 基于冠醚的离子识别响应型智能材料研究新进展[J]. 化工学报, 2013, 64(1): 261-267.

References 37

[1]	Chu L Y, Xie R, Ju X J.Stimuli-responsive membranes:smart tools for controllable mass-transfer and separation processes[J].Chinese J.Chem.Eng., 2011,19(6):891-903
[2]	Chu Liangyin(褚良银), Xie Rui(谢锐), Ju Xiaojie(巨晓洁).Progress of development of smart membrane materials[J].Chemical Industry and Engineering Progress(化工进展), 2011,30(1):167-171
[3]	Liu Yong(刘永), Cui Yingde(崔英德), Yin Guoqiang(尹国强), Li Xinming(黎新明), Chen Xunjun(陈循军), Zhang Buning(张步宁).Intelligent hydrogels for controlled release of drug[J].Chemical Industry and Engineering Progress(化工进展), 2008,27(10):1593-1596
[4]	Rolfs A, Hediger M A.Metal ion transporters in mammals:structure, function and pathological implications[J].J.Physiol-London, 1999,518(1):1-12
[5]	Schnabl J, Sigel R K O.Controlling ribozyme activity by metal ions[J].Curr.Opin.Chem.Biol., 2010,14(2):269-275
[6]	Catterall W A.Structure and function of voltage-sensitive ion channels[J].Science, 1988,242(4875):50-61
[7]	Hutchinson T C, Meema K M.Lead, Mercury,Cadmium, and Arsenic in the Environment[M].New York:John Wiley & Sons Ltd., 1988
[8]	Vallee B L, Ulmer D D.Biochemical effects of mercury, cadmium, and lead[J].Annu.Rev.Biochem., 1972,41(10):91-128
[9]	Godwin H A.The biological chemistry of lead[J].Curr.Opin.Chem.Biol., 2001,5(2):223-227
[10]	Pedersen C J.Cyclic polyethers and their complexes with metal salts[J].J.Am.Chem.Soc., 1967,89(10):2495-2496
[11]	Pedersen C J.Cyclic polyethers and their complexes with metal salts[J].J.Am.Chem.Soc., 1967,89(26):7017-7036
[12]	Liu Yu(刘育), You Changcheng(尤长城), Zhang Hengyi(张衡益).Supramolecular Chemistry—Molecular Recognition and Assembly of Synthetic Receptors(超分子化学——合成受体的分子识别与组装)[M].Tianjin:Nankai University Press, 2001:38-40
[13]	Izatt R M, Pawlak K, Bradshaw J S, Bruening R L. Thermodynamic and kinetic data for macrocycle interaction with cations and anions[J].Chem.Rev., 1991,91(8):1721-2085
[14]	Guo X J, Zhu Y D, Wei M J, Wu X M, Lu L H, Lu X H. Theoretical study of hydration effects on the selectivity of 18-crown-6 between K+ and Na+[J].Chinese J. Chem. Eng., 2011,19(2):212-216
[15]	Lin S Y, Liu S W, Lin C M, Chen C H.Recognition of potassium ion in water by 15-crown-5 functionalized gold nanoparticles[J].Anal.Chem., 2002,74(2):330-335
[16]	Yamauchi A, Hayashita T, Nishizawa S, Watanabe M, Teramae N.Benzo-15-crown-5 fluoroionophore/γ-cyclodextrin complex with remarkably high potassium ion sensitivity and selectivity in water[J].J.Am.Chem.Soc., 1999,121(10):2319-2320
[17]	Xia W S, Schmehl R H, Li C J.A highly selective fluorescent chemosensor for K+ from a bis-15-crown-5 derivative[J].J.Am.Chem.Soc., 1999,121(23):5599-5600
[18]	Irie M, Misumi Y, Tanaka T.Stimuli-responsive polymers:chemical induced reversible phase separation of an aqueous solution of poly(N-isopropylacrylamide)with pendent crown ether groups[J].Polymer, 1993,34(21):4531-4535
[19]	Zhang B, Ju X J, Xie R, Liu Z, Pi S W, Chu L Y. Comprehensive effects of metal ions on responsive characteristics of P(NIPAM-co-B18C6Am)[J].J. Phys. Chem. B, 2012,116(18):5527-5536
[20]	Mi P, Chu L Y, Ju X J, Niu C H.A smart polymer with ion-induced negative shift of the lower critical solution temperature for phase-transition[J].Macromol.Rapid Comm., 2008,29(1):27-32
[21]	Chen Yongchao(陈永朝), Xie Rui(谢锐), Li Pengfei(李鹏飞), Ju Xiaojie(巨晓洁), Chu Liangyin(褚良银).Gating characteristics of dual pH-/thermo-responsive membranes with grafted diblock copolymers[J].CIESC Journal(化工学报), 2010,61(7):1866-1872
[22]	Xie Rui(谢锐), Chu Liangyin(褚良银), Chen Wenmei(陈文梅), Xiao Wen(肖文), Wang Haidong(王海东), Qu Jianbo(曲剑波), Wang Guangjin(王广金).Micro structures and thermo-responsive characteristics of poly(N-isopropylacrylamide)-grafted polycarbonate track-etched membranes prepared by plasma-graft pore-filling polymerization[J].Journal of Chemical Industry and Engineering(China)(化工学报), 2005,56(11):2212-2218
[23]	Yamaguchi T, Ito T, Sato T, Shinbo T, Nakao S. Development of a fast response molecular recognition ion gating membrane[J].J.Am.Chem.Soc., 1999,121(16):4078-4079
[24]	Ito T, Hioki T, Yamaguchi T, Shinbo T, Nakao S, Kimura S.Development of a molecular recognition ion gating membrane and estimation of its pore size control[J].J.Am.Chem.Soc., 2002,124(26):7840-7846
[25]	Ito T, Sato Y, Yamaguchi T, Nakao S.Response mechanism of a molecular recognition ion gating membrane[J].Macromolecules, 2004,37(9):3407-3414
[26]	Ito T, Yamaguchi T.Controlled release of model drugs through a molecular recognition ion gating membrane in response to a specific ion signal[J].Langmuir, 2006,22(8):3945-3949
[27]	Okajima S, Sakai Y, Yamaguchi T.Development of a regenerable cell culture system that senses and releases dead cells[J].Langmuir, 2005,21(9):4043-4049
[28]	Okajima S, Yamaguchi T, Sakai Y, Nakao S.Regulation of cell adhesion using a signal-responsive membrane substrate[J].Biotechnol.Bioeng., 2005,91(2):237-243
[29]	Chu L Y, Yamaguchi T, Nakao S.A molecular-recognition microcapsule for environmental stimuli-responsive controlled release[J].Adv.Mater., 2002,14(5):386-389
[30]	Liu Z, Luo F, Ju X J, Xie R, Luo T, Sun Y M, Chu L Y. Positively K+-responsive membranes with functional gates driven by host-guest molecular recognition[J].Adv.Funct.Mater., 2012, 22(22):4742-4750
[31]	Ju X J, Chu L Y, Liu L, Mi P, Lee Y M.A novel thermo-responsive hydrogel with ion-recognition property through supramolecular host-guest complexation[J].J. Phys. Chem.B, 2008,112(4):1112-1118
[32]	Ju X J, Zhang S B, Zhou M Y, Xie R, Yang L, Chu L Y.Novel heavy-metal adsorption material:ion-recognition P(NIPAM-co- BCAm)hydrogels for removal of lead(Ⅱ)ions[J].J.Hazard.Mater., 2009,167(1/2/3):114-118
[33]	Mi P, Ju X J, Xie R, Wu H G, Ma J, Chu L Y.A novel stimuli-responsive hydrogel for K+-induced controlled-release[J].Polymer, 2010,51(7):1648-1653
[34]	Wu H G, Ju X J, Xie R, Liu Y M, Deng J G, Niu C H, Chu L Y.A novel ion-imprinted hydrogel for recognition of potassium ions with rapid response[J].Polym. Advan. Technol., 2011,22(9):1389-1394
[35]	Ju X J, Liu L, Xie R, Niu C H, Chu L Y.Dual thermo-responsive and ion-recognizable monodisperse microspheres[J].Polymer, 2009,50(3):922-929
[36]	Pi S W, Ju X J, Wu H G, Xie R, Chu L Y.Smart responsive microcapsules capable of recognizing heavy metal ions[J].J.Colloid Interf.Sci., 2010,349(2):512-518
[37]	Liu Z, Liu L, Ju X J, Xie R, Zhang B, Chu L Y.K+-recognition capsules with squirting release mechanisms[J].Chem.Commun., 2011,47(45):12283-12285

Development of ion-recognition-responsive smart materials based on crown ethers

基于冠醚的离子识别响应型智能材料研究新进展

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