Analysis on polycyclic aromatic hydrocarbons in pyrolysis oil from municipal wastewater sewage sludge

doi:10.3969/j.issn.0438-1157.2013.06.043

CIESC Journal ›› 2013, Vol. 64 ›› Issue (6): 2227-2231.DOI: 10.3969/j.issn.0438-1157.2013.06.043

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Analysis on polycyclic aromatic hydrocarbons in pyrolysis oil from municipal wastewater sewage sludge

HU Yanjun, GUAN Zhichao, ZHENG Xiaoyan

Institute of Energy and Power Engineering, Zhejiang University of Technology, Hangzhou 310023, Zhejiang, China

Received:2012-11-29 Revised:2013-01-15 Online:2013-06-05 Published:2013-06-05
Supported by:
supported by the National Natural Science Foundation of China(51008279)and Zhejiang Provincial Natural Science Foundation(Y5100258).

污水污泥裂解油中多环芳烃的分析

胡艳军, 管志超, 郑小艳

浙江工业大学能源与动力工程研究所,浙江杭州 310023

通讯作者: 胡艳军(1979—),女,博士,副教授。
作者简介:胡艳军(1979—),女,博士,副教授。
基金资助:
国家自然科学基金项目(51008279);浙江省自然科学基金项目(Y5100258)。

Abstract

Abstract: Pretreatment of oil samples from pyrolysis of wastewater sewage sludge was carried out using combination route of extraction, enrichment and purification for determining PAHs.Quantitative and qualitative analysis of PAHs were then conducted by GC-MS.16 kinds of PAHs were detected out in sludge pyrolysis oil.The recovery ratio of PAHs is above 80% except for naphthalene on the basis of the constructed pretreatment method and GC-MS analysis condition.Finally, distribution of PAHs was also investigated using experimental tests in three sludge pyrolysis oil samples produced from various ending temperature and heating rate.The total content of the target PAHs in three oil samples is from 2.3 mg·kg^-1 to 47.8 mg·kg^-1.In addition, the ending temperature and heating rate have evident influences on PAHs concentrations in sludge pyrolysis oil.

Key words: wastewater sewage sludge, pyrolysis oil, polycyclic aromatic hydrocarbons, recovery ratio

关键词: 污水污泥, 裂解油, 多环芳烃, 回收率

CLC Number:

HU Yanjun, GUAN Zhichao, ZHENG Xiaoyan. Analysis on polycyclic aromatic hydrocarbons in pyrolysis oil from municipal wastewater sewage sludge[J]. CIESC Journal, 2013, 64(6): 2227-2231.

胡艳军, 管志超, 郑小艳. 污水污泥裂解油中多环芳烃的分析[J]. 化工学报, 2013, 64(6): 2227-2231.

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Analysis on polycyclic aromatic hydrocarbons in pyrolysis oil from municipal wastewater sewage sludge

污水污泥裂解油中多环芳烃的分析

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