A review for research on thermodynamics and kinetics of carbon dioxide absorption with organic amines

doi:10.3969/j.issn.0438-1157.2014.01.002

Abstract

Abstract: Carbon capture and storage technology is aimed to solve the problem of global warming mainly caused by increase of atmospheric CO₂ level. Amine absorption method, as the most mature technology with economic and technical aspects, is an important technology for CO₂ capture. In this review, from the start point of basic reaction mechanism, research works and results on the thermodynamic and kinetic properties of CO₂ absorption with amines are summarized, and relationship of CO₂ absorption solubility and reaction rates with molecular structures of different types of amines are described. Finally some research directions for thermodynamics and kinetics of CO₂ absorption are put forward.

Key words: thermodynamics, kinetics, CO₂ capture, absorption, amines

摘要： 二氧化碳捕集与封存技术（CCS）是针对大气CO₂含量增高导致的全球气候变暖而提出的全球性解决方案。有机胺吸收法作为经济与技术层面最成熟的技术，是实现二氧化碳捕集的重要工艺过程。从有机胺法吸收二氧化碳的基本反应机理出发，系统评述了应用有机胺法吸收捕集CO₂的热力学与动力学性质的研究进展，介绍了不同类型胺溶剂分子结构与CO₂捕集溶解度和反应速度的关系，并对今后CO₂吸收捕集的热力学和动力学的研究方向提出了展望。

关键词: 热力学, 动力学, CO₂捕集, 吸收法, 有机胺

CLC Number:

TQ028.8

CHEN Jian, LUO Weiliang, LI Han. A review for research on thermodynamics and kinetics of carbon dioxide absorption with organic amines[J]. , 2014, 65(1): 12-21.

陈健, 罗伟亮, 李晗. 有机胺吸收二氧化碳的热力学和动力学研究进展[J]. CIESC Journal, 2014, 65(1): 12-21.

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