• THERMODYNAMICS • Previous Articles Next Articles
ZHAO Changwei; MA Peisheng; XIA Shuqian
Received:
Revised:
Online:
Published:
Contact:
赵长伟; 马沛生; 夏淑倩
通讯作者:
Abstract: Abstract Densities of aqueous solutions of eight amino acids, glycine, L-alanine, L-valine, L-isoleucine, L-serine, L-threonine, L-arginine and L-phenylalanine, are measured as a function of amino acid concentration from 293.15 K to 333.15 K. These data are used to calculate the apparent molar volume Vφ^0 and infinite dilution apparent molar volume Vφ^0 (partial molar volume). Data of five amino acids are used to correlate partial molar volume Vφ^00 using group contribution method to estimate the contributions of the zwitterionic end groups (NH+,COO-) and CH2 group, OH group, CNHNHNH2 group and C6H5(phenyl) group of amino acids. The results show that Vφ^0 values for all kinds of groups of amino acids studied increase with increase of temperature except those for CH2^φ group, which are almost constant within the studied temperature range. Data of other amino acids, L-valine, L-isoleucine and L-threonine, are chosen for comparison with the predicted partial molar volume Vφ^0 using the group additivity parameters obtained. The results confirm that this group additivity method has excellent predictive utility.
Key words: partial molar volume, amino acid, group contribution
摘要: Abstract Densities of aqueous solutions of eight amino acids, glycine, L-alanine, L-valine, L-isoleucine, L-serine, L-threonine, L-arginine and L-phenylalanine, are measured as a function of amino acid concentration from 293.15 K to 333.15 K. These data are used to calculate the apparent molar volume Vφ^0 and infinite dilution apparent molar volume Vφ^0 (partial molar volume). Data of five amino acids are used to correlate partial molar volume Vφ^00 using group contribution method to estimate the contributions of the zwitterionic end groups (NH+,COO-) and CH2 group, OH group, CNHNHNH2 group and C6H5(phenyl) group of amino acids. The results show that Vφ^0 values for all kinds of groups of amino acids studied increase with increase of temperature except those for CH2^φ group, which are almost constant within the studied temperature range. Data of other amino acids, L-valine, L-isoleucine and L-threonine, are chosen for comparison with the predicted partial molar volume Vφ^0 using the group additivity parameters obtained. The results confirm that this group additivity method has excellent predictive utility.
关键词: 氨基酸;水溶液;生物化学;P2O5;多肽酶;热力学;输运性能
ZHAO Changwei, MA Peisheng, XIA Shuqian. Studies on Partial Molar Volumes of Some Amino Acids and Their Groups in Aqueous Solutions from 293.15K to 333.15K[J]. .
赵长伟,马沛生,夏淑倩. 293.15K到333.15K温度下一些氨基酸及其相应基团水溶液中的偏摩尔体积研究[J]. CIESC Journal.
0 / / Recommend
Add to citation manager EndNote|Ris|BibTeX
URL: https://hgxb.cip.com.cn/EN/
https://hgxb.cip.com.cn/EN/Y2004/V12/I4/521