Prediction and verification of calcium sulfate scaling trend in hydrothermal desalination process of high salinity mine

doi:10.11949/0438-1157.20240417

CIESC Journal ›› 2025, Vol. 76 ›› Issue (1): 81-92.DOI: 10.11949/0438-1157.20240417

• Thermodynamics • Previous Articles Next Articles

Prediction and verification of calcium sulfate scaling trend in hydrothermal desalination process of high salinity mine

Yuanhui TANG¹^,²^,³(), Yuanji BAI²^,³, Qiang GUO¹, Xiaolei HE⁴, Lixin YU³, Yakai LIN³(), Xiaolin WANG³

^1.State Key Laboratory of Water Resource Protection and Utilization in Coal Mining, National Institute of Clean-and-Low-Carbon Energy, Beijing 102209, China
^2.College of Chemistry and Environmental Engineering, China University of Mining and Technology, Beijing 100083, China
^3.Key Laboratory of Membrane Materials and Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
^4.China Huaneng Clean Energy Research Institute Co. , Ltd. , Beijing 102209, China

Received:2024-04-16 Revised:2024-08-18 Online:2025-02-08 Published:2025-01-25
Contact: Yakai LIN

高矿化度矿井水热法脱盐过程中硫酸钙的结垢趋势预测及验证

唐元晖¹^,²^,³(), 柏元吉²^,³, 郭强¹, 何晓磊⁴, 余立新³, 林亚凯³(), 王晓琳³

^1.北京低碳清洁能源研究院，煤炭开采水资源保护与利用全国重点实验室，北京 102209
^2.中国矿业大学（北京）化学与环境工程学院，北京 100083
^3.清华大学化学工程系，膜材料与工程北京市重点实验室，北京 100084
^4.中国华能清洁能源研究院有限公司，北京 102209

通讯作者: 林亚凯
作者简介:唐元晖(1986—)，女，博士，副教授，tyh@cumtb.edu.cn
基金资助:
煤炭开采水资源保护与利用国家重点实验室2020年开放基金课题项目(GJNY-20-113-09);中央高校基本科研业务费专项资金项目(2022YQHH04);北京市自然科学基金项目(2232018);国家自然科学基金面上项目(22378225);国家重点研发计划项目(2022YFC2105103)

Abstract

Abstract:

The highly mineralized mine water is characterized by its complex composition, high salinity, and significant hardness, which leads to the formation of inorganic scales during thermal desalination processes, primarily composed of CaSO₄. Based on the typical composition of highly mineralized mine water, a simulated feed solution containing Ca²⁺, Mg²⁺, Na⁺, Cl⁻, and $S O_{4}^{2 -}$ was prepared. The solubility of CaSO₄ in the Ca²⁺-Mg²⁺-Na⁺-Cl⁻- $S O_{4}^{2 -}$ system was then investigated using an isothermal dissolution method at temperatures of 40, 50, 60, and 70℃. The results indicate that within the temperature range of 40℃ to 70℃, the solubility of CaSO₄ decreases with increasing temperature, increases with higher MgCl₂ concentration, and decreases with higher Na₂SO₄ concentration. The Oddo-Tomson saturation index method was used to predict the scaling trend of CaSO₄ in the thermal desalination process, and the modified saturation index (SI) equation was obtained. The prediction results of this equation are consistent with the scaling experiment of CaSO₄ on the surface of stainless steel pipe at 65℃. When the saturation index exceeded 0.2, CaSO₄ crystals began to precipitate on the surface of stainless steel tubes in the Ca²⁺-Mg²⁺-Na⁺-Cl⁻- $S O_{4}^{2 -}$ system. Finally, scaling experiments using simulated high-mineralized mine water SA and SB were employed to demonstrate the feasibility and limitations of this method in practical mine water applications.

Key words: highly mineralized mine water, calcium sulfate, saturation index, scaling, thermal desalination

摘要：

高矿化度矿井水具有成分复杂、含盐量高、硬度大的特点，在热法脱盐过程中会产生以CaSO₄为主的无机垢。根据高矿化度矿井水的典型组成，配制含有Ca²⁺-Mg²⁺-Na⁺-Cl^-- $S O_{4}^{2 -}$ 的模拟原料液，首先采用恒温溶解法，考察温度为40、50、60、70℃时CaSO₄在Ca²⁺-Mg²⁺-Na⁺-Cl^-- $S O_{4}^{2 -}$ 体系的溶解度。结果表明：在40~70℃的范围内，CaSO₄的溶解度随温度的升高而减小，随MgCl₂浓度的增加而增大，随Na₂SO₄浓度的增加而减小。采用Oddo-Tomson饱和指数法，对CaSO₄在热法脱盐过程的结垢趋势进行预测，得到修正的饱和指数（SI）方程，该方程预测结果与65℃下CaSO₄在不锈钢管表面的结垢实验相吻合。且当饱和指数大于0.2时，Ca²⁺-Mg²⁺-Na⁺-Cl^-- $S O_{4}^{2 -}$ 体系中的CaSO₄晶体开始在不锈钢管表面析出，最后采用模拟高矿化度矿井水SA和SB的结垢实验说明本方法在实际矿井水应用的可行性和局限性。

关键词: 高矿化度矿井水, CaSO₄, 饱和指数, 结垢, 热法脱盐

CLC Number:

TQ 028.8

Yuanhui TANG, Yuanji BAI, Qiang GUO, Xiaolei HE, Lixin YU, Yakai LIN, Xiaolin WANG. Prediction and verification of calcium sulfate scaling trend in hydrothermal desalination process of high salinity mine[J]. CIESC Journal, 2025, 76(1): 81-92.

唐元晖, 柏元吉, 郭强, 何晓磊, 余立新, 林亚凯, 王晓琳. 高矿化度矿井水热法脱盐过程中硫酸钙的结垢趋势预测及验证[J]. 化工学报, 2025, 76(1): 81-92.

Figures/Tables 17

Table 1 Main water quality indexes of high salinity mine water， sea water and oilfield water［27-29］

水质	矿井水1	矿井水2	油田水1	油田水2	油田水3	海水
K⁺/(mg·L^-1)	12	—	—	—	—	399
Ca²⁺/(mg·L^-1)	194	562	1587	652	212	412
Na⁺/(mg·L^-1)	1803	—	—	385	—	10770
Mg²⁺/(mg·L^-1)	289	342	784	385	40.5	1294
Ba²⁺/(mg·L^-1)	—	—	528	423	80.2	—
Sr²⁺/(mg·L^-1)	—	—	435	12.	52.4	3.3
COD/(mg·L^-1)	19.92	—	19.92	60	—	50
总碱度（以CaCO₃计）/(mg·L^-1)	388	—	150	372	330	300
Cl^-/(mg·L^-1)	1789	1.45	23578	17482	7658	19354
$S O_{4}^{2 -}$ /(mg·L^-1)	1732	1940	75.81	15.2	16.8	2712
pH	7.67	3.38	7.9	7.2	7.3	8.1
含盐量/(mg·L^-1)	5963	2773	30782	25745	14879	35000

Table 1 Main water quality indexes of high salinity mine water， sea water and oilfield water［27-29］

水质	矿井水1	矿井水2	油田水1	油田水2	油田水3	海水
K⁺/(mg·L^-1)	12	—	—	—	—	399
Ca²⁺/(mg·L^-1)	194	562	1587	652	212	412
Na⁺/(mg·L^-1)	1803	—	—	385	—	10770
Mg²⁺/(mg·L^-1)	289	342	784	385	40.5	1294
Ba²⁺/(mg·L^-1)	—	—	528	423	80.2	—
Sr²⁺/(mg·L^-1)	—	—	435	12.	52.4	3.3
COD/(mg·L^-1)	19.92	—	19.92	60	—	50
总碱度（以CaCO₃计）/(mg·L^-1)	388	—	150	372	330	300
Cl^-/(mg·L^-1)	1789	1.45	23578	17482	7658	19354
$S O_{4}^{2 -}$ /(mg·L^-1)	1732	1940	75.81	15.2	16.8	2712
pH	7.67	3.38	7.9	7.2	7.3	8.1
含盐量/(mg·L^-1)	5963	2773	30782	25745	14879	35000

Table 2 Main water quality indices of high salinity mine water

水质	数值	水质	数值
含盐量/(mg·L^-1)	7191	Mg²⁺/(mg·L^-1)	75.6
K⁺/(mg·L^-1)	38.4	Cl^-/(mg·L^-1)	1302
Ca²⁺/( mg·L^-1)	267.3	$S O_{4}^{2 -}$ /(mg·L^-1)	2925
Na⁺/( mg·L^-1)	1881	pH	7.7

Table 2 Main water quality indices of high salinity mine water

水质	数值	水质	数值
含盐量/(mg·L^-1)	7191	Mg²⁺/(mg·L^-1)	75.6
K⁺/(mg·L^-1)	38.4	Cl^-/(mg·L^-1)	1302
Ca²⁺/( mg·L^-1)	267.3	$S O_{4}^{2 -}$ /(mg·L^-1)	2925
Na⁺/( mg·L^-1)	1881	pH	7.7

Table 3 Compositions of the simulated feed solutions

编号	MgCl₂/(mg·L^-1)	Na₂SO₄/(mg·L^-1)	CaCl₂/(mg·L^-1)
A-1	395.8	8135	1803
A-2	1781	8135	1803
A-3	3166	8135	1803
A-4	4552	8135	1803
A-5	5937	8135	1803
A-6	3166	1479	1803
A-7	3166	4807	1803
A-8	3166	11463	1803
A-9	3166	14791	1803

Fig.1 The variation of Ca²⁺ concentration over time in the 40℃ system

Fig.2 Flowchart for testing CaSO₄ solubility

Fig.3 The scaling experiment validation setup

Fig. 4 Effect of MgCl₂ concentration on CaSO₄ solubility at different temperatures

Fig. 5 Effect of Na2SO4 concentration on CaSO₄ solubility at different temperatures

Fig. 6 Comparison between experimental and fitting values of saturation index equation

Table 4 Compositions of feed solution used for the verification of the saturation index equation

序号	$S O_{4}^{2 -}$ /(mg·L^-1)	Cl^-/(mg·L^-1)	Ca²⁺/(mg·L^-1)	Mg²⁺/(mg·L^-1)	Na⁺/(mg·L^-1)	温度/℃	离子强度/(mol·L^-1)	SI
1	3409	1477	672.0	316.0	1126	45	0.17	0.002
2	4961	2946	735.0	664.0	2245	45	0.29	0.006
3	4961	2946	735.0	664.0	2946	45	0.31	-0.010
4	6424	3432	647.0	450.0	3432	45	0.32	0.009
5	6424	3432	647.0	450.0	3713	45	0.33	0.001
6	2953	2759	1078.0	292.0	1855	55	0.22	0.010
7	2953	2759	1078.0	292.0	2759	55	0.24	0.030
8	6191	3335	553.0	450.0	3335	55	0.31	-0.010
9	6191	3335	553.0	450.0	3713	55	0.32	-0.020
10	8124	2950	587.4	467.0	4331	55	0.37	0.050
11	3488	2069	571.0	467.0	1466	65	0.20	-0.003
12	3488	2069	571.0	467.0	2069	65	0.21	-0.030
13	6093	3392	510.0	450.0	3713	65	0.32	-0.020
14	6866	3123	599.9	456.3	3859	65	0.34	-0.020
15	7480	3463	537.0	800.0	3713	65	0.38	0.007

Table 4 Compositions of feed solution used for the verification of the saturation index equation

序号	$S O_{4}^{2 -}$ /(mg·L^-1)	Cl^-/(mg·L^-1)	Ca²⁺/(mg·L^-1)	Mg²⁺/(mg·L^-1)	Na⁺/(mg·L^-1)	温度/℃	离子强度/(mol·L^-1)	SI
1	3409	1477	672.0	316.0	1126	45	0.17	0.002
2	4961	2946	735.0	664.0	2245	45	0.29	0.006
3	4961	2946	735.0	664.0	2946	45	0.31	-0.010
4	6424	3432	647.0	450.0	3432	45	0.32	0.009
5	6424	3432	647.0	450.0	3713	45	0.33	0.001
6	2953	2759	1078.0	292.0	1855	55	0.22	0.010
7	2953	2759	1078.0	292.0	2759	55	0.24	0.030
8	6191	3335	553.0	450.0	3335	55	0.31	-0.010
9	6191	3335	553.0	450.0	3713	55	0.32	-0.020
10	8124	2950	587.4	467.0	4331	55	0.37	0.050
11	3488	2069	571.0	467.0	1466	65	0.20	-0.003
12	3488	2069	571.0	467.0	2069	65	0.21	-0.030
13	6093	3392	510.0	450.0	3713	65	0.32	-0.020
14	6866	3123	599.9	456.3	3859	65	0.34	-0.020
15	7480	3463	537.0	800.0	3713	65	0.38	0.007

Fig. 7 Verification of the saturation index equation

Table 5 The fouling on the surface of stainless steel pipe with different saturation indices

编号	Ca²⁺/(mg·L^-1)	Mg²⁺/(mg·L^-1)	Na⁺/(mg·L^-1)	Cl^-/(mg·L^-1)	$S O_{4}^{2 -}$ /(mg·L^-1)	温度/℃	SI	有无沉淀
S-1	600	800	4313	3431.7	9000	65	0.08	无
S-2	650	800	4313	3520	9000	65	0.11	无
S-3	700	800	4313	3609	9000	65	0.14	无
S-4	750	800	4313	3698	9000	65	0.16	无
S-5	800	800	4313	3786	9000	65	0.20	有
S-6	850	800	4313	3874	9000	65	0.21	有
S-7	900	800	4313	3964.2	9000	65	0.23	有
S-8	950	800	4313	4053	9000	65	0.25	有

Table 5 The fouling on the surface of stainless steel pipe with different saturation indices

编号	Ca²⁺/(mg·L^-1)	Mg²⁺/(mg·L^-1)	Na⁺/(mg·L^-1)	Cl^-/(mg·L^-1)	$S O_{4}^{2 -}$ /(mg·L^-1)	温度/℃	SI	有无沉淀
S-1	600	800	4313	3431.7	9000	65	0.08	无
S-2	650	800	4313	3520	9000	65	0.11	无
S-3	700	800	4313	3609	9000	65	0.14	无
S-4	750	800	4313	3698	9000	65	0.16	无
S-5	800	800	4313	3786	9000	65	0.20	有
S-6	850	800	4313	3874	9000	65	0.21	有
S-7	900	800	4313	3964.2	9000	65	0.23	有
S-8	950	800	4313	4053	9000	65	0.25	有

Fig. 8 The micromorphology of the precipitate

Table 6 The composition and content of precipitated elements at different saturation index

元素	质量分数/%
元素	S-5	S-6	S-7	S-8
O	73.34	71.54	67.30	76.68
Na	—	0.06	0.12	0.03
Mg	0.01	0.03	—	0.04
S	25.13	14.36	15.85	11.66
Ca	19.91	14.00	16.73	11.58

Table 7 Composition of real mine water and simulated mine water

水质	真实矿井水A	模拟矿井水SA	真实矿井水B	模拟矿井水SB
K⁺/(mg·L^-1)	6.86	6.50	12.8	12.8
Ca²⁺/(mg·L^-1)	283	293	89.1	89.0
Na⁺/(mg·L^-1)	1150	1329	627	627
Mg²⁺/(mg·L^-1)	48.8	49	25.2	25.2
氨氮/(mg·L^-1)	0.166	—	2.11	—
Mn²⁺/(mg·L^-1)	0.139	—	0.06	—
Ba²⁺/(mg·L^-1)	<0.01	—	0.04	—
Fe²⁺/(mg·L^-1)	<0.03	—	0.08	—
Al³⁺/(mg·L^-1)	<0.07	—	0.014	—
镧/(mg·L^-1)	<0.04	—	—	—
锌/(mg·L^-1)	<0.009	—	0.127	—
$S O_{4}^{2 -}$ /(mg·L^-1)	3580	3500	975	975
Cl^-/(mg·L^-1)	91	91	434	612
$H C O_{3}^{-}$ /(mg·L^-1)	66	66	—	—
$C O_{3}^{2 -}$ /(mg·L^-1)	5	5	—	—
F^-/(mg·L^-1)	0.208	—	0.384	—
磷酸根/(mg·L^-1)	<0.051	—	—	—
$N O_{3}^{-}$ /(mg·L^-1)	<0.016	—	—	—
COD/(mg·L^-1)	0.6	—	—	—
总碱度/(mg·L^-1)	69	—	401	—
悬浮物/(mg·L^-1)	<5	—	—	—
总有机碳/(mg·L^-1)	<0.1	—	—	—
pH	8.42		7.7
含盐量/(mg·L^-1)	4010	5457	2397

Table 7 Composition of real mine water and simulated mine water

水质	真实矿井水A	模拟矿井水SA	真实矿井水B	模拟矿井水SB
K⁺/(mg·L^-1)	6.86	6.50	12.8	12.8
Ca²⁺/(mg·L^-1)	283	293	89.1	89.0
Na⁺/(mg·L^-1)	1150	1329	627	627
Mg²⁺/(mg·L^-1)	48.8	49	25.2	25.2
氨氮/(mg·L^-1)	0.166	—	2.11	—
Mn²⁺/(mg·L^-1)	0.139	—	0.06	—
Ba²⁺/(mg·L^-1)	<0.01	—	0.04	—
Fe²⁺/(mg·L^-1)	<0.03	—	0.08	—
Al³⁺/(mg·L^-1)	<0.07	—	0.014	—
镧/(mg·L^-1)	<0.04	—	—	—
锌/(mg·L^-1)	<0.009	—	0.127	—
$S O_{4}^{2 -}$ /(mg·L^-1)	3580	3500	975	975
Cl^-/(mg·L^-1)	91	91	434	612
$H C O_{3}^{-}$ /(mg·L^-1)	66	66	—	—
$C O_{3}^{2 -}$ /(mg·L^-1)	5	5	—	—
F^-/(mg·L^-1)	0.208	—	0.384	—
磷酸根/(mg·L^-1)	<0.051	—	—	—
$N O_{3}^{-}$ /(mg·L^-1)	<0.016	—	—	—
COD/(mg·L^-1)	0.6	—	—	—
总碱度/(mg·L^-1)	69	—	401	—
悬浮物/(mg·L^-1)	<5	—	—	—
总有机碳/(mg·L^-1)	<0.1	—	—	—
pH	8.42		7.7
含盐量/(mg·L^-1)	4010	5457	2397

Fig.9 The microscopic morphology of the precipitate obtained from simulated wastewater SA after 1-fold concentration and SB after 9-fold concentration

Table 8 The elemental composition and content of the precipitate obtained from simulated wastewater SA after 1-fold concentration and SB after 9-fold concentration

元素	质量分数/%
元素	SA	SB
O	43.95	41.87
S	23.69	24.73
Ca	32.36	33.39

References 35

24	Wang L, Tang H W, Gao Y. Study of gathering system scaling prediction[J]. Pipeline Technique and Equipment, 2012(3): 12-13.
25	倪兵, 沈胜强, 陈石, 等. 高盐海水中硫酸钙结垢趋势预测及验证[J]. 大连理工大学学报, 2019, 59(5): 471-479.
	Ni B, Shen S Q, Chen S, et al. Prediction and verification of calcium sulfate scaling tendency in high salinity seawater[J]. Journal of Dalian University of Technology, 2019, 59(5): 471-479.
26	陈浩. 含盐废水CaSO₄结垢倾向及其软化工艺研究[D]. 杭州: 浙江理工大学, 2018.
	Chen H. Study on scaling tendency and softening process of CaSO₄ in saline wastewater[D]. Hangzhou: Zhejiang Sci-Tech University, 2018.
27	郭强, 李井峰, 刘兆峰, 等. 高矿化度矿井水的膜蒸馏处理[J]. 煤炭学报, 2023, 48(9): 3494-3502.
	Guo Q, Li J F, Liu Z F, et al. Membrane distillation treatment of high-salinity mine water[J]. Journal of China Coal Society, 2023, 48(9): 3494-3502.
28	林光鑫, 许昶, 沈飞, 等. 酸性矿井水的治理思路及工程实例分析[J]. 四川环境, 2023, 42(6): 219-225.
	Lin G X, Xu C, Shen F, et al. Thoughts on treatment of acid mine water and analysis of engineering examples[J]. Sichuan Environment, 2023, 42(6): 219-225.
29	路遥军, 石美, 刁永强, 等. 油田采出水结垢趋势及工艺优化技术研究[J]. 石油工程建设, 2020, 46(5): 14-20.
	Lu Y J, Shi M, Diao Y Q, et al. Trend of scaling in oilfield produced water and process optimization[J]. Petroleum Engineering Construction, 2020, 46(5): 14-20.
30	Li Z B, Demopoulos G P. Effect of NaCl, MgCl₂, FeCl₂, FeCl₃, and AlCl₃ on solubility of CaSO₄ phases in aqueous HCl or HCl + CaCl₂ solutions at 298 to 353 K[J]. Journal of Chemical & Engineering Data, 2006, 51(2): 569-576.
31	Ling Y B, Demopoulos G P. Solubility of calcium sulfate hydrates in (0 to 3.5) mol·kg^-1 sulfuric acid solutions at 100℃[J]. Journal of Chemical & Engineering Data, 2004, 49(5): 1263-1268.
1	张春晖, 赵桂峰, 苏佩东, 等. 基于 "深地-井下-地面" 联动的煤矿矿井水处理利用模式初探[J]. 矿业科学学报, 2024, 9(1): 1-12.
	Zhang C H, Zhao G F, Su P D, et al. Treatment and utilization of coal mine water based on "deep ground-underground-surface ground" linkage system[J]. Journal of Mining Science and Technology, 2024, 9(1): 1-12.
2	龙玉桥, 崔婷婷, 李伟, 等. 地下水污染物溯源的数学模拟方法研究进展[J]. 地下水, 2017, 39(1): 1-7.
	Long Y Q, Cui T T, Li W, et al. A Review of mathematical simulation methods for groundwater pollution source identification[J]. Ground Water, 2017, 39(1): 1-7.
3	发展改革委水利部关于印发《国家节水行动方案》的通知[J]. 中华人民共和国国务院公报, 2019 (22): 39-45.
	Notice of the Ministry of Water Resources of the National Development and Reform Commission on issuing the 《National Water-Saving Action Plan》[J]. Bulletin of The State Council of the People's Republic of China, 2019 (22): 39-45.
4	马莲净, 王颂, 杜松, 等. 宁东煤田枯竭油层回注存储高矿化度矿井水技术思路[J]. 煤炭科学技术, 2023, 51(12): 149-158.
	Ma L J, Wang S, Du S, et al. Depleted petroleum reservoirs reinjection and storage technical thinking of highly-mineralized mine water in Ningdong Coalfield[J]. Coal Science and Technology, 2023, 51(12): 149-158.
5	刘遵义, 李小亮. 高矿化度矿井水处理技术应用现状[J]. 洁净煤技术, 2023, 29(S2): 436-441.
	Liu Z Y, Li X L. Application status of high salinity mine water treatment technology[J]. Clean Coal Technology, 2023, 29(S2): 436-441.
6	卞伟, 李井峰, 刘淑琴, 等. 宁东基地高矿化度矿井水处理工程实践与发展方向[J]. 水处理技术, 2021, 47(8): 120-123, 127.
	Bian W, Li J F, Liu S Q, et al. Study on the technical route of highly mineralized mine water treatment in ningdong energy base[J]. Technology of Water Treatment, 2021, 47(8): 120-123, 127.
7	李岸然, 杨庆卫. 高盐矿井水蒸馏处理工艺中水质结垢趋势分析[J]. 煤炭加工与综合利用, 2019(1): 75-78.
	Li A R, Yang Q W. Analysis of water scaling tendency in high-salt mine water distillation treatment process[J]. Coal Processing & Comprehensive Utilization, 2019(1): 75-78.
8	方惠明, 戚凯, 李向东, 等. 高矿化度矿井水结垢趋势及影响因素研究[J]. 中国煤炭地质, 2021, 33(2): 60-63.
	Fang H M, Qi K, Li X D, et al. A research for highly mineralized mine water scaling trend and impacting factors[J]. Coal Geology of China, 2021, 33(2): 60-63.
9	Olajire A A. A review of oilfield scale management technology for oil and gas production[J]. Journal of Petroleum Science and Engineering, 2015, 135: 723-737.
10	王天媛, 陈春波, 孙琳, 等. 基于全周期缓慢结垢的多效蒸发海水淡化慢时变系统优化设计[J]. 化工学报, 2022, 73(2): 759-769.
	Wang T Y, Chen C B, Sun L, et al. Optimal design of slow-time-varying system for multi-effect distillation desalination based on full-cycle slow fouling[J]. CIESC Journal, 2022, 73(2): 759-769.
11	赖富国, 高国华, 肖燕飞, 等. 氯-硫酸盐体系下硫酸钙溶解度相图的研究进展[J]. 无机盐工业, 2018, 50(8): 16-21.
	Lai F G, Gao G H, Xiao Y F, et al. Research progress on solubility phase diagrams of calcium sulfate in chloride-sulfate solutions[J]. Inorganic Chemicals Industry, 2018, 50(8): 16-21.
12	Wu X Q, He W, Guan B H, et al. Solubility of calcium sulfate dihydrate in Ca-Mg-K chloride salt solution in the range of (348.15 to 371.15) K[J]. Journal of Chemical & Engineering Data, 2010, 55(6): 2100-2107.
13	Bock E. On the solubility of anhydrous calcium sulphate and of gypsum in concentrated solutions of sodium chloride at 25℃, 30℃, 40℃, and 50℃[J]. Canadian Journal of Chemistry, 1961, 39(9): 1746-1751.
14	Glew D N, Hames D A. Gypsum, disodium pentacalcium sulfate, and anhydrite solubilities in concentrated sodium chloride solutions[J]. Canadian Journal of Chemistry, 1970, 48(23): 3733-3738.
15	王可苗. Ca-Mg-K-Cl-H₂O盐溶液体系中硫酸钙的结晶过程[D]. 武汉: 武汉科技大学, 2013.
	Wang K M. Crystallization process of calcium sulfate in Ca-Mg-K-Cl-H₂O salt solution system[D]. Wuhan: Wuhan University of Science and Technology, 2013.
16	尹忠, 赵晓东. 硫酸钙在盐酸和氯化钠水溶液中的溶解度[J]. 油田化学, 1994, 11(4): 345-347.
	Yin Z, Zhao X D. Solubilities of calcium sulfate in hydrochloric acid and aqueous sodiium chloride solution[J]. Oilfield Chemistry, 1994, 11(4): 345-347.
17	Barba D, Brandani V, di Giacomo G. A thermodynamic model of CaSO₄ solubility in multicomponent aqueous solutions[J]. The Chemical Engineering Journal, 1982, 24(2): 191-200.
18	Meijer J A M, van Rosmalen G M. Solubilities and supersaturations of calcium sulfate and its hydrates in seawater[J]. Desalination, 1984, 51(3): 255-305.
19	田萍, 宁朋歌, 曹宏斌, 等. 二水硫酸钙在铵盐溶液中溶解度测定及热力学计算[J]. 过程工程学报, 2012, 12(4): 625-630.
	Tian P, Ning P G, Cao H B, et al. Solubility measurement of calcium sulfate dihydrate in NH₄Cl-(NH₄)₂SO₄ solutions and thermodynamic calculation[J]. The Chinese Journal of Process Engineering, 2012, 12(4): 625-630.
20	Li Z B, Demopoulos G P. Speciation-based chemical equilibrium model of CaSO₄ solubility in the H + Na + Ca+ Mg + Al + Fe(Ⅱ) + Cl + SO₄ + H₂O system[J]. Industrial & Engineering Chemistry Research, 2007, 46(20): 6385-6392.
21	Azimi G, Papangelakis V G, Dutrizac J E. Development of an MSE-based chemical model for the solubility of calcium sulphate in mixed chloride-sulphate solutions[J]. Fluid Phase Equilibria, 2008, 266(1/2): 172-186.
22	Oddo J E, Tomson M B. Why scale forms in the oil field and methods to predict it[J]. SPE Production & Facilities, 1994, 9(1): 47-54.
23	袁存光, 唐仕明, 于剑峰, 等. 江苏油田卤水输送管道中硫酸钙结垢趋势预测[J]. 中国石油大学学报, 2011, 35(4): 154-156.
	Yuan C G, Tang S M, Yu J F, et al. Scaling trend prediction of calcium sulfate in brine pipeline in Jiangsu Oilfield[J]. Journal of China University of Petroleum, 2011, 35(4): 154-156.
24	王磊, 唐红伟, 高雨. 油气田地面集输系统结垢预测模型研究[J]. 管道技术与设备, 2012(3): 12-13.
32	Li Z B, Demopoulos G P. Solubility of CaSO₄, phases in aqueous HCl + CaCl₂ solutions from 283 K to 353 K[J]. ChemInform, 2006, 37(7): 1971-1982.
33	石征宇, 石大安, 吕孟. 物质溶解度影响因素的调研[J]. 大众科技, 2007, 9(11): 102-103.
	Shi Z Y, Shi D A, Lyu M. Investigation on the factors affecting the solubility of substances[J]. Popular Science & Technology, 2007, 9(11): 102-103.
34	Barba D, Brandani V, Di Giacomo G. Solubility of calcium sulfate dihydrate in the system sodium sulfate-magnesium chloride-water[J]. Journal of Chemical & Engineering Data, 1984, 29(1): 42-45.
35	葛敬, 朱家骅, 夏素兰, 等. 二水硫酸钙在硫酸铵溶液中的溶解度测定[J]. 化工学报, 2018, 69(7): 2829-2837.
	Ge J, Zhu J H, Xia S L, et al. Solubility determination of calcium sulfate dihydrate in ammonium sulfate solution[J]. CIESC Journal, 2018, 69(7): 2829-2837.

[1]	Nan TU, Xiaoqun LIU, Chiyu WANG, Jiabin FANG. Study on adaptability of scaling law to residence time distribution in bubbling fluidized beds with continuous operation [J]. CIESC Journal, 2024, 75(2): 543-552.
[2]	Hao ZHANG, Yu ZHAO, Zhiming XU, Jinhui LI. Study on scale inhibition characteristics of carboxymethyl dextran by fast controlled precipitation method [J]. CIESC Journal, 2022, 73(4): 1515-1522.
[3]	Wenjie HAN, Jiazhong ZHOU, Di WU, Yongjie GUAN, Qinghua SUN. Study on influence of suspended carrier scaling on CANON-MBBR system and restoration control [J]. CIESC Journal, 2019, 70(6): 2298-2307.
[4]	Yuling ZHANG, Liping ZHANG, Qian WANG, Xudong LI, Xiaodong LIU, Jinghong ZHANG. Optimization of extraction process of inorganic phosphorus in scale of circulating cooling system [J]. CIESC Journal, 2019, 70(3): 1083-1088.
[5]	GE Jing, ZHU Jiahua, XIA Sulan, LIU Shizhong. Solubility determination of calcium sulfate dihydrate in ammonium sulfate solution [J]. CIESC Journal, 2018, 69(7): 2829-2837.
[6]	LUO Zhiqiang, YANG Qingfeng. Effect of rotating magnetic field coupled with water volume on CaCO₃ crystallization [J]. CIESC Journal, 2018, 69(7): 3029-3037.
[7]	LIU Tonghai, DOU Yan, FANG Yang, CUI Peng, SHEN Hao, ZHENG Zhiyin, LIU Rong. Influence of Al³⁺, Na⁺ and Mg²⁺ on crystallization of calcium sulfate dihydrate [J]. CIESC Journal, 2016, 67(S1): 296-301.
[8]	HAN Qiaoyun, YANG Xiaojie, ZOU Shenghua. Micro-mechanism of scaling in a cooling system under deep mine [J]. CIESC Journal, 2016, 67(9): 3936-3945.
[9]	DOU Yan, LIU Tonghai, SHEN Hao, ZHENG Zhiyin, LIU Rong, CUI Peng. Characteristic and structure of calcium sulfate dihydrate crystallites in crystallization process during reaction [J]. CIESC Journal, 2016, 67(6): 2449-2455.
[10]	WANG Zining, ZHOU Jiabei, ZHU Jiahua, WU Hui, CHEN Changguo, LIU Shizhong. Dissolution kinetics of calcium sulfate dihydrate [J]. CIESC Journal, 2015, 66(3): 1001-1006.
[11]	WANG Jianguo, LI Yutong, DENG Lijuan. Influence of electromagnetic frequency on scale inhibition for spiral winding variable frequency electromagnetic water processor [J]. CIESC Journal, 2015, 66(3): 972-978.
[12]	FENG Juan1，TANG Yongbo2，3，PENG Tao3. Prediction model of penicillin fed-batch fermentation based on KTA-LSSVM [J]. Chemical Industry and Engineering Progree, 2014, 33(09): 2438-2443.
[13]	MA Baoguo, RU Xiaohong, ZOU Kaibo, LU Siwen, FU Haobing. Preparation of α-calcium sulfate hemihydrate from phosphogypsum in Ca-Na-Cl solutions under atmospheric pressure [J]. CIESC Journal, 2013, 64(7): 2701-2707.
[14]	Lü Pengfei，FEI Dejun，DANG Yagu. Preparation of calcium sulfate whisker from phosphogypsum and its application [J]. Chemical Industry and Engineering Progree, 2013, 32(04): 842-847.
[15]	XIONG Lan, MIAO Xuefei, WU Yimei, CHEN Jiapeng, XIE Zijie. Anti-scaling effect comparison of high-frequency electromagnetic pulses stimulation in processing chambers with different electrodes [J]. CIESC Journal, 2012, 63(10): 3220-3224.

Prediction and verification of calcium sulfate scaling trend in hydrothermal desalination process of high salinity mine

高矿化度矿井水热法脱盐过程中硫酸钙的结垢趋势预测及验证

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 17

References 35

Related Articles 15

Recommended Articles 0

Metrics

Comments