Scale preparation of carbon nanotubes/epoxy resin cellucotton composite and its oil/water separation performance

doi:10.11949/j.issn.0438-1157.20141432

CIESC Journal ›› 2015, Vol. 66 ›› Issue (3): 1194-1200.DOI: 10.11949/j.issn.0438-1157.20141432

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Scale preparation of carbon nanotubes/epoxy resin cellucotton composite and its oil/water separation performance

NAN Hui¹, WANG Chong², WANG Gang², LIN Hong^2,3, WEI Haomin¹, WANG Ziling¹

1 School of Mechanical Engineering, Qinghai University, Xining 810016, Qinghai, China;
2 School of Chemical Engineering, Qinghai University, Xining 810016, Qinghai, China;
3 State Key Laboratary of New Ceramics & Fine Processing, School of Material Science and Engineering, Tsinghua University, Beijing 100084, China

Received:2014-09-23 Revised:2014-12-03 Online:2015-03-05 Published:2015-03-05
Supported by:
supported by the National Natural Science Foundation of China(51362025) and the Youth Foundation of Qinghai University (2013-QGY-8).

碳纳米管/环氧树脂复合纤维棉宏量制备及其吸油性能

南辉¹, 王冲², 王刚², 林红^2,3, 韦浩民¹, 王子玲¹

1 青海大学机械工程学院, 青海西宁 810016;
2 青海大学化工学院, 青海西宁 810016;
3 清华大学材料学院新型陶瓷与精细工艺国家重点实验室, 北京 100084

通讯作者: 王刚
基金资助:
国家自然科学基金项目(51362025);青海大学中青年基金项目(2013-QGY-8)。

Abstract

Abstract:

Carbon nanotubes/epoxy resin (EP) cellucotton composite was prepared on a large scale using EP as the precursor sol, aluminum plates covered with carbon nanotubes as substrate, by a simple and convenient electrospinning and collaborative pulling technology. The morphology, structure and composition of the obtained samples were investigated with scanning electron microscopy, thermogravimetric analyzer, mercury injection test and Raman spectroscopy. Carbon nanotubes were partly wrapped and distributed evenly on the surface of the EP fibers, and the composite structures had high specific surface area and porosity. The contact angle of the carbon nanotube/EP composite structure was 114.1° for water, and 66.8° for vegetable oil. The as-made carbon nanotubes/EP composites showed superior adsorption capacity for vegetable oil, which was better than polypropylene fiber, and could adsorb more than 10 times of oil in terms of their own mass.

Key words: carbon nanotubes, porous media, nanostructure, adsorption

摘要：

采用环氧树脂作为前驱体溶胶,利用负载有碳纳米管的铝板为接收基板,通过简单方便的静电纺丝协同拉拔技术,宏量制备了碳纳米管/环氧树脂复合纤维棉,并对这种复合纤维棉的吸油性能进行了探索。采用扫描电子显微镜(SEM)、热重分析仪(TGA)、压汞仪、拉曼光谱仪等设备系统分析了复合纤维棉的形貌、结构和组成。结果表明,复合纤维棉具有高的比表面积与孔隙率,碳纳米管均匀地分布在复合纤维棉中。复合纤维棉与水和植物油的接触角分别为114.1°与66.8°;与丙纶纤维相比较,复合纤维棉展现出更加优异的吸油能力,可吸附超过自身质量10倍的油类物质。

关键词: 碳纳米管, 多孔介质, 纳米结构, 吸收

CLC Number:

O647.3

NAN Hui, WANG Chong, WANG Gang, LIN Hong, WEI Haomin, WANG Ziling. Scale preparation of carbon nanotubes/epoxy resin cellucotton composite and its oil/water separation performance[J]. CIESC Journal, 2015, 66(3): 1194-1200.

南辉, 王冲, 王刚, 林红, 韦浩民, 王子玲. 碳纳米管/环氧树脂复合纤维棉宏量制备及其吸油性能[J]. 化工学报, 2015, 66(3): 1194-1200.

References 25

[1]	Shi W, Johnson J K. Gas adsorption on heterogeneous single-walled carbon nanotube bundles [J]. Physical Review Letters, 2003, 91: 15504
[2]	Chang H, Lee J D, Lee S M, et al. Adsorption of NH3 and NO2 molecules on carbon nanotubes [J]. Applied Physics Letters,2001, 79(23): 3863-3865
[3]	Lu Jindong(陆金东), Chen Aiping(陈爱平), Ma Lei(马磊), He Hongbo(何洪波), Ni Daoke (倪道克), Li Chunzhong(李春忠). Synthesis of CNTs-Ni-TiO2 nanocomposites by in-situ fluidized bed CVD and its photocatalytic activity [J]. CIESC Journal (化工学报), 2012, 63(4): 1070-1075
[4]	Wang Y, Wei F, Luo G H, et al. The large-scale production of carbon nanotubes in a nano-agglomerate fluidized-bed reactor [J]. Chemical Physics Letters, 2002, 364(5/6): 568-572
[5]	Behabtu N, Young C C, Tsentalovich D E, et al. Strong, light, multifunctional fibers of carbon nanotubes with ultrahigh conductivity [J]. Science, 2013, 339(6116): 182-186
[6]	Shang Y Y, He X D, Li Y B, et al. Super-stretchable spring-like carbon nanotube ropes [J]. Advanced Materials,2012, 24(21): 2896-2900
[7]	Wepasnick K A, Smith B A, Bitter J L, et al. Chemical and structural characterization of carbon nanotube surfaces [J]. Analytical and Bioanalytical Chemistry,2010, 396(3): 1003-1014
[8]	Wu Zhuangchun,Chen Zhihong,Du Xu,et al. Transparent conductive carbon nanotube films [J]. Science, 2004, 305(5688): 1273-1276
[9]	Li Kan, Ju Jie, Jiang Lei, et al. Structured cone arrays for continuous and effective collection of micron-sized oil droplets from water [J]. Nature Communications, 2013, 4: 2276
[10]	Hu H, Zhao Z B, Qiu J S, et al. Compressible carbon nanotube- graphene hybrid aerogels with superhydrophobicity and superoleophilicity for oil sorption [J]. Environ. Sci. Technol. Lett., 2014, 1(3): 214-220
[11]	Hu H, Zhao Z B, Qiu J S, et al. Ultralight and highly compressible graphene aerogels [J]. Advanced Materials, 2013, 25(15): 2219-2223
[12]	Xiao N, Zhou Y, Qiu J S, et al. Synthesis of a carbon nanofiber/carbon foam composite from coal liquefaction residue for the separation of oil and water [J]. Carbon, 2013, 59: 530-536
[13]	Yu C, Fan L M, Yang J, et al. Phase-reversal emulsion catalysis with CNT-TiO2 nanohybrids for the selective oxidation of benzyl alcohol [J]. Chem.-A Euro. J., 2013, 19(48): 16192-16195
[14]	Lee C, Baik S. Vertically-aligned carbon nano-tube membrane filters with superhydrophobicity and superoleophilicity [J]. Carbon, 2010, 48: 2192-2197
[15]	Hashim D P, Narayanan N T, Romo-Herrera J M, et al. Covalently boned three-dimensional carbon nanotube solids via boron induced nanojunctions [J]. Scientific Reports, 2012, 2:363
[16]	Rao G P, Lu C, Su F. Sorption of divalent metal ions from aqueous solution by carbon nanotubes: a review [J]. Separation and Purification Technology, 2007, 58(1): 224-231
[17]	Ma X M, Tsige M, Uddin S, et al. Application of carbon nanotubes for removing organic contaminants from water [J]. Materials Express,2011, 1(3): 183-200
[18]	Pan B, Xing B S. Adsorption mechanisms of organic chemicals on carbon nanotubes [J]. Environmental Science & Technology,2008, 42(24): 9005-9013
[19]	Baji A, Mai Y W, Wong S C, et al. Electrospinning of polymer nanofibers: effects on oriented morphology, structures and tensile properties [J]. Composites Science and Technology, 2010, 70(5): 703-718
[20]	Chen D J, Lei S, Wang R H, et al. Dielectrophoresis carbon nanotube and conductive polyaniline nanofiber NH3 gas sensor [J]. Chinese J. Anal. Chem., 2012, 40(10): 145-149
[21]	Adebajo M O, Frost R L, Kloprogge J T, et al. Porous materials for oil spill cleanup: a review of synthesis and absorbing properties [J]. Journal of Porous Materials, 2003, 10(3): 159-170
[22]	Sun Bin (孙斌), Qian Zheng (钱铮). Boiling heat transfer characteristics of nano-refrigerant CuO/R141b flowing in smoothtube [J]. CIESC Journal (化工学报), 2012, 63(3): 733-739
[23]	Shao S J, Zhou S B, Li L, et al. Osteoblast function on electrically conductive electrospun PLA/MWCHTs nanofibers [J]. Biomaterials, 2011, 32(10): 2821-2833
[24]	Gui X C, Wei J Q, Wang K L, et al. Carbon nanotube sponges [J]. Advanced Materials, 2010, 22(5): 617-621
[25]	Liu Changjiu (刘长久), Li Peipei (李培培), Zhao Weimin (赵卫民), Huang Lianghua (黄良花). Electrochemical performance of α-nickel hydroxide codoped with La and Zn [J].CIESC Journal (化工学报),2010, 61(10): 2743-2747

Scale preparation of carbon nanotubes/epoxy resin cellucotton composite and its oil/water separation performance

碳纳米管/环氧树脂复合纤维棉宏量制备及其吸油性能

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