Synthesis and characterization of ion exchange capacity controlled and self-crosslinked anion exchange membranes

doi:10.11949/j.issn.0438-1157.20150362

›› 2015, Vol. 66 ›› Issue (S1): 237-241.DOI: 10.11949/j.issn.0438-1157.20150362

Previous Articles Next Articles

Synthesis and characterization of ion exchange capacity controlled and self-crosslinked anion exchange membranes

ZHANG Xuefei^1,2, WANG Shubo², FEI Zhejun², LI Weiwei², ZHAO Yang², XIE Xiaofeng², QI Shicheng¹, LÜ Yafei¹

1 College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China;
2 Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China

Received:2015-03-20 Revised:2015-03-27 Online:2015-06-30 Published:2015-06-30
Supported by:
supported by the National High Technology Research and Development Program of China (2012AA051201) and the National Basic Research Program of China( 2012CB215505).

离子交换容量可控自交联型阴离子交换膜的制备

张雪飞^1,2, 王树博², 费哲君², 李薇薇², 赵阳², 谢晓峰², 齐士成¹, 吕亚非¹

1 北京化工大学材料科学与工程学院, 北京 100029;
2 清华大学核能与新能源技术研究院, 北京 100084

通讯作者: 齐士成, 谢晓峰
基金资助:
国家高技术研究发展计划项目(2012AA051201);国家重点基础研究发展计划项目( 2012CB215505)。

Abstract

Abstract: Functionalized fluorinated poly (arylene ether oxadiazole) (FPAEO) based cross-linked anion exchange membranes (AEMs) with bifunctional agents were prepared via copolymerization, bromination and solution casting using a thermal cross-linking method. FPAEO-TM synthesized via copolymerization of 4, 4'-isopropylidenebis (2, 6-dimethylphenol) (TM-BPA) and 2, 5-bis(2, 3, 4, 5, 6-pentafluorophenyl)-1, 3, 4- oxadiazole(FPOx) was brominated by N-bromosuccinimide (NBS), thereby avoiding chloromethylation, which required carcinogenic reagents. 1-vinylimidazole acted as a bifunctional agent and played two roles: it served as an ion exchange functional group which provided membranes high conductivity, or as a crosslinking agent to improve the membranes' characteristics. The mambrane's conductivity is 9.02×10^-2 S·cm^-1 at 80℃ and methanol permeability is 1.89×10^-7 cm²·s^-1(20℃). Membranes had the potential to be used in alkaline fuel cell alkaline (AFC).

Key words: electrolytes, self-cross-linking, bifunctional agent, permeability, fuel cells

摘要： 以N-溴代丁二酰亚胺(NBS)为溴化试剂, 对十氟二唑与四甲基双酚A(TM-BPA)聚合的聚合物主链进行溴化, 随后以N-乙烯基咪唑作为双功能化试剂进行功能化, 制备了含有双功能化试剂的氟化聚二唑芳醚阴离子交换膜。其中, 功能化试剂(作为离子交换的功能基传导离子及作为膜内分子的交联点)改善膜物理性质。制备的阴离子交换膜在80℃下的离子传导率为9.02×10^-2 S·cm^-1, 甲醇渗透率为1.89×10^-7 cm²·s^-1(20℃), 在碱性燃料电池中具有应用潜力。

关键词: 电解质, 自交联, 双功能化试剂, 渗透率, 燃料电池

CLC Number:

TQ152

ZHANG Xuefei, WANG Shubo, FEI Zhejun, LI Weiwei, ZHAO Yang, XIE Xiaofeng, QI Shicheng, LÜ Yafei. Synthesis and characterization of ion exchange capacity controlled and self-crosslinked anion exchange membranes[J]. , 2015, 66(S1): 237-241.

张雪飞, 王树博, 费哲君, 李薇薇, 赵阳, 谢晓峰, 齐士成, 吕亚非. 离子交换容量可控自交联型阴离子交换膜的制备[J]. CIESC Journal, 2015, 66(S1): 237-241.

References 15

[1]	Yang Congrong, Wang Suli, Jiang Luhua, Sun Gongquan, HuJinbo, Ma Wenjia. 1, 2-Dimethylimidazolium-functionalized cross-linked alkaline anion exchange membranes for alkaline direct methanol fuel cells [J]. International Journal of Hydrogen Energy, 2015, 40(5): 2363-2370.
[2]	Sarma Loka Subramanyam, Chen Ching-Hsiang, Wang Guo-Rung. Investigations of direct methanol fuel cell (DMFC) fading mechanisms [J]. Journal of Power Sources, 2007, 167(2): 358-365.
[3]	Vega J A, Chartier C, Mustain W E. Effect of hydroxide and carbonate alkaline media on anion exchange membranes [J]. Journal of Power Sources, 2010, 195(21): 7176-7180.
[4]	Liu Zhi, Zhu Xiuling, Wang Guangfu. Novel crosslinked alkaline exchange membranes based on poly(phthalazinone ether ketone) for anion exchange membrane fuel cell applications [J]. Journal of Polymer Science Part B: Polymer Physics, 2013, 51(22): 1632- 1639.
[5]	Zhang Shiman, Li Cunpu, Xie Xiaofeng. Novel cross-linked anion exchange membranes with diamines as ionic exchange functional groups and crosslinking groups [J]. International Journal of Hydrogen Energy, 2014, 39(25): 13718-13724.
[6]	Zhao Chengji, Ma Wenjia, Sun Wenmo, Na Hui. Preparation of anion exchange membrane based on homogeneous quaternization of bromomethylated poly(arylene ether sulfone) [J]. Journal of Applied Polymer Science, 2014, 131(10): 40256.
[7]	Lin Xiaochen, Liang Xuhao, Poynton Simon D, Varcoe John R, Ong Ai Lien, Ran Jin, Li Yan, Li Qiuhua, Xu Tongwen. Novel alkaline anion exchange membranes containing pendant benzimidazolium groups for alkaline fuel cells [J]. Journal of Membrane Science, 2013, 443: 193-200.
[8]	Wang Wenpin, Wang Shubo, Li Weiwei, Xie Xiaofeng, Lv Yafei. Synthesis and characterization of a fluorinated cross-linked anion exchange membrane [J]. International Journal of Hydrogen Energy, 2013, 38(25): 11045-11052.
[9]	Li Weiwei, Wang Shubo, Zhang Xuefei, Wang Wenpin, Xie Xiaofeng, Pei Pucheng. Degradation of guanidinium-functionalized anion exchange membrane during alkaline environment [J]. International Journal of Hydrogen Energy, 2014, 39(25): 13710- 13717.
[10]	Zhang Shouhai, Zhang Bengui, Xing Dongbo, Jian Xigao. Poly(phthalazinone ether ketone ketone) anion exchange membranes with pyridinium as ion exchange groups for vanadium redox flow battery applications [J]. Journal of Materials Chemistry A, 2013, 1(39): 12246-12254.
[11]	Gu Fenglou, Dong Huilong, Li Youyong, Si Zhihong, Yan Feng. Highly stable N3-substituted imidazolium-based alkaline anion exchange membranes: experimental studies and theoretical calculations [J]. Macromolecules, 2014, 47(1): 208-216.
[12]	Srinophakun, Thongchai, Martkumchan, Suwalee. Ionic conductivity in a chitosan membrane for a PEM fuel cell using molecular dynamics simulation [J]. Carbohydrate Polymers, 2012, 88(1): 194-200.
[13]	Ding Jianfu, Michael Day. Novel highly fluorinated poly(arylene ether-1, 3, 4-oxadiazole)s, their preparation, and sensory properties to fluoride anion [J]. Macromolecules, 2006, 39(18): 6054-6062.
[14]	Li Cunpu, Wang Shubo, Wang Wenpin, Xie Xiaofeng, Lv Yafei, Deng Changsheng. A cross-linked fluorinated poly(aryl ether oxadiazole)s using a thermal cross-linking for anion exchange membranes [J]. International Journal of Hydrogen Energy, 2013, 38(25): 11038-11044.
[15]	Zhang Yang, Fei Xu, Zhang Gang, Li Hongtao, Shao Ke, Zhu Jing, Zhao Chengji, Liu Zhongguo, Han Miaomiao, Na Hui. Preparation and properties of epoxy-based cross-linked sulfonated poly(arylene ether ketone) proton exchange membrane for direct methanol fuel cell applications [J]. International Journal of Hydrogen Energy, 2010, 35(12): 6409-6417.

Synthesis and characterization of ion exchange capacity controlled and self-crosslinked anion exchange membranes

离子交换容量可控自交联型阴离子交换膜的制备

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References 15

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Mengmeng ZHANG, Dong YAN, Yongfeng SHEN, Wencui LI. Effect of electrolyte types on the storage behaviors of anions and cations for dual-ion batteries [J]. CIESC Journal, 2023, 74(7): 3116-3126.
[2]	Xiaoyu JIA, Jian YANG, Bo WANG, Mei LIN, Qiuwang WANG. Pore scale numerical simulations for wicking performance of metallic woven mesh [J]. CIESC Journal, 2023, 74(5): 1928-1938.
[3]	Laiming LUO, Jin ZHANG, Zhibin GUO, Haining WANG, Shanfu LU, Yan XIANG. Simulation and experiment of high temperature polymer electrolyte membrane fuel cells stack in the 1—5 kW range [J]. CIESC Journal, 2023, 74(4): 1724-1734.
[4]	Zhiguang QIAN, Yue FAN, Shixue WANG, Like YUE, Jinshan WANG, Yu ZHU. Effect of purging conditions on the impedance relaxation phenomenon and low temperature start-up of PEMFC [J]. CIESC Journal, 2023, 74(3): 1286-1293.
[5]	Xiang GUO, Jinshuo QIAO, Zhenhua WANG, Wang SUN, Kening SUN. Progress of structure for carbon-fueled solid oxide fuel cells [J]. CIESC Journal, 2023, 74(1): 290-302.
[6]	Xin LI, Shaojuan ZENG, Kuilin PENG, Lei YUAN, Xiangping ZHANG. Research progress and tendency of CO₂ electrocatalytic reduction to syngas [J]. CIESC Journal, 2023, 74(1): 313-329.
[7]	Jian SHAO, Junzong FENG, Fengqi LIU, Yonggang JIANG, Liangjun LI, Jian FENG. Research progress on structural modulation and functionalized preparation of phenolic resin-based carbon microspheres [J]. CIESC Journal, 2022, 73(9): 3787-3801.
[8]	Wanchen ZHANG, Xiaoyang CHEN, Qiuqiu LYU, Qin ZHONG, Tenglong ZHU. Performance and durability of cobalt doped SrTi_0.3Fe_0.7O_3-_δ anode SOFC fueled with by-product gas from chemical industry [J]. CIESC Journal, 2022, 73(9): 4079-4086.
[9]	Wangxin GE, Yihua ZHU, Hongliang JIANG, Chunzhong LI. Research progress on electrolytes for carbon dioxide electroreduction [J]. CIESC Journal, 2022, 73(8): 3433-3447.
[10]	Jiaming WANG, Xuehua RUAN, Gaohong HE. Research progress of membrane separation materials for different industrial CO₂-containing mixtures [J]. CIESC Journal, 2022, 73(8): 3417-3432.
[11]	Chengyi AI, Jinshuo QIAO, Zhenhuan WANG, Wang SUN, Kening SUN. Investigation on PrBaFe₂O_6-_δ anode material with in-situ FeNi nanoparticle in direct carbon solid oxide fuel cell [J]. CIESC Journal, 2022, 73(8): 3708-3719.
[12]	Guang YANG, Xin CHENG, Zheng WANG, Ye WANG, Liangjun ZHANG, Jingyi WU. Analytical prediction model of permeability for rarefied gas flow in porous structures with micro or nanopores [J]. CIESC Journal, 2022, 73(7): 2895-2901.
[13]	Bin LI, Wenming SONG, Kunlong YANG, Shuang JIANG, Tianyong ZHANG. Molecular engineering research progress of active materials for aqueous organic flow batteries [J]. CIESC Journal, 2022, 73(7): 2806-2818.
[14]	Wenhuai LI, Wei ZHOU. Analysis of influencing factors and design strategies of high oxygen ion conductivity perovskite [J]. CIESC Journal, 2022, 73(4): 1455-1471.
[15]	Xiaole HUANG, Fu YANG, Lei HAN, Xing NING, Ruiyu LI, Lingxiao DONG, Husheng CAO, Lei DENG, Defu CHE. 3D characterization of pore structure and seepage simulation of tar-rich coal (long flame coal) [J]. CIESC Journal, 2022, 73(11): 5078-5087.