Hydroxyapatite Coatings on Titanium Prepared by Electrodeposition in a Modified Simulated Body Fluid

›› 2009, Vol. 17 ›› Issue (4): 667-671.

• PRODUCT ENGINEERING AND CHEMICAL TECHNOLOGY • Previous Articles Next Articles

Hydroxyapatite Coatings on Titanium Prepared by Electrodeposition in a Modified Simulated Body Fluid

ZHAO Xuhui, YANG Lingfang, ZUO Yu, XIONG Jinping

School of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China

Received:2008-12-08 Revised:2009-05-24 Online:2010-12-30 Published:2009-08-28
Supported by:
Supported by the Young Scholars Fund of Beijing University of Chemical Technology(QN0713)

Hydroxyapatite Coatings on Titanium Prepared by Electrodeposition in a Modified Simulated Body Fluid

赵旭辉, 杨灵芳, 左禹, 熊金平

School of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China

通讯作者: ZUO Yu, E-mail: zuoy@mail.buct.edu.cn
作者简介:
基金资助:
Supported by the Young Scholars Fund of Beijing University of Chemical Technology(QN0713)

Abstract

Abstract: Hydroxyapatite coatings were directly prepared on anodized titanium by electro-deposition method in a modified simulated body fluid.The configuration,structure and bioactivity of the coating were investigated with scanning electron microscopy(SEM),X-ray diffraction analyzer(XRD)and Fourier transform infrared spectroscopy(FTIR)techniques.The results demonstrated that pure and homogeneous hydroxyapatite coating can be obtained without any post-treatment.The prepared coating showed good bioactivity in simulated body fluid(SBF).The time required for a fully covered dense hydroxyapatite coatings was 4 days immersion in SBF.

Key words: hydroxyapatite coating, electro-deposition, modified simulated body fluid, titanium, anodization

摘要： Hydroxyapatite coatings were directly prepared on anodized titanium by electro-deposition method in a modified simulated body fluid.The configuration,structure and bioactivity of the coating were investigated with scanning electron microscopy(SEM),X-ray diffraction analyzer(XRD)and Fourier transform infrared spectroscopy(FTIR)techniques.The results demonstrated that pure and homogeneous hydroxyapatite coating can be obtained without any post-treatment.The prepared coating showed good bioactivity in simulated body fluid(SBF).The time required for a fully covered dense hydroxyapatite coatings was 4 days immersion in SBF.

关键词: hydroxyapatite coating, electro-deposition, modified simulated body fluid, titanium, anodization

ZHAO Xuhui, YANG Lingfang, ZUO Yu, XIONG Jinping. Hydroxyapatite Coatings on Titanium Prepared by Electrodeposition in a Modified Simulated Body Fluid[J]. , 2009, 17(4): 667-671.

赵旭辉, 杨灵芳, 左禹, 熊金平. Hydroxyapatite Coatings on Titanium Prepared by Electrodeposition in a Modified Simulated Body Fluid[J]. CIESC Journal, 2009, 17(4): 667-671.

References

1 Suchank,W.,Yoshimura,M.,“Processing and properties of hydroxyapatite-based biomaterials for use as hard tissue replacement implants”,J.Mater.Res.,13(1),94-117(1998).
2 Porter,A.E.,Hobbs,L.W.,Benzra,R.V.,“The ultrastructure of the plasma-sprayed hydroxyapatite—bone interface predisposing to bone bonding”,Biomaterials,23(3),725-733(2002).
3 Lu,Y.P.,Li,M.S.,Wang,Z.G.,“Plasma-sprayed hydroxyapatite+titania composite bond coat for hydroxyapatite coating on titanium substrate”,Biomaterials,25(18),4393-4403(2004).
4 Ding,S.J.,Ju,C.P.,Chern,L.J.H.,“Characterization of hydroxyapatite and titanium coatings sputtered on Ti-6Al-4V substrate”,J.Biomedicine Mater.Res.,44(3),266-279(1999).
5 Wang,C.K.,Chern,L.J.H.,Ju,C.P.,Ong,H.C.,Chang,R.P.H., “Structural characterization of pulsed laser-deposited hydroxyapatite film on titanium substrate”,Biomaterials,18(20),1331-1338(1997).
6 Hsieh,M.F.,Perng,L.H.,Chin,T.S.,“Hydroxyapatite coating on Ti6Al4V alloy using a sol-gel derived precursor”,Mater.Chem.Phys., 74(3),245-250(2002).
7 Stoch,A.,Jastrzebski,W.,Dlugon,E.,Lejda,W.,“Sol-gel derived hydroxyapatite coatings on titanium and its alloy Ti6Al4V”,J.Mol. Struct.,744-747,633-640(2005).
8 Manso,M.,Jiménez,C.,Morant,C.,Herrero,P.,Martínez-Duart, J.M.,“Electrodeposition of hydroxyapatite coatings in basic conditions”,Biomaterials,21(17),1755-1761(2000).
9 Park,J.H.,Lee,D.Y.,Oh,K.T.,“Bioactivity of calcium phosphate coatings prepared by electrodeposition in a modified simulated body fluid”,Mater.Lett.,60(11/12),2573-2577(2006).
10 Zhang,Y.Y.,Tao,J.,Pang,Y.C.,Wang,L.,Wang,W.,“Electrochemically deposited coatings of hydroxyapatite on titanium”,Rare Metal Mater. Eng.,35(3),459-462(2006).(in Chinese)
11 Wang,Y.Q.,Tao,J.,“Hydroxyapatite coatings deposited electrochemically on titanium substrate”,China Surf.Eng.,19(6),47-50 (2006).(in Chinese)
12 Stoch,A.,Brozek,A.,Kmita,G.,Stoch,J.,Jastrzebski,W., “Electrophoretic coating of hydroxyapatite on titanium implants”,J. Mol.Struct.,596(1-3),191-200(2001).
13 Ban,S.,Maruno,S.,“Morphology and microstructure of electrochemically deposited calcium phosphates in a modified simulated body fluid”,Biomaterials,19(14),1245-1253(1998).
14 Tsuchiya,H.,Macak,J.M.,Gicov,A.,“Characterization of electronic properties of TiO₂ nanotube films”,Corros.Sci.,49(1), 203-210(2007).
15 Zhao,J.L.,Wang,X.H.,Sun,T.,Li,L.T.,“Crystal phase transition and properties of titanium oxide nanotube arrays prepared by anodization”,J.Alloy.Comp.,434-435,792-795(2007).
16 Kaneco,S.,Chen,Y.,Westerhoff,P.,Crittenden,J.,“Fabrication of uniform size titanium oxide nanotubes:Impact of current density and solution conditions”,Scripta Materialia,56(5),373-376(2007).
17 Yang,L.F.,Zuo,Y.,Xiong,J.P.,Zhao,X.H.,“Properties of hydroxyapatite coatings prepared by electrodeposition in a modified simulated body fluid”,Chinese J.Mater.Res.,22(4),444-448 (2008).(in Chinese)
18 Fowler,B.O.,Moreno,E.C.,Brown,W.E.,“Infra-red spectra of hydroxyapatite,octacalcium phosphate and pyrolysed octacalcium phosphate”,Arch Oral Boil,11(5),477-492(1966).
19 Ban,S.,Maruno,S.,“Deposition of calcium phosphate on titanium by electrochemical process in simulated body fluid”,Jpn.J.Appl. Phys.,32(10B),L1577-L1580(1993).
20 Sauer,G.R.,Wuthier,R.E.,“Fourier transform infrared characterization of mineral phases formed during induction of mineralization by collagenase-released matrix vesicles in vitro”,J.Biol.Chem.,263 (27),13718-13724(1988).
21 Kokubo,T.,Kawashita,H.M.,“Novel bioactive materials with different mechanical properties”,Biomaterials,24(13),2161-2175 (2003).

[1]	Airan ZHOU, Ping LU, Jianhui XIA, Dongqin LI, Jie GUO, Ming DU, Lichun DONG. Scarring analysis and numerical simulation of TiCl₄ oxidation reactor in chloride process of titanium dioxide [J]. CIESC Journal, 2023, 74(4): 1499-1508.
[2]	Qingyi LIU, Tong XIAO, Wenjie SUN, Jiahao ZHANG, Changhui LIU. Progress in the research of phase change energy storage enhanced by titanium dioxide nanoparticles [J]. CIESC Journal, 2022, 73(5): 1863-1882.
[3]	Yanhu YAO, Chen YANG, Bing ZHANG, Yonghong WU, Tonghua WANG. Preparation, structure and properties of carbon molecular sieving membranes enabled by hybridization of TiO₂ sol [J]. CIESC Journal, 2021, 72(8): 4418-4424.
[4]	YE Zhiping, ZHOU Danfei, LIU Zifeng, ZHOU Qingqing, WANG Jiade. Electro-oxidation information of p-toluene sulfonic acid on Ti/PbO₂electrode [J]. CIESC Journal, 2021, 72(5): 2810-2816.
[5]	Gang WANG,Xuezhi DUAN,Weikang YUAN,Xinggui ZHOU. Mechanistic insights into catalytic isomerization of propylene oxide over TS-1 [J]. CIESC Journal, 2021, 72(10): 5150-5158.
[6]	Qianqian LI, Siyang TANG, Hairong YUE, Changjun LIU, Kui MA, Shan ZHONG, Bin LIANG. Study on the photocatalytic oxidative dehydrogenation of ethane with CO₂ over Pd-Rh /TiO₂ catalyst [J]. CIESC Journal, 2020, 71(8): 3556-3564.
[7]	Jingyu HU, Rong YAO, Yuhang PAN, Chao ZHU, Shuang SONG, Yi SHEN. Photo-assisted regeneration of titanium dioxide/layered double hydroxide for removal of organic dyes in water [J]. CIESC Journal, 2020, 71(7): 3296-3303.
[8]	Jingran NIU, Huining DENG, Wei ZHANG, Baisong HU, Shaofeng ZHANG. Regulation of support structure by TiO₂ deposition and its effect on performance of GO membranes [J]. CIESC Journal, 2020, 71(6): 2850-2856.
[9]	Yuan SANG, Maoqiao XIANG, Miao SONG, Qingshan ZHU. Preparation of nearly-stoichiometric TiN powder by chemical vapor deposition in fluidized-bed [J]. CIESC Journal, 2020, 71(6): 2743-2751.
[10]	Huang ZHOU, Yu CHANG, Xing FAN, Nannan ZHANG, Changyuan TAO. Study on diffusion-reaction coupled strengthening mechanism based on electrosynthesis of titanium dioxide nanotube array [J]. CIESC Journal, 2020, 71(10): 4663-4673.
[11]	GAO Jiaming, WANG Ming, MA Xiaohua, XU Zhenliang. Effect of sintering temperature on structures and properties of TiO₂/stainless steel hollow fiber composite membrane [J]. CIESC Journal, 2018, 69(11): 4879-4886.
[12]	LU Xiaohua, JIANG Guancong, ZHU Yudan, FENG Xin, LÜ Linghong. Preliminary study on controlling nanoconfined fluid behavior and modelling molecular thermodynamics: progress in development of high-specific surface area TiO₂ [J]. CIESC Journal, 2018, 69(1): 1-8.
[13]	DU Qianqian, GU Jinghua, MO Guang, WEI Yanru, YIN Wenjie, LI Jia. Study on controlled hydrolysis of titanium isopropoxide by small angle X-ray scattering [J]. CIESC Journal, 2017, 68(9): 3607-3615.
[14]	LI Yuhua, LI Qinggang, ZHANG Guiqing, CAO Zuoying, GUAN Wenjuan, ZENG Li. Recycling utilization of scandium from hydrolyzed sulfuric acid of titanium dioxide production [J]. CIESC Journal, 2017, 68(7): 2818-2825.
[15]	XU Yanming, ZHAO Ming, LI Jian, REN Qiang, WANG Chenyi. Visible near-infrared amino phthalocyanine-titanium dioxide photocatalyst: preparation and performance [J]. CIESC Journal, 2016, 67(5): 1915-1921.

Hydroxyapatite Coatings on Titanium Prepared by Electrodeposition in a Modified Simulated Body Fluid

Hydroxyapatite Coatings on Titanium Prepared by Electrodeposition in a Modified Simulated Body Fluid

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments