Effect of Temperature on Volumetric and Viscometric Properties of Homologous Amino Acids in Aqueous Solutions of Metformin Hydrochloride

Abstract

Abstract: Density(ρ)and viscosity(η)are measured for glycine,DL-α-alanine DL-α-valine,and DL-α-leucine in 0.05,0.10,0.15 and 0.20 mol·L^-1 aqueous metformin hydrochloride at 308.15,313.15 and 318.15 K.The measured values are used to estimate some important parameters,such as partial molal volume V_φ,standard partial molal volume V_φ⁰,transfer volume ΔV_φ⁰,hydration number n_H,the second derivative of infinite dilution of partial molal volume with respect to temperature,viz.,∂²V_φ⁰/∂T²,viscosity B-coefficient,variation of B with temperature,viz., dB/dT,free energy of activation per mole of solvent Δμ₁⁰ and solute Δμ₂⁰ of the amino acids.These parameters are interpreted in terms of solute-solute and solute-solvent interactions and structure making/breaking ability of solutes in the given solution.In addition,V_φ⁰, ΔV_φ⁰,viscosity B-coefficient,ΔB and Δμ₂⁰ are split into group contributions(NH₃⁺COO^-)and —CH₂ of the amino acids using their linear correlation and their behavior is discussed.

Key words: standard partial molal volume, transfer volume, hydration number, viscosity B-coefficient, activation energy, metformin hydrochloride

摘要： Density(ρ)and viscosity(η)are measured for glycine,DL-α-alanine DL-α-valine,and DL-α-leucine in 0.05,0.10,0.15 and 0.20 mol·L^-1 aqueous metformin hydrochloride at 308.15,313.15 and 318.15 K.The measured values are used to estimate some important parameters,such as partial molal volume V_φ,standard partial molal volume V_φ⁰,transfer volume ΔV_φ⁰,hydration number n_H,the second derivative of infinite dilution of partial molal volume with respect to temperature,viz.,∂²V_φ⁰/∂T²,viscosity B-coefficient,variation of B with temperature,viz., dB/dT,free energy of activation per mole of solvent Δμ₁⁰ and solute Δμ₂⁰ of the amino acids.These parameters are interpreted in terms of solute-solute and solute-solvent interactions and structure making/breaking ability of solutes in the given solution.In addition,V_φ⁰, ΔV_φ⁰,viscosity B-coefficient,ΔB and Δμ₂⁰ are split into group contributions(NH₃⁺COO^-)and —CH₂ of the amino acids using their linear correlation and their behavior is discussed.

关键词: standard partial molal volume, transfer volume, hydration number, viscosity B-coefficient, activation energy, metformin hydrochloride

K. Rajagopal, S. S. Jayabalakrishnan. Effect of Temperature on Volumetric and Viscometric Properties of Homologous Amino Acids in Aqueous Solutions of Metformin Hydrochloride[J]. , 2010, 18(3): 425-445.

References

1 Jencks, W.P., Catalysis in Chemistry and Enzymology, Daver Publications, New York(1969).
2 Von Hippel, P.H., Schleich, T., Structure and Stability of Biological Macromolecules, Marcel Dekker, New York(1969).
3 Franks, F., “Protein stability:the value of ‘old literature'” Biophys. Chem., 96,117(2002).
4 Zaho, H., “Effect of ions and other compatible solutes on enzyme activity and its implication for bio catalyzing using ionic liquids”, J. Mol. Catal. B:Enzym., 37, 16-25(2005).
5 Wiggins, P.M., “Hydrophobic hydration, hydrophobic forces, and protein folding”, Physica Ser. A, 238, 113-128(1997).
6 Zubay, G.L., Biochemistry, 4th edition, W.M.C. Brown Publications, London(1996).
7 Akhtar, Y., “Volumetric and viscometric behavior of amino acids in aqueous metal electro solutions at 308.15 K”, Fluid Phase Equilib., 258, 125-130,(2007).
8 Bhat, R., Ahluwalia, J.C., “Partial molar heat capacities and volumes of transfer of some amino acids, peptides from water to aqueous sodium chloride solutions at 298.15 K”, J. Phys. Chem., 89, 1099-1105(1985).
9 Yuan, Q., Li, Z.F., Wang, B.H., “Partial molar volume of DL-alanine, DL-serine, DL-theonine, L-histidine, glycine and glycylglycine in water, NACL and DMSO aqueous solution at T=298.15 K”, J. Chem. Thermodyn., 38, 20-33(2006).
10 Lu, J., Hakin, A.W., Hedwig, G.R., “Partial molar volumes and heat capacities of the N-acetyle amide derivatives of the amino acids asparagines, glutamine, tyrosine and lycine mono hydrochloride in aqueous solution at temperatures from T=288.15 K to T=328.15 K”, J. Chem. Thermodyn., 38, 1640-1650(2006).
11 Singh, M., Pandey, M., Yadav, R.K., Varma, H.S., “Thermodynamic studying of molar volume pair and triplet interactions increasing side chain length of α-amino acids in aqueous potassium chloride solutions at different concentrations at 310.15 K”, J. Mol. Liq., 135, 42-45(2007).
12 Yan, Z., Wang, J., Kong, W., Liu, J., “Effect of temperature on volumetric and viscosity properties of some α-amino acids in aqueous calcium chloride solutions”, Fluid Phase Equilib., 215, 143-150(2004).
13 Yan, Z., Wang, J., Zhang, H., Liu, D., “Volumetric properties of some α-amino acids in aqueous guanidine hydrochloride solutions at 5℃, 15℃, 25℃ and 35℃”, J. Solution. Chem., 27, 473-483(1998).
14 Natarajan, M., Wadi, R.K., Gaur, H.C., “Apparent molar volumes and viscosities of some α-and α,ω-amino acids in aqueous ammonium chloride solutions at 298.15 K”, J. Chem. Eng. Data., 35, 87-93(1990).
15 Jensen, W.A., Armstrong, J.M.D., Giorgo, J.D., Hearn, M.T.W., “Stability studies on pig heart mitochondrial malate dehydrogenase:The effect of salts and amino acids”, Biochim. Biophys. Acta, 1296, 23-24(1994).
16 Rajagopal, K., Jayabalakrishnan, S.S., “Viscometric, volumetric and acoustical studies of metformin hydrochloride in both aqueous and non aqueous media at 303.15 K”, J. Pure Appl. Ultrason., 28, 81-86(2006).
17 Hu, L.D., Liu, Y., Tang, X., Zhang, Q., “Preparation and in vitro/in vivo evaluation of sustained release metformin hydrochloride pallets”, Eur. J. Pharm. Sci. BioPharm., 64, 185-192(2006).
18 Corti, G., Lirri, M.S., Maestrelli, F., Manine, N., Mura, P., “Sustained release matrix tablets of metformin hydrochloride in combinations with triacetyle-β-cyclodextrin”, Eur. J. Pharm. Biopharm., 68, 303-309(2008).
19 Kharakoz, D.P., “Partial volumes and compressibilities of extended poly peptide chains in aqueous solutions additivity scheme and implactions of protein unfolding at normal and high pressure”, Bio. Chem., 36, 10276-10285(1997).
20 Sakurai, M., Nakumaura, T., Takenaka, N., “Apparent molar volumes and apparent molar adiabatic compressions of water in some alcohols”, Bull. Chem. Soc. Jpn., 67, 352-356(1994).
21 Kikuchi, M., Sakurai, M, Nitta, N., “Partial molar volumes and insentropic compressibilities of N-acetyl amino acid amides in dilute aqueous solutions at 5℃, 15℃, 25℃, 35℃ and 45℃”, J. Chem. Eng. Data, 41, 1439-1445(1996).
22 Pal, A., Kumar, S., “Volumetric and viscometric studies of glycine in binary aqueous solutions of sucrose at different temperatures”, Indian J. Chem., 44, 469-473(2005).
23 Iqbal, M., Ahmed, T., “Partial molar volumes and expansibility of some amino acids in water at 35℃”, Indian J. Chem., 32, 119-123(1993).
24 Rajagopal, K., Jayabalakrishnan, S.S., “Volumetric and viscometric studies of 4-amino butyric acid in aqueous solutions of salbutamol sulphate at 308.15 K, 313.15 K and 318.15 K”, Chin. J. Chem. Eng., 17(5), 796-804(2009).
25 Yan, Z., Wang, J., Liu, W., Lu, J., “Apparent molar volumes and viscosity coefficients of some α-amino acids in aqueous solutions from 278.15 to 318.15 K”, Thermochim. Acta, 334, 17-27(1999).
26 Ren, X., Hu, X., Lin, R., Zong, H., “Apparent molar volumes of L-glycine, L-alanine and L-serine in water + dimethyl formamide mixtures at 298.15 K”, J. Chem. Eng. Data, 43, 700-702(1998).
27 Wadi, R.K., Ramasami, R., “Partial molar volumes and adiabatic compressibilities of transfer of glycine and DL-alanine from water to aqueous sodium sulphate at 288.15, 298.15 and 308.15 K”, J. Chem. Soc. Faraday Trans., 93, 243-247(1997).
28 Gopal, R, Agarwal, D.K., Kumar, R., “Variation of limiting apparent molal volume with temperature in some amino acids in aqueous solutions”, Indian J. Chem., 11, 1061-1062(1973).
29 Lark, B.S., Patyar, P., Banipal, T.S., Kishore, N., “Densities, partial molar volumes and heat capacities of glycine, L-alanine and L-leucine in aqueous magnesium chloride solutions at different temperature”, J. Chem. Eng. Data, 49, 553-565(2004).
30 Munde, M., Kishore, N., “Volumetric properties of aqueous 2-chloroethanol solutions and volumes of transfer of some amino acids and peptides from water to aqueous 2-chloroethanol solutions”, J. Solution. Chem., 32, 791-802(2003).
31 Kikuchi, M., Nitta, K., “Partial molar volumes and adiabatic compressibilities of amino acids in dilute aqueous solutions at 5, 15, 25, 35 and 45℃”, J. Chem. Eng. Data, 935-942(1995).
32 Lark, B.S., Bala, K., “Apparent molal volumes and apparent molal expansibilities of glycine in aqueous solutions”, Indian J. Chem. A, 22, 192-194(1983).
33 Zhao, C, Ma, P., Xia, S., “Studies on partial molar volumes of some amino acids and their groups in aqueous solutions from 293.15 K to 333.15 K”, Chin. J. Chem. Eng., 12, 521-526(2004).
34 Banipal, T.S., Kapoor, P., “Partial molal volumes and expansibilities of some amino acids in aqueous solutions”, J. Indian. Chem. Soc., 76, 431-467(1999).
35 Hakin, W, Duke, M.M., Marty, J.L., Preuss, K.E., “Some thermodynamic properties of aqueous amino acid systems at 288.15, 298.15 and 328.15 group additivity analysis of standard state volumes and heat capacities”, J. Chem. Soc. Faraday Trans., 90, 2027-2035(1994).
36 Hakin, W., Duke, M.M., Groft, L.L., Marty, J.L., Rushfeldt, M.L., “Calorimetric investigations of aqueous amino acid and dipeptide system from 288.15 to 328.15 K”, Can. J. Chem., 73, 725-734(1995).
37 Belibagli, K., Ayranci, E., “Viscosities and apparent molar volumes of some amino acids in water in 6M guanidine hydrochloride at 25℃”, J. Solution. Chem., 19, 867-882(1990).
38 FriedMan, H., Krishnan, C.V., Water:A Comprehensive Treatise, Plenum Press, New York(1973).
39 Bhat, R., Kishore, N., Ahluwalia, J.C., “Thermodynamic studies of transfer of some amino acids and peptides from water to aqueous glucose and sucrose solutions at 298.15 K”, J. Chem. Faraday Trans. I, 84(8), 2561-2665(1988).
40 Li, Z., Sang, W., Lin, R., “Partial molar volumes of glycine, L-alanine and L-serine in aqueous glucose solutions at T=298.15 K”, J. Chem. Thermodyn., 34, 1761-1768(2002).
41 Banipal, T.S., Kaur, D., Lal, P., Sing, G., Banipal, P.K., “Densities and viscosities of glycine, DL-α-alanine, DL-α-amino-n-butyric acid and L-leucine in aqueous 1,2-propanediol solutions at 298.15 K”, J. Chem. Eng. Data, 47, 1391-1395(2002).
42 Franks, F., Quickenden, M.A., Reig, D.S., Watson, B., “Calorimetric and volumetric studies of dilute aqueous of cycle ether derivatives”, Trans. Faraday. Soc. Trans. I, 66, 582-589(1970).
43 Millero, F.J, Surdo, A.L, Shein, C., “The apparent molar volumes and adiabatic compressibilities of aqueous amino acids at 25℃”, J. Phys. Chem., 82, 784-792(1978).
44 Pal, A., Kumar, S., “Volumetric and ultrasonic studies of some amino acids in binary aqueous solutions of MgCl₂·6H₂O at 298.15 K”, J. Mol. Liq., 121, 148-155(2005).
45 Millero, F.J., Ward, G.K., Lepple, F.K., Hoff, E.V., “Isothermal compressibility of aqueous sodium chloride, magnesium chloride, sodium sulphate and magnesium sulphate solutions from 0 to 45℃ at 1 atm”, J. Phys. Chem., 78, 1636-1643(1974).
46 Zhao, C., Ma, P., Lu, J., “Partial molar volumes and viscosity B-coefficients of arginine in aqueous glucose, sucrose and L-ascorbic acid solutions at T=298.15 K”, J. Chem. Thermodyn., 37, 37-42(2005).
47 Lark, B.S., Patyar, P., Banipal, T.S., “Thermodynamic studies on the interactions of diglycine with MgCl₂ in aqueous medium at different temperatures”, J. Chem. Thermodyn., 38, 1592-1605(2006).
48 McMillan, W.G., Mayer, J.E., “The statistical thermodynamics of multi component system”, J. Chem. Phys., 13, 276-305(1945).
49 Banipal, T.S., Kaur, D., Banipal, P.K., “Effect of magnesium acetate on the volumetric and transport behavior of some amino acids in aqueous solutions at 298.15 K”, J. Chem. Thermodyn., 38, 1214-1226(2006).
50 Hepler, L., “Thermal expansion and structure in water and aqueous solutions”, Can. J. Chem., 47, 4613-4617(1969).
51 Franks, F., Water:A Comprehensive Treatise, Plenum Press, New York(1978).
52 Pal, A., Kumar, S., “Viscometric and volumetric studies of some amino acids in binary aqueous solutions of urea at various temperatures”, J. Mol. Liq., 109, 23-31(2004).
53 Lark, B.S., Patyar, P., Banipal, T.S., Kishore, N., “Densities partial molar volumes and heat capacities of glycine, L-alanine and L-leucine in aqueous magnesium chloride solutions at different temperatures”, J. Chem. Eng. Data, 49, 553-565(2004).
54 Jones, G., Dole, M., “The viscosity of aqueous solutions of strong electrolytes with special reference to barium chloride”, J. Am. Chem. Soc., 51, 2950-2964(1929).
55 Stokes, R.H, Milles, R., International Encyclopedia of Physical Chemistry and Chemical Physics, Pergamon Press, New York(1965).
56 Banipal, T.S, Singh, G., “Thermodynamic study of salvation of some amino acids, diglycine and lysozyme in aqueous and mixed aqueous solutions”, Thermochim. Acta, 412, 63-83(2004).
57 Yan, Z., Wang, J., Lu, J., “Viscosity behavior of some α-amino acids and their groups in water-sodium acetate mixtures”, Biophys. Chem., 99, 199-207(2002).
58 Sandhu, J.S., Kashyap, U., “Viscosities of some amino acids in methanol-water mixtures”, Indian. J. Chem. A., 26, 952-955(1987).
59 Islam, M.N., Wadi, R.K., “Temperature dependence of apparent molar volumes and viscosity coefficients of amino acids in aqueous sodium sulphate solutions from 15 to 35℃”, Phys. Chem. Liq., 41, 533-544(2003).
60 Bhattacharya, M.M., Sengupta, M., “Ion solvent interaction of amino acids the role of the zwitterionic and the ionic forms in the modification of water structure over the temperature range 25℃-45℃”, Bull. Chem. Soc. Jpn., 61, 4107-4112(1988).
61 Kumar, G., Dey, N.C., Saikia, B.K., “Viscosities of glycine and L-α-alanine in D(+) glucose-water mixtures at 25℃ and 35℃”, Z. Phys. Chem.(N.F.), 149, 183-190(1986).
62 Bhattacharya, M.M., Sengupta, M., “Ion solvent interaction of amino acids, α-alanine in aqueous solution in the cationic anionic and zwitterionic forms”, Z. Phys. Chem.(N.F.), 121, 135-139(1980).
63 Jenkins, H.D.B., Marcus, Y., “Viscosity B-coefficients of ions in solutions”, Chem. Rev., 95, 2695-2724(1995).
64 Bai, T.C, Yan, G.B., “Viscosity B-coefficients and activation parameters for viscous flow of a solution of heptanedioic acid in aqueous sucrose solutions”, Carbohydr. Res., 338, 2921-2927(2003).
65 Kaminsky, M., “Densities and apparent molal volumes of some aqueous rare earth solutions at 25℃”, Discuss Faraday. Soc., 24, 171(1957).
66 Sharma, T.S., Ahluwalia, J.C., “Experimental studies on the structure of aqueous solutions by hydrophobic solutes”, Chem. Soc. Rev., 2, 203-232(1973).
67 Feakins, D., Bates, F.M., Waghorne, W.E., Lawrence, K.G., “Relative viscosities and quasi thermodynamics of solutions of tert-butyl alcohol in the methanol water system:a different view of the alkyl water interaction”, J. Chem. Soc. Faraday Trans., 89, 3381-3388(1993).
68 Glasstone, S., Laidler, K., Eyring, H., The Theory of Rate Processes, Mc Graw Hill, New York(1941).
69 Mishra, A.P, Gautam, S.K, “Viscometric and volumetric studies of some transition metal chlorides in glycine water solutions”, Indian. J. Chem. Part-A, 40, 100-104(2001).
70 Yan, Z., Wang, J., Lu, J., “Apparent molar volumes and viscosities of some α-amino acids in aqueous sodium butyrate solutions at 298.15 K”, J. Chem. Eng. Data, 46, 217-222(2001).
71 Wadi, P., Goyal, R.K., “Temperature dependence of apparent molar volumes and viscosity coefficients of amino acids in aqueous potassium thiocynate solutions from 15℃ to 35℃”, J. Solution. Chem., 21, 163-170(1992).
72 Paleez, B., “Thermochemical properties of L-α-amino acids in electrolyte water mixtures”, Fluid Phase Equilib., 167, 253-261(2000).

[1]	Xueyan WEI, Yong QIAN. Experimental study on the low to medium temperature oxidation characteristics and kinetics of micro-size iron powder [J]. CIESC Journal, 2023, 74(6): 2624-2638.
[2]	Jian WANG, Zixuan LEI, Jiayu YAO, Jian LI, Yuhong LIU. Synthesis and curing kinetics of terephthalaldehyde phenolic resin [J]. CIESC Journal, 2022, 73(3): 1403-1415.
[3]	ZHANG Rui, SHAO Qi, ZHANG Huayu, JIN Zelong, ZHANG Xiaoliang. Fabrication of boron-doped hybrid silica membranes for pervaporation desalination [J]. CIESC Journal, 2021, 72(4): 2317-2327.
[4]	LIU Ning, CHU Changhui, WANG Qian, SUN Shipeng. Preparation of nanofiltration membrane for separation of mixed monovalent salts [J]. CIESC Journal, 2021, 72(1): 578-588.
[5]	Yifan ZHOU, Congxue YAO, Jingwen WANG, Wenwen GUO, Lei SONG, Xiaowei MU, Yuan HU. Study on thermal decomposition characteristics and kinetics of soybean [J]. CIESC Journal, 2020, 71(S2): 187-194.
[6]	Liping WEI,Guodong JIANG,Yukuan GU,Haipeng TENG. Evaluation and application of pyrolysis kinetic model of Wucaiwan coal and Tulufan coal [J]. CIESC Journal, 2019, 70(S2): 275-286.
[7]	ZHENG Lifang, WANG Zhaozhong, XIE Yajie, YUE Lina, WANG Li. Kinetic study on thermal decomposition of GFRP under γ irradiation [J]. CIESC Journal, 2018, 69(S1): 161-169.
[8]	SU Jiale, ZHOU Junhu, ZHANG Xing, ZHAO Qingchen, WANG Yefeng, YANG Weijuan. Kinetics of ethanol oxidation over Pt/ZSM-5 catalyst [J]. CIESC Journal, 2018, 69(10): 4269-4275.
[9]	HOU Liangpei, ZHAO Rongxiang, LI Xiuping. Highly efficient catalytic oxidation desulfurization from model oil based on acid deep eutectic solvents tetraethylammonium chloride/trifluoroacetic acid [J]. CIESC Journal, 2017, 68(4): 1614-1621.
[10]	GONG Yue, WANG Xuguang, HE Jie, YAN Shilong, CHENG Yangfan. Influence of aluminum particle size on energy output characteristics and thermal stability of emulsion explosive [J]. CIESC Journal, 2017, 68(4): 1721-1727.
[11]	YANG Shuqing, ZHENG Xianmin, WANG Beifu, DU Yan, WANG Luhui. Analysis of pyrolysis kinetics of neighboring-port oil sludge [J]. CIESC Journal, 2015, 66(S1): 319-325.
[12]	LIU Yang, YANG Yongping. Experimental and model study of carbonation of calcined limestone in presence of steam [J]. CIESC Journal, 2015, 66(3): 1088-1096.
[13]	WANG Zining, ZHOU Jiabei, ZHU Jiahua, WU Hui, CHEN Changguo, LIU Shizhong. Dissolution kinetics of calcium sulfate dihydrate [J]. CIESC Journal, 2015, 66(3): 1001-1006.
[14]	MA Chuan, SUN Lushi, JIN Limei, XIANG Jun, HU Song, SU Sheng. Pyrolysis kinetics modeling of flame retarded HIPS [J]. CIESC Journal, 2014, 65(9): 3479-3484.
[15]	DONG Hongxing, ZHAO Qingchen, ZHANG Jin, CHEN Ye, YUE Guojun, LIU Wenxin, LIU Jinsong, LIU Lijia, ZHANG Chunhong. Curing process and kinetics of CMC/E44/DDM systems [J]. CIESC Journal, 2014, 65(11): 4392-4399.