Preparation and heat and salt resistance of AM/AMPS/SSS terpolymer

doi:10.11949/0438-1157.20221020

Abstract

Abstract:

China's oil fields have entered the stage of tertiary oil recovery. The development of oil displacement agents adapted to high temperature and high salt production environment has attracted extensive attention. In this paper, polyacrylamide, a traditional oil displacement agent, was modified, and acrylamide / 2-acrylamyl-2-methyl-1-propane sulfonic acid / sodium p-styrene sulfonate (AM/AMPS/SSS) terpolymer was prepared and optimized using aqueous solution polymerization. The effects of various reaction conditions on the apparent viscosity of the product aqueous solution were explored, and the optimum preparation conditions of terpolymer were obtained. The apparent viscosity, heat and salt resistance of terpolymer solution were studied by using rotary viscosimeter. Finally, AM/AMPS/SSS terpolymer with obvious heat and salt resistance and good thermal stability was obtained, which has a good application prospect in the current severe crude oil exploitation environment.

Key words: polymers, preparation, viscosity, polyacrylamide, multiple copolymerization, heat and salt resistance

摘要：

我国油田已全面进入三次采油阶段，研制适应高温高盐开采环境下的驱油剂受到广泛关注。针对传统聚丙烯酰胺类驱油剂进行了改性，采用水溶液聚合的方法，制备并优化了丙烯酰胺/2-丙烯酰胺基-2-甲基-1-丙烷磺酸/对苯乙烯磺酸钠（AM/AMPS/SSS）三元共聚物，探究了各种反应条件对产物水溶液表观黏度的影响，总结分析了相关规律，得到最优的共聚物制备条件。使用旋转黏度计，对聚合物溶液的表观黏度、耐温耐盐性能进行了研究，最终得到了耐温、耐盐效果明显，热稳定性良好的AM/AMPS/SSS三元共聚物，在目前严峻的原油开采环境中有较好的应用前景。

关键词: 聚合物, 制备, 黏度, 聚丙烯酰胺, 多元共聚, 耐温耐盐性能

CLC Number:

TQ 316.3

Zhiyuan JIN, Guorong SHAN, Pengju PAN. Preparation and heat and salt resistance of AM/AMPS/SSS terpolymer[J]. CIESC Journal, 2023, 74(2): 916-923.

靳志远, 单国荣, 潘鹏举. AM/AMPS/SSS三元共聚物的制备及耐温耐盐性能[J]. 化工学报, 2023, 74(2): 916-923.

Figures/Tables 10

Table 1 Initial reaction conditions

Initiator concentration	Monomer mass ratio (AM∶AMPS∶SSS)	Monomer concentration	System pH	Polymerization temperature
0.2%(mass)	4∶1∶0.1	20%(mass)	7	40℃

Fig.1 Effect of initiator concentration on apparent viscosity of product aqueous solution

Fig.2 Effect of AMPS ratio on apparent viscosity of product aqueous solution

Fig.3 Effect of SSS addition on apparent viscosity of product aqueous solution

Fig.4 Effect of monomer concentration on apparent viscosity of product aqueous solution

Fig.5 Effect of pH on apparent viscosity of product aqueous solution

Fig.6 Effect of polymerization temperature on apparent viscosity of product aqueous solution

Fig. 7 Relationship between monomer conversion and apparent viscosity

Fig.8 Effect of temperature on apparent viscosity of three polymer aqueous solutions

Fig.9 Effect of salt concentration on apparent viscosity of three polymer solutions

References 27

28	Song H, Zhang S F, Ma X C, et al. Synthesis and application of starch-graft-poly(AM-co-AMPS) by using a complex initiation system of CS-APS[J]. Carbohydrate Polymers, 2007, 69(1): 189-195.
29	丁伟, 刘海燕, 于涛, 等. 离子液体中AM/AMPS/N8AM三元共聚物的合成及溶液性能[J]. 高等学校化学学报, 2008, 29(4): 868-870.
	Ding W, Liu H Y, Yu T, et al. Synthesis of AM/AMPS/N8AM tercopolymer in ionic liquids and performance of the polymer solution[J]. Chemical Journal of Chinese Universities, 2008, 29(4): 868-870.
30	王贵江, 张杰, 欧阳坚, 等. 驱油用耐温抗盐三元共聚物的溶液性能研究[J]. 油田化学, 2009, 26(2): 169-171, 182.
	Wang G J, Zhang J, Ouyang J, et al. Solution properties of terpolymer NKP for EOR with improved temperature resistance and salt tolerance[J]. Oilfield Chemistry, 2009, 26(2): 169-171, 182.
31	Ke Y C, Wei G Y, Wang Y. Preparation, morphology and properties of nanocomposites of polyacrylamide copolymers with monodisperse silica[J]. European Polymer Journal, 2008, 44(8): 2448-2457.
32	Xu J, Wu Y M, Wang C X, et al. Dispersion polymerization of acrylamide with 2-acrylamide-2-methyl-1-propane sulfonate in aqueous solution of sodium sulfate[J]. Journal of Polymer Research, 2009, 16(5): 569-575.
1	张祺. 中国石油进口依存度问题研究[D]. 武汉: 武汉大学, 2013.
	Zhang Q. A study on oil import dependency of China[D]. Wuhan: Wuhan University, 2013.
2	李国欣, 朱如凯. 中国石油非常规油气发展现状、挑战与关注问题[J]. 中国石油勘探, 2020, 25(2): 1-13.
	Li G X, Zhu R K. Progress, challenges and key issues of unconventional oil and gas development of CNPC[J]. China Petroleum Exploration, 2020, 25(2): 1-13.
3	佟福财. 中国石油现状和对建设石油市场争取国际定价权的建议[D]. 上海: 上海交通大学, 2013.
	Tong F C. Oil in China and the construction of the oil market for international pricing power of advice[D]. Shanghai: Shanghai Jiao Tong University, 2013.
4	冯永生, 郭静, 蒋风松, 等. 三次采油技术的研究现状及进展[J]. 内蒙古石油化工, 2016, 42(3): 114-116.
	Feng Y S, Guo J, Jiang F S, et al. Research status and progress of tertiary oil recovery technology[J]. Inner Mongolia Petrochemical Industry, 2016, 42(3): 114-116.
5	Wyatt N B, Gunther C M, Liberatore M W. Increasing viscosity in entangled polyelectrolyte solutions by the addition of salt[J]. Polymer, 2011, 52(11): 2437-2444.
6	Wyatt N B, Liberatore M W. Rheology and viscosity scaling of the polyelectrolyte xanthan gum[J]. Journal of Applied Polymer Science, 2009, 114(6): 4076-4084.
7	Vink H. Rheology of dilute polyelectrolyte solutions[J]. Polymer, 1992, 33(17): 3711-3716.
8	Cohen J, Priel Z, Rabin Y. Viscosity of dilute polyelectrolyte solutions[J]. The Journal of Chemical Physics, 1988, 88(11): 7111-7116.
9	Jan J S, Breedveld V. Microrheological study of polyelectrolyte collapse and reexpansion in the presence of multivalent counterions[J]. Macromolecules, 2008, 41(17): 6517-6522.
10	Candau F, Zekhnini Z, Heatley F, et al. Characterization of poly(acrylamide-co-acrylates) obtained by inverse microemulsion polymerization[J]. Colloid and Polymer Science, 1986, 264(8): 676-682.
11	Zhang Z, Li J C, Zhou J F. Microscopic roles of “viscoelasticity” in HPMA polymer flooding for EOR[J]. Transport in Porous Media, 2011, 86(1): 199-214.
12	周吉生. 部分水解聚丙烯酰胺链结构与驱油机理的研究[D]. 长春: 吉林大学, 2004.
	Zhou J S. The study on the chain structure and oil recovery mechanism of partially hydrolyzed polyacrylamide[D]. Changchun: Jilin University, 2004.
13	闵敬丽. 聚丙烯酰胺类耐温抗盐聚合物的合成及其性能研究[D]. 济南: 山东大学, 2017.
	Min J L. Study on synthesis and properties of temperature resistance and salt tolerance polyacrylamide copolymer[D]. Jinan: Shandong University, 2017.
14	Xue W, Hamley I W, Castelletto V, et al. Synthesis and characterization of hydrophobically modified polyacrylamides and some observations on rheological properties[J]. European Polymer Journal, 2004, 40(1): 47-56.
15	Ghannam M, Esmail N. Flow behavior of enhanced oil recovery Alcoflood polymers[J]. Journal of Applied Polymer Science, 2002, 85(14): 2896-2904.
16	黄宁, 苏雪霞, 史康玲. 水溶性聚合物驱油剂国内研究近况[J]. 精细石油化工, 2001, 18(5): 53-56.
	Huang N, Su X X, Shi K L. The recent situation in studies on hydrotropic polymers for eor at home[J]. Speciality Petrochemicals, 2001, 18(5): 53-56.
17	王玉普, 罗健辉, 卜若颖, 等. 三次采油用抗温抗盐聚合物分析[J]. 化工进展, 2003, 22(3): 271-274.
	Wang Y P, Luo J H, Bu R Y, et al. Analysis on polymers of temperature and salt-resistant for enhanced oil recovery[J]. Chemical Industry and Engineering Progress, 2003, 22(3): 271-274.
18	于志省, 夏燕敏, 李应成. 耐温抗盐丙烯酰胺系聚合物驱油剂最新研究进展[J]. 精细化工, 2012, 29(5): 417-424, 442.
	Yu Z S, Xia Y M, Li Y C. Newest research development of acrylamide based polymer flooding agent with temperature resistance and salt tolerance[J]. Fine Chemicals, 2012, 29(5): 417-424, 442.
19	Wu Y M, Zhang B Q, Wu T, et al. Properties of the forpolymer of N-vinylpyrrolidone with itaconic acid, acrylamide and 2-acrylamido-2-methyl-1-propane sulfonic acid as a fluid-loss reducer for drilling fluid at high temperatures[J]. Colloid and Polymer Science, 2001, 279(9): 836-842.
20	Ye L, Huang R H. Study of p(AM-NVP-DMDA) hydrophobically associating water-soluble terpolymer[J]. Journal of Applied Polymer Science, 1999, 74(1): 211-217.
21	Kujawa P, Rosiak J M, Selb J, et al. Micellar synthesis and properties of hydrophobically associating polyampholytes[J]. Macromolecular Chemistry and Physics, 2001, 202(8): 1384-1397.
22	赵方园, 毛炳权, 伊卓, 等. 丙烯酰胺/2-丙烯酰胺基-2-甲基丙磺酸共聚物合成的逐级放大及其性能的研究[J]. 石油化工, 2013, 42(1): 34-38.
	Zhao F Y, Mao B Q, Yi Z, et al. Stepwise scaling up of acrylamide/2-acrylamide-2-methylpropanesulfonic acid copolymer synthesis and its properties[J]. Petrochemical Technology, 2013, 42(1): 34-38.
23	梁兵, 代华, 黄荣华. AM/DMAM/AMPS共聚物的合成及结构分析[J]. 油田化学, 1997, 14(3): 248-251.
	Liang B, Dai H, Huang R H. A study on preparation and structural analysis of AM/DMAM/AMPS terpolymer[J]. Oilfield Chemistry, 1997, 14(3): 248-251.
24	梁兵, 代华, 黄荣华. AM/DMAM/AMPS共聚物溶液的黏度性能[J]. 油田化学, 1997, 14(4): 357-360.
	Liang B, Dai H, Huang R H. Viscosity properties of aqueous AM/DMAM/AMPS copolymer solutions[J]. Oilfield Chemistry, 1997, 14(4): 357-360.
25	李俊中, 蒲万芬, 杨燕. AM/AMPS/第三单体三元共聚物耐温抗盐驱油体系的合成与性能[J]. 石油天然气学报, 2011, 33(3): 128-131, 169.
	Li J Z, Pu W F, Yang Y. Synthesis and performance of temperature and salt resistance of third monomer flooding system with AM-AMPS[J]. Journal of Oil and Gas Technology, 2011, 33(3): 128-131, 169.
26	任奕, 易飞, 刘观军, 等. AM/AMPS/DMAM三元共聚物的制备及其性能[J]. 油田化学, 2019, 36(2): 314-319.
	Ren Y, Yi F, Liu G J, et al. Preparation and properties of the temperature resistant and salt tolerant AM/AMPS/DMAM copolymer[J]. Oilfield Chemistry, 2019, 36(2): 314-319.
27	Durmaz S, Okay O. Acrylamide/2-acrylamido-2-methylpropane sulfonic acid sodium salt-based hydrogels: synthesis and characterization[J]. Polymer, 2000, 41(10): 3693-3704.

[1]	Shuang LIU, Linzhou ZHANG, Zhiming XU, Suoqi ZHAO. Study on molecular level composition correlation of viscosity of residual oil and its components [J]. CIESC Journal, 2023, 74(8): 3226-3241.
[2]	Jie LIU, Lisheng WU, Jinjin LI, Zhenghong LUO, Yinning ZHOU. Preparation and properties of polyether-based vinylogous urethane reversible crosslinked polymers [J]. CIESC Journal, 2023, 74(7): 3051-3057.
[3]	Wentao WU, Liangyong CHU, Lingjie ZHANG, Weimin TAN, Liming SHEN, Ningzhong BAO. High-efficient preparation of cardanol-based self-healing microcapsules [J]. CIESC Journal, 2023, 74(7): 3103-3115.
[4]	Zhilong WANG, Ye YANG, Zhenzhen ZHAO, Tao TIAN, Tong ZHAO, Yahui CUI. Influence of mixing time and sequence on the dispersion properties of the cathode slurry of lithium-ion battery [J]. CIESC Journal, 2023, 74(7): 3127-3138.
[5]	Feng ZHU, Kailin CHEN, Xiaofeng HUANG, Yinzhu BAO, Wenbin LI, Jiaxin LIU, Weiqiang WU, Wangwei GAO. Performance study of KOH modified carbide slag for removal of carbonyl sulfide [J]. CIESC Journal, 2023, 74(6): 2668-2679.
[6]	Shaoyun CHEN, Dong XU, Long CHEN, Yu ZHANG, Yuanfang ZHANG, Qingliang YOU, Chenglong HU, Jian CHEN. Preparation and adsorption properties of monolayer polyaniline microsphere arrays [J]. CIESC Journal, 2023, 74(5): 2228-2238.
[7]	Bowen LEI, Jianhua WU, Qihang WU. Research on high injection superheat cycle for R290 low pressure ratio heat pump [J]. CIESC Journal, 2023, 74(5): 1875-1883.
[8]	Bimao ZHOU, Shisen XU, Xiaoxiao WANG, Gang LIU, Xiaoyu LI, Yongqiang REN, Houzhang TAN. Effect of burner bias angle on distribution characteristics of gasifier slag layer [J]. CIESC Journal, 2023, 74(5): 1939-1949.
[9]	Yongquan ZHANG, Weiwei XUAN. Mechanism of alkali metal/(FeO+CaO+MgO) influence on the structure and viscosity of silicate ash slag [J]. CIESC Journal, 2023, 74(4): 1764-1771.
[10]	Xuehong WU, Linlin LUAN, Yanan CHEN, Min ZHAO, Cai LYU, Yong LIU. Preparation and thermal properties of degradable flexible phase change films [J]. CIESC Journal, 2023, 74(4): 1818-1826.
[11]	Dong XU, Du TIAN, Long CHEN, Yu ZHANG, Qingliang YOU, Chenglong HU, Shaoyun CHEN, Jian CHEN. Preparation and electrochemical energy storage of polyaniline/manganese dioxide/polypyrrole composite nanospheres [J]. CIESC Journal, 2023, 74(3): 1379-1389.
[12]	Haiqin LIU, Bowen LI, Zhe LING, Liang LIU, Juan YU, Yimin FAN, Qiang YONG. Facile preparation and properties of chemically modified galactomannan films via mild hydroxy-alkyne click reaction [J]. CIESC Journal, 2023, 74(3): 1370-1378.
[13]	Xueting ZHANG, Jijiang HU, Jing ZHAO, Bogeng LI. Preparation of high molecular weight polypropylene glycol in microchannel reactor [J]. CIESC Journal, 2023, 74(3): 1343-1351.
[14]	Yajing ZHAO, Jijiang HU, Suyun JIE, Bo-Geng LI. Modification of unsaturated polyester resin by HTPB: effect of introducing method of the rubber [J]. CIESC Journal, 2023, 74(2): 883-892.
[15]	Min LI, Xueru YAN, Xinlei LIU. Advances in benzimidazole-linked polymer adsorbents and membranes [J]. CIESC Journal, 2023, 74(2): 599-616.