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吕田田(), 原敏, 王江, 高美珍, 杨佳辉, 徐红, 董晋湘, 石琪()
收稿日期:
2024-01-03
修回日期:
2024-03-31
出版日期:
2024-04-26
通讯作者:
石琪
作者简介:
吕田田(1999—),女,硕士研究生,lvtian0609@163.com
基金资助:
Tiantian LYU(), Min YUAN, Jiang WANG, Meizhen GAO, Jiahui YANG, Hong XU, Jinxiang DONG, Qi SHI()
Received:
2024-01-03
Revised:
2024-03-31
Online:
2024-04-26
Contact:
Qi SHI
摘要:
经过生物质酸性催化转化的5-羟甲基糠醛(5-HMF)原液的组成为低浓度水溶液和多组分酸性副产物乙酰丙酸(LA)和甲酸(FA),因此5-HMF分离吸附剂设计需要疏水、耐酸和高选择性。本文以高N的沸石型四氮唑-咪唑骨架材料(ZTIFs)为前体,通过调控碳化和活化条件制备具有耐酸性、疏水性和合适微介孔分布的多孔碳,利用多孔碳和5-HMF的π-π作用可实现含酸水溶液中5-HMF的高效富集分离。以ZTIF-8为前体,通过调控碳化温度和活化碱碳比,制备了三种具有不同N含量和微介孔分布的ZTIF-8基多孔碳;建立了ZTIF-8基多孔碳N含量和微介孔分布与5-HMF吸附分离性能的关系;具有低N和丰富大微孔小介孔(12~30 Å,1 Å=0.1 nm)的NCZTIF-8700C-800A2是从含酸性副产物水溶液中高效富集分离5-HMF的吸附剂。
中图分类号:
吕田田, 原敏, 王江, 高美珍, 杨佳辉, 徐红, 董晋湘, 石琪. ZTIF基疏水微介孔碳的制备及5-羟甲基糠醛吸附分离性能[J]. 化工学报, DOI: 10.11949/0438-1157.20231418.
Tiantian LYU, Min YUAN, Jiang WANG, Meizhen GAO, Jiahui YANG, Hong XU, Jinxiang DONG, Qi SHI. Preparation of ZTIF based hydrophobic micro-mesoporous carbon and their adsorption and separation performance of 5-hydroxymethylfurfural[J]. CIESC Journal, DOI: 10.11949/0438-1157.20231418.
Samples | Bulk N/ (%) Quality score | BET/ (m²·g-1) | Total Pore Volume/ (cm³·g-1) | Cumulative Pore Volume/(cm3·g-1) | ||||
---|---|---|---|---|---|---|---|---|
<12 Å | 12-22 Å | 22-30 Å | 12-30 Å | 30-60 Å | ||||
ZTIF-8 | — | 1570.5 | 0.59 | 0.31 | 0.24 | 0 | 0.24 | 0 |
NCZTIF-8700C | 21.81 | 853.3 | 0.41 | 0.32 | 0 | 0 | 0 | 0 |
NCZTIF-8700C-800A0.5 | 12.33 | 1863.5 | 0.86 | 0.51 | 0.29 | 0 | 0.29 | 0 |
NCZTIF-8700C-800A1 | 6.85 | 3096 | 1.96 | 0.50 | 0.72 | 0.63 | 1.35 | 0 |
NCZTIF-8700C-800A2 | 1.62 | 2701.4 | 2.39 | 0.36 | 0.36 | 0.88 | 1.24 | 0.67 |
NCZTIF-8700C-800A4 | 1.30 | 2643.5 | 2.83 | 0.29 | 0.43 | 0.32 | 0.75 | 1.43 |
表1 ZTIF-8,NCZTIF-8700C和NCZTIF-8700C-800AZ的孔结构和元素分析
Table 1 The pore structures and elemental analysis of ZTIF-8,NCZTIF-8700C and NCZTIF-8700C-800AZ
Samples | Bulk N/ (%) Quality score | BET/ (m²·g-1) | Total Pore Volume/ (cm³·g-1) | Cumulative Pore Volume/(cm3·g-1) | ||||
---|---|---|---|---|---|---|---|---|
<12 Å | 12-22 Å | 22-30 Å | 12-30 Å | 30-60 Å | ||||
ZTIF-8 | — | 1570.5 | 0.59 | 0.31 | 0.24 | 0 | 0.24 | 0 |
NCZTIF-8700C | 21.81 | 853.3 | 0.41 | 0.32 | 0 | 0 | 0 | 0 |
NCZTIF-8700C-800A0.5 | 12.33 | 1863.5 | 0.86 | 0.51 | 0.29 | 0 | 0.29 | 0 |
NCZTIF-8700C-800A1 | 6.85 | 3096 | 1.96 | 0.50 | 0.72 | 0.63 | 1.35 | 0 |
NCZTIF-8700C-800A2 | 1.62 | 2701.4 | 2.39 | 0.36 | 0.36 | 0.88 | 1.24 | 0.67 |
NCZTIF-8700C-800A4 | 1.30 | 2643.5 | 2.83 | 0.29 | 0.43 | 0.32 | 0.75 | 1.43 |
Samples | single-component Qe/(mg·g-1) | ternary-component Qi,e/(mg·g-1) | Si,j | |||||
---|---|---|---|---|---|---|---|---|
5-HMF 5.0% | LA 2.5% | FA 1.0% | 5-HMF 5.0% | LA 2.5% | FA 1.0% | 5-HMF /LA | 5-HMF /FA | |
NCZTIF-8700C-800A1 | 842 | 399.7 | 86.1 | 555.8 | 60.8 | 9.5 | 5.0 | 12.3 |
NCZTIF-8700C-800A2 | 1072.7 | 626.6 | 111.5 | 803.6 | 103.5 | 5.8 | 4.2 | 29.0 |
NCZTIF-8700C-800A4 | 968 | 451.0 | 89.2 | 727.9 | 71.6 | 3.1 | 5.6 | 49.4 |
表2 NCZTIF-8700C-800AZ的静态吸附量和选择性汇总
Table 2 Summary of static adsorption capacity and selectivity of NCZTIF-8700C-800AZ
Samples | single-component Qe/(mg·g-1) | ternary-component Qi,e/(mg·g-1) | Si,j | |||||
---|---|---|---|---|---|---|---|---|
5-HMF 5.0% | LA 2.5% | FA 1.0% | 5-HMF 5.0% | LA 2.5% | FA 1.0% | 5-HMF /LA | 5-HMF /FA | |
NCZTIF-8700C-800A1 | 842 | 399.7 | 86.1 | 555.8 | 60.8 | 9.5 | 5.0 | 12.3 |
NCZTIF-8700C-800A2 | 1072.7 | 626.6 | 111.5 | 803.6 | 103.5 | 5.8 | 4.2 | 29.0 |
NCZTIF-8700C-800A4 | 968 | 451.0 | 89.2 | 727.9 | 71.6 | 3.1 | 5.6 | 49.4 |
Samples | ternary-component Qi,ads/(mg·g-1) | Si,j | |||
---|---|---|---|---|---|
5-HMF 5.0% | LA 2.5% | FA 1.0% | 5-HMF /LA | 5-HMF /FA | |
NCZTIF-8700C-800A1 | 774.3 | 88.6 | 29.7 | 4.4 | 5.2 |
NCZTIF-8700C-800A2 | 1092.3 | 109.5 | 15.5 | 5.2 | 14.3 |
NCZTIF-8700C-800A4 | 1040.3 | 107.1 | 6.8 | 5.1 | 30.4 |
表3 NCZTIF-8700C-800AZ的动态柱吸附量和选择性汇总
Table 3 Summary of dynamic column adsorption capacity and selectivity of NCZTIF-8700C-800AZ
Samples | ternary-component Qi,ads/(mg·g-1) | Si,j | |||
---|---|---|---|---|---|
5-HMF 5.0% | LA 2.5% | FA 1.0% | 5-HMF /LA | 5-HMF /FA | |
NCZTIF-8700C-800A1 | 774.3 | 88.6 | 29.7 | 4.4 | 5.2 |
NCZTIF-8700C-800A2 | 1092.3 | 109.5 | 15.5 | 5.2 | 14.3 |
NCZTIF-8700C-800A4 | 1040.3 | 107.1 | 6.8 | 5.1 | 30.4 |
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