化工学报 ›› 2021, Vol. 72 ›› Issue (1): 292-303.DOI: 10.11949/0438-1157.20201168
收稿日期:
2020-08-17
修回日期:
2020-11-15
出版日期:
2021-01-05
发布日期:
2021-01-05
通讯作者:
程道建
作者简介:
张眉佳(1997—),女,硕士研究生,ZHANG Meijia(),WU Dengfeng,XU Haoxiang,CHENG Daojian()
Received:
2020-08-17
Revised:
2020-11-15
Online:
2021-01-05
Published:
2021-01-05
Contact:
CHENG Daojian
摘要:
开发高活性、高选择性的催化剂是实现氢氧直接合成过氧化氢(DSHP)工业化应用的关键。本文系统性地综述了Pd基DSHP催化剂的设计、制备与开发,从催化作用机理、活性组分优化、形貌与尺寸调控、载体选择、制备方法改进、反应添加剂选择、反应环境调节等角度,着重讨论了目前对Pd基催化剂的活性和选择性的优化策略。最后对DSHP用Pd基催化剂的研究进展进行了总结,并对其未来发展前景进行了展望。
中图分类号:
张眉佳, 吴登峰, 许昊翔, 程道建. 氢氧直接合成过氧化氢用钯基催化剂研究进展[J]. 化工学报, 2021, 72(1): 292-303.
ZHANG Meijia, WU Dengfeng, XU Haoxiang, CHENG Daojian. Research progress of Pd-based catalysts for DSHP from hydrogen and oxygen[J]. CIESC Journal, 2021, 72(1): 292-303.
1 | Li H B, Zheng B, Pan Z Y, et al. Advances in the slurry reactor technology of the anthraquinone process for H2O2 production[J]. Frontiers in Chemical Engineering, 2018, 12(1): 124-131. |
2 | Gudarzi D, Simakova O A, Carucci J R H, et al. Direct synthesis of H2O2 from H2 and O2 over carbon supported Au, Pd and Au-Pd/C bimetallic catalysts[J]. Chemical Engineering Transactions, 2010, 21: 925-930. |
3 | Gu J, Wang S, He Z, et al. Direct synthesis of hydrogen peroxide from hydrogen and oxygen over activated-carbon-supported Pd-Ag alloy catalysts[J]. Catalysis Science & Technology, 2016, 6: 809-817. |
4 | Wilson N M, Pan Y T, Shao Y T, et al. Direct synthesis of H2O2 on AgPt octahedra: the importance of Ag-Pt coordination for high H2O2 selectivity[J]. ACS Catalysis, 2018, 8(4): 2880-2889. |
5 | Xu H X, Cheng D J, Gao Y. Design of high-performance Pd-based alloy nanocatalysts for direct synthesis of H2O2[J]. ACS Catalysis, 2017, 7(3): 2164-2170. |
6 | Choudhary V R, Samanta C, Choudhary T V. Direct oxidation of H2 to H2O2 over Pd-based catalysts: influence of oxidation state, support and metal additives[J]. Applied Catalysis A: General, 2006, 308: 128-133. |
7 | Song X, Sun K, Hao X, et al. Facet-dependent of catalyticselectivity: the case of H2O2 direct synthesis on Pd surfaces[J]. The Journal of Physical Chemistry C, 2019, 123(43): 26324-26337. |
8 | Liu Q S, Gath K K, Bauer J C, et al. The active phase in the direct synthesis of H2O2 from H2 and O2 over Pd/SiO2 catalyst in a H2SO4 ethanol system[J]. Catalysis Letters, 2009, 132: 342. |
9 | Hu B, Deng W, Li R, et al. Carbon-supported palladium catalysts for the direct synthesis of hydrogen peroxide from hydrogen and oxygen[J]. Journal of Catalysis, 2014, 319: 15-26. |
10 | Kanungo S, Haandel L V, Hensen E J M, et al. Direct synthesis of H2O2 in AuPd coated micro channels: an in-situ X-Ray absorption spectroscopic study[J]. Journal of Catalysis, 2019, 370: 200-209. |
12 | Priyadarshini P, Flaherty D W. Form of the catalytically active Pd species during the direct synthesis of hydrogen peroxide[J]. AIChE Journal, 2019, 65(12): e16829. |
13 | Edwards J K, Pritchard J, Piccinini M, et al. The effect of heat treatment on the performance and structure of carbon-supported Au-Pd catalysts for the direct synthesis of hydrogen peroxide[J]. Journal of Catalysis, 2012, 292: 227-238. |
14 | Tian P, Ouyang L, Xu X, et al. The origin of palladium particle size effects in the direct synthesis of H2O2: is smaller better?[J]. Journal of Catalysis, 2017, 349: 30-40. |
15 | Ding D, Xu X, Tian P, et al. Promotional effects of Sb on Pd-based catalysts for the direct synthesis of hydrogen peroxide at ambient pressure[J]. Chinese Journal of Catalysis, 2018, 39(4): 673-681. |
16 | Ouyang L, Da G J, Tian P F, et al. Insight into active sites of Pd-Au/TiO2 catalysts in hydrogen peroxide synthesis directly from H2 and O2[J]. Journal of Catalysis, 2014, 311: 129-136. |
17 | Ledendecker M, Pizzutilo E, Malta G, et al. Isolated Pd sites as selective catalysts for electrochemical and direct hydrogen peroxide synthesis[J]. ACS Catalysis, 2020, 10(10): 5928-5938. |
18 | Edwards J K, Solsona B, Ntainjua N E, et al. Switching off hydrogen peroxide hydrogenation in the direct synthesis process[J]. Science, 2009, 323(5917): 1037-1041. |
19 | Edwards J K, Freakley S J, Carley A F, et al. Strategies for designing supported gold-palladium bimetallic catalysts for the direct synthesis of hydrogen peroxide[J]. Accounts of Chemical Research, 2014, 47(3): 845-854. |
20 | Xu J, Ouyang L, Da G, et al. Pt promotional effects on Pd-Pt alloy catalysts for hydrogen peroxide synthesis directly from hydrogen and oxygen[J]. Journal of Catalysis, 2012, 285(1): 74-82. |
21 | Han G H, Xiao X, Hong J, et al. Tailored palladium-platinum nanoconcave cubes as high performance catalysts for the direct synthesis of hydrogen peroxide[J]. ACS Applied Materials & Interfaces, 2020, 12(5): 6328-6335. |
22 | Edwards J K, Pritchard J, Lu L, et al. The direct synthesis of hydrogen peroxide using platinum-promoted gold-palladium catalysts[J]. Angewandte Chemie, 2014, 126: 2413-2416. |
23 | Gong X, Lewis R J, Zhou S, et al. Enhanced catalyst selectivity in the direct synthesis of H2O2 through Pt incorporation into TiO2 supported AuPd catalysts[J]. Catalysis Science & Technology, 2020, 10: 4635-4644. |
24 | Waldt C T, Ananthaneni S, Rankin R B. Towards quaternary alloy Au-Pd catalysts for direct synthesis of hydrogen peroxide[J]. Materials Today Energy, 2020, 16: 100399. |
25 | Alotaibi F, Al-Mayman S, Alotaibi M, et al. Direct synthesis of hydrogen peroxide using Cs-containing heteropolyacid-supported palladium-copper catalysts[J]. Catalysis Letters, 2019, 149: 998-1006. |
26 | Wang S, Lewis R J, Doronkin D E, et al. The direct synthesis of hydrogen peroxide from H2 and O2 using Pd-Ga and Pd-In catalysts[J]. Catalysis Science & Technology, 2020, 10: 1925-1932. |
27 | Wilson N M, Schröder J, Priyadarshini P, et al. Direct synthesis of H2O2 on PdZn nanoparticles: the impact of electronic modifications and heterogeneity of active sites[J]. Journal of Catalysis, 2018, 368: 261-274. |
28 | Freakley S J, He Q, Harrhy J H, et al. Palladium-tin catalysts for the direct synthesis of H2O2 with high selectivity[J]. Science, 2016, 351(6276): 965-968. |
29 | Feng Y, Shao Q, Huang B, et al. Surface engineering at the interface of core-shell nanoparticles promotes hydrogen peroxide generation[J]. National Science Review, 2018, 5(6): 895-906. |
30 | Li F, Shao Q, Hu M, et al. Hollow Pd-Sn nanocrystals for efficient direct H2O2 synthesis: the critical role of Sn on structure evolution and catalytic performance[J]. ACS Catalysis, 2018, 8(4): 3418-3423. |
31 | Kim S, Lee D W, Lee K Y. Direct synthesis of hydrogen peroxide from hydrogen and oxygen over single-crystal cubic palladium on silica catalysts[J]. Journal of Molecular Catalysis A: Chemical, 2014, 383/384: 64-69. |
11 | Flaherty D W. Direct synthesis of H2O2 from H2 and O2 on Pd catalysts: current understanding, outstanding questions, and research needs[J]. ACS Catalysis, 2018, 8(2): 1520-1527. |
32 | Kim S, Lee D W, Lee K Y. Shape-dependent catalytic activity of palladium nanoparticles for the direct synthesis of hydrogen peroxide from hydrogen and oxygen[J]. Journal of Molecular Catalysis A: Chemical, 2014, 391: 48-54. |
33 | Jeong H E, Kim S, Seo M, et al. Catalytic activity of Pd octahedrons/SiO2 for the direct synthesis of hydrogen peroxide from hydrogen and oxygen[J]. Journal of Molecular Catalysis A: Chemical, 2016, 420: 88-95. |
34 | Tian P, Ouyang L, Xu X, et al. Density functional theory study of direct synthesis of H2O2 from H2 and O2 on Pd(111), Pd(100), and Pd(110) surfaces[J]. Chinese Journal of Catalysis, 2013, 34(5): 1002-1012. |
35 | Liu P, Lin Q, Pan H, et al. Direct synthesis of hydrogen peroxide from hydrogen and oxygen over yolk-shell nanocatalyst Pd@HCS with controlled Pd nanoparticle size[J]. Journal of Catalysis, 2019, 377: 511-523. |
36 | Tian P, Ding D, Sun Y, et al. Theoretical study of size effects on the direct synthesis of hydrogen peroxide over palladium catalysts[J]. Journal of Catalysis, 2019, 369: 95-104. |
37 | Park S, Lee J, Song J H, et al. Direct synthesis of hydrogen peroxide from hydrogen and oxygen over Pd/HZSM-5 catalysts: effect of Brönsted acidity[J]. Journal of Molecular Catalysis A: Chemical, 2012, 363/364: 230-236. |
38 | Lewis R J, Ueura K, Fukuta Y, et al. The direct synthesis of H2O2 using TS-1 supported catalysts[J]. ChemCatChem, 2019, 11(6): 1673-1680. |
39 | Yook S, Kwon H C, Kim Y G, et al. Significant roles of carbon pore and surface structure in AuPd/C catalyst for achieving high chemoselectivity in direct hydrogen peroxide synthesis[J]. ACS Sustainable Chemistry & Engineering, 2017, 5(1): 1208-1216. |
40 | Ntainjua N E, Edwards J K, Carley A F, et al. The role of the support in achieving high selectivity in the direct formation of hydrogen peroxide[J]. Green Chemistry, 2008, 10: 1162-1169. |
41 | Giorgianni G, Abate S, Centi G, et al. Direct synthesis of H2O2 on Pd based catalysts: modelling the particle size effects and the promoting role of polyvinyl alcohol[J]. ChemCatChem, 2019, 11(1): 550-559. |
42 | Deguchi T, Yamano H, Takenouchi S, et al. Enhancement of catalytic activity of Pd-PVP colloid for direct H2O2 synthesis from H2 and O2 in water with addition of 0.5 atom% Pt or Ir[J]. Catalysis Science & Technology, 2018, 8: 1002-1015. |
43 | Santos A, Lewis R J, Malta G, et al. Direct synthesis of hydrogen peroxide over Au-Pd supported nanoparticles under ambient conditions[J]. Industrial & Engineering Chemistry Research, 2019, 58(28): 12623-12631. |
44 | Wang S, Doronkin D E, Hähsler M, et al. Palladium-based bimetallic nanocrystal catalysts for the direct synthesis of hydrogen peroxide[J]. ChemSusChem, 2020, 13(12): 3243-3251. |
45 | Seo M, Lee D W, Han S S, et al. Direct synthesis of hydrogen peroxide from hydrogen and oxygen over mesoporous silica-shell-coated, Pd-nanocrystal-grafted SiO2 nano-beads[J]. ACS Catalysis, 2017, 7(4): 3039-3048. |
46 | Quon S, Jo D Y, Han G H, et al. Role of Pt atoms on Pd(111) surface in the direct synthesis of hydrogen peroxide: nano-catalytic experiments and DFT calculations[J]. Journal of Catalysis, 2018, 368: 237-247. |
47 | Seo M, Kim S, Jeong H E, et al. A yolk-shell structured Pd@void@ZrO2 catalyst for direct synthesis of hydrogen peroxide from hydrogen and oxygen[J]. Journal of Molecular Catalysis A: Chemical, 2016, 413: 1-6. |
48 | Seo M, Kim S, Lee D W, et al. Core-shell structured, nano-Pd-embedded SiO2-Al2O3 catalyst (Pd@SiO2-Al2O3) for direct hydrogen peroxide synthesis from hydrogen and oxygen[J]. Applied Catalysis A: General, 2016, 511: 87-94. |
49 | Ao C, Tian P, Ouyang L, et al. Dispersing Pd nanoparticles on N-doped TiO2: a highly selective catalyst for H2O2 synthesis[J]. Catalysis Science & Technology, 2016, 6: 5060-5068. |
50 | Kim J, Chung Y M, Kang S M, et al. Palladium nanocatalysts immobilized on functionalized resin for the direct synthesis of hydrogen peroxide from hydrogen and oxygen[J]. ACS Catalysis, 2012, 2(6): 1042-1048. |
51 | Park S, Lee S H, Song S H, et al. Direct synthesis of hydrogen peroxide from hydrogen and oxygen over palladium-exchanged insoluble heteropolyacid catalysts[J]. Catalysis Communications, 2009, 10(4): 391-394. |
52 | Park S, Kim T J, Chung Y M, et al. Direct synthesis of hydrogen peroxide from hydrogen and oxygen over insoluble Pd0.15M2.5H0.2PW12O40 (M=K, Rb and Cs) heteropolyacid catalysts[J]. Research on Chemical Intermediates, 2010, 36: 639-646. |
53 | Park S, Choi J H, Kim T J, et al. Direct synthesis of hydrogen peroxide from hydrogen and oxygen over Pd/CsxH3-xPW12O40/MCF (x=1.7, 2.0, 2.2, 2.5, and 2.7) catalysts[J]. Journal of Molecular Catalysis A: Chemical, 2012, 353/354: 37-43. |
54 | Park S, Choi J H, Kim T J, et al. Direct synthesis of H2O2 from H2 and O2 over Pd catalyst supported on Cs2.5H0.5PW12O40-MCF silica[J]. Catalysis Today, 2012, 185(1): 162-167. |
55 | Freakley S J, Lewis R J, Morgan D J, et al. Direct synthesis of hydrogen peroxide using Au-Pd supported and ion-exchanged heteropolyacids precipitated with various metal ions[J]. Catalysis Today, 2015, 248: 10-17. |
56 | Pritchard J C, He Q, Ntainjua E N, et al. The effect of catalyst preparation method on the performance of supported Au-Pd catalysts for the direct synthesis of hydrogen peroxide[J]. Green Chemistry, 2010, 12: 915-921. |
57 | Lyu J, Wei J, Niu L, et al. Highly efficient hydrogen peroxide direct synthesis over a hierarchical TS-1 encapsulated subnano Pd/PdO hybrid[J]. RSC Advances, 2019, 9: 13398-13402. |
58 | 陈志超, 田敏, 潘红艳, 等. Pd-SiO2催化剂制备、结构及其用于氢氧直接合成过氧化氢的反应性能[J]. 硅酸盐通报, 2016, 35(5): 1427-1432, 1437. |
Chen Z C, Tian M, Pan H Y, et al. Preparation and structure of Pd-SiO2 catalysts and its performance for direct synthesis of hydrogen peroxide from hydrogen and oxygen[J]. Bulletin of the Chinese Ceramic Society, 2016, 35(5): 1427-1432, 1437. | |
59 | Lopez-Sanchez J A, Dimitratos N, Miedziak P, et al. Au-Pd supported nanocrystals prepared by a sol immobilisation technique as catalysts for selective chemical synthesis[J]. Physical Chemistry Chemical Physics, 2008, 10: 1921-1930. |
60 | Sterchele S, Biasi P, Centomo P, et al. The effect of the metal precursor-reduction with hydrogen on a library of bimetallic Pd-Au and Pd-Pt catalysts for the direct synthesis of H2O2[J]. Catalysis Today, 2015, 248: 40-47. |
61 | Edwards J K, Parker S F, Pritchard J, et al. Effect of acid pre-treatment on AuPd/SiO2 catalysts for the direct synthesis of hydrogen peroxide[J]. Catalysis Science & Technology, 2013, 3: 812-818. |
62 | Pritchard J, Piccinini M, Tiruvalam R, et al. Effect of heat treatment on Au-Pd catalysts synthesized by sol immobilisation for the direct synthesis of hydrogen peroxide and benzyl alcoholoxidation[J]. Catalysis Science & Technology, 2013, 3: 308-317. |
63 | Herzing A A, Carley A F, Edwards J K, et al. Microstructural development and catalytic performance of Au-Pd nanoparticles on Al2O3 supports: the effect of heat treatment temperature and atmosphere[J]. Chemistry of Materials, 2008, 20(4): 1492-1501. |
64 | Gallina G, García-Serna J, Salmi T O, et al. Bromide and acids: a comprehensive study on their role on the hydrogen peroxide direct synthesis[J]. Industrial & Engineering Chemistry Research, 2017, 56(45): 13367-13378. |
65 | Lewis R J, Edwards J K, Freakley S J, et al. Solid acid additives as recoverable promoters for the direct synthesis of hydrogen peroxide[J]. Industrial & Engineering Chemistry Research, 2017, 56(45): 13287-13293. |
66 | Blanco-Brieva G, Desmedt F, Miquel P, et al. Direct synthesis of hydrogen peroxide without the use of acids or halide promoters in dissolution[J]. Catalysis Science & Technology, 2020, 10: 2333-2336. |
67 | Crole D A, Freakley S J, Edwards J K, et al. Direct synthesis of hydrogen peroxide in water at ambient temperature[J]. Proceedings of the Royal Society A, 2016, 472: 20160156. |
68 | Freakley S J, Piccinini M, Edwards J K, et al. Effect of reaction conditions on the direct synthesis of hydrogen peroxide with a AuPd/TiO2 catalyst in a flow reactor[J]. ACS Catalysis, 2013, 3(4): 487-501. |
69 | Piccinini M, Ntainjua N E, Edwards J K, et al. Effect of the reaction conditions on the performance of Au-Pd/TiO2 catalyst for the direct synthesis of hydrogen peroxide[J]. Physical Chemistry Chemical Physics, 2010, 12: 2488-2492. |
70 | Edwards J K, Thomas A, Carley A F, et al. Au-Pd supported nanocrystals as catalysts for the direct synthesis of hydrogen peroxide from H2 and O2[J]. Green Chemistry, 2008, 10: 388-394. |
71 | Piccinini M, Edwards J K, Moulijn J A, et al. Influence of reaction conditions on the direct synthesis of hydrogen peroxide over AuPd/carbon catalysts[J]. Catalysis Science & Technology, 2012, 2: 1908-1913. |
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