化工学报 ›› 2007, Vol. 58 ›› Issue (10): 2629-2635.

• 能源和环境工程 • 上一篇    下一篇

水蒸气对煤粉再燃还原NO的影响

苟湘;周俊虎;周志军;杨卫娟;刘建忠;岑可法   

  1. 能源清洁利用国家重点实验室(浙江大学)
  • 出版日期:2007-10-05 发布日期:2007-10-05

Effect of water vapor on NO reduction by pulverized coal reburning

GOU Xiang;ZHOU Junhu;ZHOU Zhijun;YANG Weijuan;LIU Jianzhong;CEN Kefa   

  • Online:2007-10-05 Published:2007-10-05

摘要: 在兖州烟煤煤粉再燃还原NO的固定床反应器试验中加入不同量的水蒸汽,研究了水蒸汽对煤粉再燃还原NO的影响。结果表明,水蒸汽的加入加快了煤粉再燃还原NO的速度,但单位质量煤粉的还原效果随水蒸汽量的增加而降低,原因是水蒸汽同时也加速了煤粉的燃尽。水蒸汽加快了CO和CO2生成速度以及O2消耗速度,在挥发分为主的反应阶段促进CO2的生成更明显,而在焦炭为主的反应阶段促进CO的生成更明显,但单位质量煤粉的CO2生成量和O2消耗量均降低、CO生成量增加。煤粉再燃的燃尽时间随水蒸汽量的增加而缩短,比如当水蒸汽量为2%时,燃尽时间缩短了25.9%,当水蒸汽量为4%时,燃尽时间缩短了47.8%。在再燃区加入一定量的水蒸汽,既能改善煤粉对NO的还原效果,又能提高煤粉的燃尽率。工程应用要根据煤质特点、主燃区NO浓度、再燃煤粉比例、再燃区过量空气系数、经济性评价等因素进行试验确定最佳水蒸汽量。

关键词: 热能动力工程, 水蒸气, 再燃, NO, 燃尽

Abstract:

The experiments on NO reduction by the reburning of pulverized Yanzhou bituminous coal were conducted separately with different amounts of water vapor added in a fixedbed reactor,through which the effect of water vapor on NO reduction by pulverized coal reburning was studiedIt is found that NO reduction by pulverized coal reburning was accelerated by adding water vapor,but NO reduction per unit mass of coal decreased with the increase of water vapor since the burnout of pulverized coal was also accelerated at the same timeMoreover,the rates of CO production,CO2 production and O2 consumption were increased separately by water vapor,and CO2 production was promoted more significantly during the reaction stage dominated by volatile matter,but CO production was promoted more significantly during the reaction stage dominated by charHowever,CO2 production and O2 consumption decreased separately and CO production increased when they were counted by per unit mass of pulverized coalThe burnout time of coal reburning could become shorter with increasing water vapor,for example the burnout time was shortened by 25.9% at 2% water vapor,and was shortened by 47.8% at 4% water vaporAdding a certain amount of water vapor into the reburning zone could not only improve NO reduction by pulverized coal reburning but also increase burnout ratioThe optimum amount of water vapor could be obtained through experiments on the basis of coal properties of coal,NO concentration in the main combustion zone,the proportion of reburning coal,the excess air coefficient of the reburning zone,and economic appraisal in engineering practice.

Key words: 热能动力工程, 水蒸气, 再燃, NO, 燃尽