1,3-二元脂肪醇萃取硼酸的平衡特性

doi:10.3969/j.issn.0438-1157.2012.11.024

化工学报 ›› 2012, Vol. 63 ›› Issue (11): 3546-3552.DOI: 10.3969/j.issn.0438-1157.2012.11.024

1,3-二元脂肪醇萃取硼酸的平衡特性

熊妍, 鲍宗必, 邢华斌, 苏宝根, 杨亦文, 任其龙

浙江大学生物质化工教育部重点实验室, 化学工程与生物工程学系, 浙江杭州 310027

收稿日期:2012-03-06 修回日期:2012-06-19 出版日期:2012-11-05 发布日期:2012-11-05
通讯作者: 任其龙
作者简介:熊妍(1988-),女,硕士研究生。
基金资助:
中央高校基本科研业务费专项资金项目(2011FZA4023);国家自然科学基金重点项目(20936005)。

Equilibrium behavior of boric acid extracted by aliphatic 1,3-diols

XIONG Yan, BAO Zongbi, XING Huabin, SU Baogen, YANG Yiwen, REN Qilong

Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, Zhejiang, China

Received:2012-03-06 Revised:2012-06-19 Online:2012-11-05 Published:2012-11-05
Supported by:
supported by the Fundamental Research Funds for the Central Universities(2011FZA4023)and the National Natural Science Foundation of China(20936005).

摘要/Abstract

摘要： 基于1,3-二元脂肪醇的溶剂萃取法在盐湖卤水提硼方面有广阔的应用前景,系统研究了两种1,3-二元脂肪醇萃取剂:2-乙基-1,3-己二醇(EHD)和2-丁基-2-乙基-1,3-丙二醇(BEPD)对硼酸的萃取性能,分别考察了萃取剂浓度、原料液pH、硼酸浓度、氯化镁浓度以及温度等因素对硼酸分配系数的影响。实验结果表明,温度为303.15 K,原料液中硼酸浓度为0.0185 mol·L^-1,EHD和BEPD甲苯溶液中浓度均为0.4 mol·L^-1时,硼酸的分配系数分别达到9.43和8.25。高浓度的萃取剂和较低的原料液pH条件对提高分配系数有利;分配系数随原料中硼酸浓度和反应温度的升高而降低,1,3-二元脂肪醇萃取硼酸的过程为放热过程;氯化镁存在下的盐析效应也有利于硼酸的萃取分配。

关键词: 硼酸, 盐湖卤水, 溶剂萃取, 1,3-二元脂肪醇, 2-乙基-1,3-己二醇, 2-丁基-2-乙基-1,3-丙二醇

Abstract: Solvent extraction based on aliphatic 1,3-diols is a promising technique for the recovery of boric acid from salt lake brine.In this work,two diols,2-ethyl-1,3-hexanediol(EHD)and 2-butyl-2-ethyl-1,3-propanediol(BEPD),were selected as extractants and toluene was used as diluent.The effects of extractant concentration,pH of brine,initial boric acid concentration,magnesium chloride concentration,and temperature on the distribution coefficients of boric acid were systematically investigated.Distribution coefficients of boric acid up to 9.43 and 8.25 were obtained from the boric acid aqueous solutions with the initial concentration of 0.0185 mol稬^-1 when using toluene containing 0.4 mol稬^-1 EHD and BEPD,respectively,as organic phases at 303.15 K.Higher extractant concentration or lower pH is favorable to the extraction.However,the distribution coefficients decrease gradually with the increase of boric acid concentration and temperature.The extraction of boric acid with aliphatic 1,3-diols is an exothermic process.The salting-out effect of magnesium chloride enhances the extraction performance.

Key words: boric acid, salt lake brine, solvent extraction, aliphatic 1,3-diol, 2-ethyl-1,3-hexanediol, 2-butyl-2-ethyl-1,3-propanediol

中图分类号:

熊妍, 鲍宗必, 邢华斌, 苏宝根, 杨亦文, 任其龙. 1,3-二元脂肪醇萃取硼酸的平衡特性[J]. 化工学报, 2012, 63(11): 3546-3552.

XIONG Yan, BAO Zongbi, XING Huabin, SU Baogen, YANG Yiwen, REN Qilong. Equilibrium behavior of boric acid extracted by aliphatic 1,3-diols[J]. CIESC Journal, 2012, 63(11): 3546-3552.

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1,3-二元脂肪醇萃取硼酸的平衡特性

Equilibrium behavior of boric acid extracted by aliphatic 1,3-diols

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