化工学报 ›› 2011, Vol. 62 ›› Issue (4): 1091-1096.

• 能源和环境工程 • 上一篇    下一篇

曝气微电解法预处理难降解含氰农药废水

于璐璐,林海,陈月芳,周立,杨河   

  1. 北京科技大学土木与环境工程学院,北京 100083
  • 出版日期:2011-04-05 发布日期:2011-04-05

  • Online:2011-04-05 Published:2011-04-05

摘要:

微电解法可减轻后续处理负荷,降低废水毒性,为后续处理创造良好的条件。研究了几个主要工艺条件对其预处理高盐含氰农药废水CODCN-的影响。结果表明,其最佳条件pH=4、铁炭质量比FeC=11、曝气量Q=150 L·h-1t=3 h时,COD

关键词: 微电解, 曝气, 农药废水, 铁溶出

Abstract:

The aerated zero-valent iron was used to treat the high salinity pesticide wastewater containing cyanide, which reduced post-processing load and the toxicity of wastewater and created favorable conditions for subsequent treatment.The results indicated, under the conditions that pH was 4, FeC(g/gwas 11, aeration flux was 150 L·h-1, reaction time was 3h, the removal rate of COD was 61.6% and the concentration of effluents CN- was 3.52 mg·L-1.Through the primary dynamics analysis, COD removal process was divided into three phases.First, the acidic dissolution phase of iron, the COD removal by aeration phase, the dissolution velocity of iron was 3.03 g TFe·h-1.Second, the high velocity phase, about 87.1% of COD that being removed in all process was transformed.Third, the stagnation phase of zero-valent iron, the COD removal was stopped.

Key words: 微电解, 曝气, 农药废水, 铁溶出