CIESC Journal ›› 2025, Vol. 76 ›› Issue (1): 374-384.DOI: 10.11949/0438-1157.20240690
• Energy and environmental engineering • Previous Articles Next Articles
Qiwo HAN1(), Yongfeng LIU1(
), Pucheng PEI2, Lu ZHANG1, Shengzhuo YAO1
Received:
2024-06-20
Revised:
2024-09-28
Online:
2025-02-08
Published:
2025-01-25
Contact:
Yongfeng LIU
韩启沃1(), 刘永峰1(
), 裴普成2, 张璐1, 姚圣卓1
通讯作者:
刘永峰
作者简介:
韩启沃(2000—),男,硕士研究生,1545833068@qq.com
基金资助:
CLC Number:
Qiwo HAN, Yongfeng LIU, Pucheng PEI, Lu ZHANG, Shengzhuo YAO. Analysis of influence of operating temperature on water distribution, proton transport and performance of PEMFC[J]. CIESC Journal, 2025, 76(1): 374-384.
韩启沃, 刘永峰, 裴普成, 张璐, 姚圣卓. 工作温度对PEMFC水分布、质子传输及性能影响分析[J]. 化工学报, 2025, 76(1): 374-384.
参数 | 数值 |
---|---|
PEM厚度/m | 5.08 |
PEM密度/(kg/m3) | 1980 |
流道数量 | 5 |
流道深度/m | 6 |
流道宽度/m | 8 |
GDL厚度/m | 0.1439 |
阳极CL厚度/m | 3 |
阴极CL厚度/m | 1 |
阳极参考交换电流密度/(A/m2) | 1 |
阴极参考交换电流密度/(A/m2) | 1 |
阴、阳极传递系数 | 1.0 |
PEM、GDL、CL热传导率/(W/(m | 0.4、1.2、1.5 |
GDL、CL电导率/(S/m) | 2500、2500 |
GDL、CL孔隙率 | 0.5、0.28 |
液态水的动力黏度/(kg/(m | 4.55 |
开路电压/V | 0.95 |
Table 1 The main parameters of the model
参数 | 数值 |
---|---|
PEM厚度/m | 5.08 |
PEM密度/(kg/m3) | 1980 |
流道数量 | 5 |
流道深度/m | 6 |
流道宽度/m | 8 |
GDL厚度/m | 0.1439 |
阳极CL厚度/m | 3 |
阴极CL厚度/m | 1 |
阳极参考交换电流密度/(A/m2) | 1 |
阴极参考交换电流密度/(A/m2) | 1 |
阴、阳极传递系数 | 1.0 |
PEM、GDL、CL热传导率/(W/(m | 0.4、1.2、1.5 |
GDL、CL电导率/(S/m) | 2500、2500 |
GDL、CL孔隙率 | 0.5、0.28 |
液态水的动力黏度/(kg/(m | 4.55 |
开路电压/V | 0.95 |
参数 | 数值 |
---|---|
PEM类型 | Nafion112 |
进气口压力/MPa | 0.1 |
电池活化面积/cm2 | 27.864 |
工作温度/ | 50,60,70 |
阴、阳极进气相对湿度/% | 100 |
氢气进气流量/(L/min) | 2 |
空气进气流量/(L/min) | 5 |
阳极化学计量比 | 1.5 |
阴极化学计量比 | 3 |
Table 2 The main parameters of the experiment
参数 | 数值 |
---|---|
PEM类型 | Nafion112 |
进气口压力/MPa | 0.1 |
电池活化面积/cm2 | 27.864 |
工作温度/ | 50,60,70 |
阴、阳极进气相对湿度/% | 100 |
氢气进气流量/(L/min) | 2 |
空气进气流量/(L/min) | 5 |
阳极化学计量比 | 1.5 |
阴极化学计量比 | 3 |
1 | Tellez-Cruz M M, Escorihuela J, Solorza-Feria O, et al. Proton exchange membrane fuel cells (PEMFCs): advances and challenges [J]. Polymers, 2021, 13(18): 3064. |
2 | Cai F Y, Cai S S, Tu Z K. Proton exchange membrane fuel cell (PEMFC) operation in high current density (HCD): problem, progress and perspective[J]. Energy Conversion and Management, 2024, 307: 118348. |
3 | Piga M. New hybrid inorganic-organic proton conducting membranes for PEMFC: synthesis, properties and conduction mechanisms[J]. 2012. |
4 | Yang T F, Sheu B H, Ghalambaz M, et al. Effects of operating parameters and load mode on dynamic cell performance of proton exchange membrane fuel cell[J]. International Journal of Energy Research, 2021, 45(2): 2474-2487. |
5 | Farcaş A C. A proposed control technique for water management in proton exchange membrane fuel cells [J]. Applied Mechanics and Materials, 2013, 436: 145-152. |
6 | He L G, Yang Y Y, Zhang Y, et al. A review of thermal management of proton exchange membrane fuel cell systems[J]. Journal of Renewable and Sustainable Energy, 2023, 15(1): 012703. |
7 | Gadhewal R, Vinod Ananthula V, Suresh Patnaikuni V. CFD simulation of hot spot in PEM fuel cell with diverging and converging flow channels[J]. Materials Today: Proceedings, 2023, 72: 410-416. |
8 | Gadhewal R, Thamida S K, Ananthula V V, et al. Hot spot identification in PEM fuel cell and its purging strategies[J]. Chemical Papers, 2022, 76(2): 1199-1211. |
9 | Zhao J J, Huang X M, Chang H W, et al. Effects of operating temperature on the carbon corrosion in a proton exchange membrane fuel cell under high current density[J]. Energy Conversion and Management: X, 2021, 10: 100087. |
10 | Xing L, Liu X T, Alaje T, et al. A two-phase flow and non-isothermal agglomerate model for a proton exchange membrane (PEM) fuel cell[J]. Energy, 2014, 73: 618-634. |
11 | Yan W M, Wang X D, Mei S S, et al. Effects of operating temperatures on performance and pressure drops for a 256 cm2 proton exchange membrane fuel cell: an experimental study[J]. Journal of Power Sources, 2008, 185(2): 1040-1048. |
12 | 曹涛锋, 林鸿, 陶文铨. 质子交换膜燃料电池温度和电流分布同步测定[J]. 化工学报, 2011, 62(S1): 174-178. |
Cao T F, Lin H, Tao W Q. Synchronous measurement of temperature and current density distribution of PEMFC[J]. CIESC Journal, 2011, 62(S1): 174-178. | |
13 | Benmouiza K, Cheknane A. Analysis of proton exchange membrane fuel cells voltage drops for different operating parameters[J]. International Journal of Hydrogen Energy, 2018, 43(6): 3512-3519. |
14 | 陈维荣, 牛茁, 韩喆, 等. 水冷PEMFC热管理系统流量跟随控制策略[J]. 化工学报, 2017, 68(4): 1490-1498. |
Chen W R, Niu Z, Han Z, et al. Flow following control strategy for thermal management of water-cooled PEMFC[J]. CIESC Journal, 2017, 68(4): 1490-1498. | |
15 | Mondal R. Fundamental insights into structure-performance relationship for proton conductivity enhancement through polymer electrolyte membrane in proton exchange membrane fuel cell[J]. Chemical Engineering and Processing-Process Intensification, 2023, 194: 109589. |
16 | Belkhiri Z, Zeroual M, Ben Moussa H, et al. Effect of temperature and water content on the performance of PEM fuel cell[J]. Journal of Renewable Energies, 2023, 14(1): 121-130. |
17 | Kim J, Lee S M, Srinivasan S, et al. Modeling of proton exchange membrane fuel cell performance with an empirical equation[J]. Journal of the Electrochemical Society, 1995, 142(8): 2670-2674. |
18 | Springer T E, Zawodzinski T A, Gottesfeld S. Polymer electrolyte fuel cell model[J]. Journal of the Electrochemical Society, 1991, 138(8): 2334-2342. |
19 | Shen J, Tu Z K, Chan S H. Evaluation criterion of different flow field patterns in a proton exchange membrane fuel cell[J]. Energy Conversion and Management, 2020, 213: 112841. |
20 | Aisyah Sarjuni C T, Lim B H, Majlan E H, et al. Analysis of fluid flow behaviour in different proton exchange membrane fuel cell flow field configurations[J]. Asia-Pacific Journal of Chemical Engineering, 2023, 18(6): 2939. |
21 | Arun Saco S, Thundil Karuppa Raj R, Karthikeyan P. A study on scaled up proton exchange membrane fuel cell with various flow channels for optimizing power output by effective water management using numerical technique[J]. Energy, 2016, 113: 558-573. |
22 | Chakraborty S, Elangovan D, Palaniswamy K, et al. A review on the numerical studies on the performance of proton exchange membrane fuel cell (PEMFC) flow channel designs for automotive applications[J]. Energies, 2022, 15(24): 9520. |
23 | Li H F, Wu Z F. Effects of operating temperature on proton exchange membrane fuel cell performance[C]//2022 8th annual international conference on network and information systems for computers (ICNISC). Hangzhou, China. IEEE, 2022:554-557. |
24 | Vijay Babu A R, Manoj Kumar P, Srinivasa Rao G. Parametric study of the proton exchange membrane fuel cell for investigation of enhanced performance used in fuel cell vehicles[J]. Alexandria Engineering Journal, 2018, 57(4): 3953-3958. |
25 | Barbir Frano. PEM Fuel Cells: Theory and Practice[M]. 2nd ed. America:Academic Press, 2012: 35-37. |
26 | 焦魁, 王博文, 杜青, 等. 质子交换膜燃料电池水热管理[M]. 北京: 科学出版社, 2020: 33-40. |
Jiao K, Wang B W, Du Q, et al. Hydrothermal Management of Proton Exchange Membrane Fuel Cell[M]. Beijing: Science Press, 2020: 33-40. | |
27 | Liu L Y, Liu T L, Ding F, et al. Exploration of the polarization curve for proton-exchange membrane fuel cells[J]. ACS Applied Materials & Interfaces, 2021, 13(49): 58838-58847. |
28 | Xu Y M, Chang G F, Zhang J N, et al. Investigation of inlet gas relative humidity on performance characteristics of PEMFC operating at elevated temperature[J]. World Electric Vehicle Journal, 2021, 12(3): 110. |
29 | Wang Z J, Zhan Z G, Tan J T, et al. Water transport law of fuel cell membranes at different current densities[J]. Chinese Science Bulletin, 2019, 64(21): 2254-2261. |
30 | Sui P C, Djilali N. Analysis of water transport in proton exchange membranes using a phenomenological model[J]. Journal of Fuel Cell Science and Technology, 2005, 2(3):149-155. |
31 | Zhang G B, Fan L H, Sun J, et al. A 3D model of PEMFC considering detailed multiphase flow and anisotropic transport properties[J]. International Journal of Heat and Mass Transfer, 2017, 115: 714-724. |
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