›› 2015, Vol. 66 ›› Issue (S1): 370-374.DOI: 10.11949/j.issn.0438-1157.20141134

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Preparation and performance of lauric acid-expanded graphite composite phase change materials

HUANG Xue1, CUI Yingde2, YIN Guoqiang1, FENG Guangzhu1, WU Zimin1   

  1. 1 College of Chemistry and Chemical Engineering, Zhongkai University of Agriculture and Engineering, Guangzhou 510550, Guangdong, China;
    2 Guangzhou Vocational College of Science and Technology, Guangzhou 510225, Guangdong, China
  • Received:2014-07-29 Revised:2015-01-11 Online:2015-06-30 Published:2015-06-30
  • Supported by:
    supported by the National Natural Science Foundation of China(31371880, 31401526).

月桂酸-膨胀石墨复合相变材料的制备及性能

黄雪1, 崔英德2, 尹国强1, 冯光炷1, 吴梓敏1   

  1. 1 仲恺农业工程学院化学化工学院, 广东 广州 510225;
    2 广州科技职业技术学院, 广东 广州 510550
  • 通讯作者: 冯光炷
  • 基金资助:
    国家自然科学基金项目(31371880, 31401526)。

Abstract: The lauric acid-expanded graphite (LA/EG) composite phase change materials was prepared by using adsorption properties of porous graphite with lauric acid as phase change material, porous expanded graphite(EG) as the skeleton carrier; and through the experiment of the basic properties of shape stabilized phase change material, surface morphology, durability were studied. The results showed that lauric acid was effectively encapsulated within the pores of the expanded graphite; phase change temperature and latent heat of LA/EG was 45.45℃and 125.30 J·g-1 respectively when mLA:mEG=95:5. LA/EG loss rate was very small after 100 times of hot and cold cycle phase transitions, which indicated that LA/EG has good stability in practice.

Key words: lauric acid, expanded graphite, stability, durability

摘要: 以月桂酸为相变材料, 多孔石墨为骨架基体, 利用多孔石墨的物理吸附特性, 制备月桂酸-膨胀石墨定形复合相变材料。并通过实验对定形复合相变材料的基本性能、表面形貌及耐久性进行了研究。结果表明, 月桂酸被有效地包封在膨胀石墨的孔隙内;m月桂酸:m膨胀石墨=95:5时定形复合相变材料的相变温度45.45℃, 相变潜热125.30 J·g-1;经100次冷热相变循环后, 复合相变材料损失量非常少, 表明月桂酸-膨胀石墨复合相变材料在实践中有良好的稳定性。

关键词: 月桂酸, 膨胀石墨, 稳定性, 耐久性

CLC Number: