Phase equilibrium in quinary system KCl-KBr-K2SO4-K2B4O7-H2O at 323 K and 348 K

doi:10.3969/j.issn.0438-1157.2013.03.007

CIESC Journal ›› 2013, Vol. 64 ›› Issue (3): 827-833.DOI: 10.3969/j.issn.0438-1157.2013.03.007

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Phase equilibrium in quinary system KCl-KBr-K₂SO₄-K₂B₄O₇-H₂O at 323 K and 348 K

CUI Ruizhi¹, SANG Shihua^1,2, LI Ting¹, ZHANG Yonggang¹

1. College of Materials and Chemistry & Chemical Engineering, Chengdu University of Technology, Chengdu 610059, Sichuan, China;
2. Mineral Resources Chemistry Key Laboratory of Sichuan Higher Education Institutions, Chengdu 610059, Sichuan, China

Received:2012-05-03 Revised:2012-07-05 Online:2013-03-05 Published:2013-03-05
Supported by:
supported by the National Natural Science Foundation of China(40973047).

五元体系KCl-KBr-K₂SO₄-K₂B₄O₇-H₂O 323 K和348 K的相平衡

崔瑞芝¹, 桑世华^1,2, 李婷¹, 张勇刚¹

1. 成都理工大学材料与化学化工学院,四川成都610059;
2. 矿产资源化学四川省高校重点实验室,四川成都610059

通讯作者: 桑世华
作者简介:崔瑞芝(1988—),女,硕士研究生。
基金资助:
国家自然科学基金项目(40973047);四川省杰出青年学科带头人培养计划项目(08ZQ026-017)。

Abstract

Abstract: Phase equilibria in the quinary system KCl-KBr-K₂SO₄-K₂B₄O₇-H₂O at 323 K and 348 K were studied by isothermal solution saturation method.The solubilities and densities of the solution in this system were determined experimentally.Using the experimental data,the phase diagrams of the quinary system were obtained(saturated with K₂SO₄).The quinary system is a solid solution.It comprises one univariant curve and two crystallization fields(saturated with K₂SO₄),i.e.,solid solution K(Cl,Br) and K₂B₄O₇·4H₂O,and does not have invariant point.K₂B₄O₇·4H₂O has larger crystallization fields,while solid solution K(Cl,Br) has smaller crystallization fields.It is also found that KBr has the salting-out effect on KCl.The density of the solution increases with the increase of KBr concentration and decreases with the increase of KCl concentration.Compared with the stable phase diagrams at 323 K and 348 K,the crystallization fields of K₂B₄O₇·4H₂O is small at 348 K,whereas the crystallization field of solid solution K(Cl,Br) is large.

Key words: salt-water system, phase equilibrium, potassium salt, solid solution

摘要： 用等温溶解平衡法研究了五元体系KCl-KBr-K₂SO₄-K₂B₄O₇-H₂O在323 K和348 K时的相平衡关系,测定了该五元体系在相应温度条件下平衡溶液的溶解度和密度,根据相平衡实验数据绘制相应的相图(K₂SO₄饱和)。研究结果表明:该五元体系在323 K和348 K条件下均属于固溶体型,相图中均有2个平衡固相结晶区,其平衡固相分别为固溶体K(Cl,Br)和K₂B₄O₇·4H₂O,1条单变量曲线。该五元体系323 K和348 K的相图相比,348 K时K₂ B₄O₇·4H₂O结晶区变小,而固溶体K(Cl,Br)结晶区变大。

关键词: 水盐体系, 相平衡, 钾盐, 固溶体

CLC Number:

O642

CUI Ruizhi, SANG Shihua, LI Ting, ZHANG Yonggang. Phase equilibrium in quinary system KCl-KBr-K₂SO₄-K₂B₄O₇-H₂O at 323 K and 348 K[J]. CIESC Journal, 2013, 64(3): 827-833.

崔瑞芝, 桑世华, 李婷, 张勇刚. 五元体系KCl-KBr-K₂SO₄-K₂B₄O₇-H₂O 323 K和348 K的相平衡[J]. 化工学报, 2013, 64(3): 827-833.

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Phase equilibrium in quinary system KCl-KBr-K₂SO₄-K₂B₄O₇-H₂O at 323 K and 348 K

五元体系KCl-KBr-K₂SO₄-K₂B₄O₇-H₂O 323 K和348 K的相平衡

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