CIESC Journal ›› 2021, Vol. 72 ›› Issue (10): 5028-5039.DOI: 10.11949/0438-1157.20210607

• Thermodynamics • Previous Articles     Next Articles

Phase equilibria determination and solubility calculation of the quaternary system CaCl2-SrCl2-BaCl2-H2O at 338.15 K

Daqun CAO1(),Yan JIN2,Hang CHEN1,Jianguo YU1()   

  1. 1.Engineering Research Center of Resource Process Engineering, Ministry of Education, East China University of Science and Technology, Shanghai 200237, China
    2.Suzhou Juzhi Tongchuang Environmental Technology Co. Ltd. , Changshu 215513, Jiangsu, China
  • Received:2021-04-29 Revised:2021-06-11 Online:2021-10-05 Published:2021-10-05
  • Contact: Jianguo YU

338.15 K时四元体系CaCl2-SrCl2-BaCl2-H2O相平衡测定及溶解度计算

曹大群1(),金艳2,陈杭1,于建国1()   

  1. 1.华东理工大学资源过程工程教育部工程研究中心,上海 200237
    2.苏州聚智同创环保科技有限公司,江苏 常熟 215513
  • 通讯作者: 于建国
  • 作者简介:曹大群(1995—),男,硕士研究生,caodq2021@foxmail.com
  • 基金资助:
    国家自然科学基金重点项目(U20A20142)

Abstract:

The stable phase equilibria of ternary system CaCl2-SrCl2-H2O, CaCl2-BaCl2-H2O and SrCl2-BaCl2-H2O at 338.15 K were studied by isothermal dissolution equilibrium method, and then the quaternary system CaCl2-SrCl2-BaCl2-H2O was studied. According to the experimental data, the phase diagram and density composition diagram of ternary system, the space diagram, phase diagram, water diagram and density composition diagram of quaternary system were drawn respectively. The results show that there is no double salt or solid solution in the quaternary system CaCl2-SrCl2-BaCl2-H2O. The stable phase diagram of the quaternary system consists of one invariant saturation point, three univariate solubility curves and three salt crystallization regions at 338.15 K, corresponding to the crystallization regions of BaCl2·2H2O, SrCl2·mH2O(m=2,6) and CaCl2·2H2O respectively. The solubility of the ternary system CaCl2-SrCl2-H2O, CaCl2-BaCl2-H2O and SrCl2-BaCl2-H2O at 338.15 K were calculated by DFT model. The calculated results are basically consistent with the experimental data. The study of stable phase equilibria of quaternary and ternary systems of CaCl2-SrCl2-BaCl2-H2O can provide data basis for comprehensive development and utilization of calcium-strontium-barium resources in oilfield brine.

Key words: water salt system, phase equilibrium, solubility, thermodynamic properties, DFT model

摘要:

采用等温溶解平衡法研究338.15 K时三元体系CaCl2-SrCl2-H2O、CaCl2-BaCl2-H2O和SrCl2-BaCl2-H2O的稳定相平衡,进一步研究四元体系CaCl2-SrCl2-BaCl2-H2O的相平衡。根据实验数据,分别绘制了三元体系的相图和密度-组成图,四元体系空间立体图、相图、水图和密度-组成图。研究结果表明:CaCl2-SrCl2-BaCl2-H2O四元体系在338.15 K时没有复盐和固溶体生成,稳定平衡相图由1个共饱点、3条单变量溶解度曲线,3个结晶区组成,分别对应BaCl2·2H2O结晶区、SrCl2·mH2O(m=2,6)结晶区和CaCl2·2H2O结晶区。采用DFT模型进行338.15 K三元体系CaCl2-SrCl2-H2O、CaCl2-BaCl2-H2O和SrCl2-BaCl2-H2O的溶解度计算,计算结果与实验结果基本吻合。针对CaCl2-SrCl2-BaCl2-H2O四元体系及三元子体系的稳定相平衡研究,可为综合开发利用油田卤水中的钙-锶-钡资源提供数据基础。

关键词: 水盐体系, 相平衡, 溶解性, 热力学性质, DFT模型

CLC Number: