Technology of recovery effective components in wastewater from glyphosate production by dynamic adsorption method

doi:10.3969/j.issn.0438-1157.2013.04.045

CIESC Journal ›› 2013, Vol. 64 ›› Issue (4): 1453-1458.DOI: 10.3969/j.issn.0438-1157.2013.04.045

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Technology of recovery effective components in wastewater from glyphosate production by dynamic adsorption method

ZHOU Cairong¹, GAO Yuguo², LI Guopeng¹

1. School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, Henan, China;
2. School of Mechanical Engineering, North China University of Water Resources and Electric Power, Zhengzhou 450011, Henan, China

Received:2012-09-06 Revised:2012-11-07 Online:2013-04-05 Published:2013-04-05
Supported by:
supported by the Scientific Research Foundation of Zhengzhou Science and Technology Bureau, Henan Province, China(0910SGYG23256-6).

动态吸附法从草甘膦生产废水中回收有效成分的工艺

周彩荣¹, 高玉国², 李国鹏¹

1. 郑州大学化工与能源学院,河南郑州 450001;
2. 华北水利水电学院机械学院,河南郑州 450011

通讯作者: 周彩荣
作者简介:周彩荣(1958—),女,博士,教授。
基金资助:
河南省郑州科技局科技攻关基金项目(0910SGYG23256-6)。

Abstract

Abstract: Using alkalescent functional fiber FFA-1 and resin D301 as adsorbent, some effective components in wastewater from glyphosate production such as glyphosate and glycine were recovered by process of dynamic adsorption-desorption.The dynamic adsorption conditions were optimized.4 g alkalescent fiber FFA-1, 6 g D301-C and 4 g activated carbon were packed and filled in a column,and FFA-1 column was at the bottom and D301-C column was at the top.Height/diameter ratio of both columns was 6.25.The wastewater of 200 g was pumped continuously into FFA-1 column and temperature was controlled at the range of 30℃ to 35℃.The wastewater flow rate was 1.6 ml·min^-1 for FFA-1 column and 1.3 ml·min^-1 for D301-C column respectively.The recovery efficiencies of glyphosate and glycine were 95% and 92% respectively, and the color of wastewater was from yellow to colorless.1.0 mol·L^-1 NaOH solution was used as a desorption solvent, and the desorption rates of glyphosate and glycine were 98% and 94%, respectively.The experimental results showed that alkalescent fiber FFA-1 and D301 resin had higher regeneration ability.

Key words: glyphosate, glycine, adsorption, alkalescent fiber FFA-1, D301 resin

关键词: 草甘膦, 甘氨酸, 吸附, 弱碱性纤维FFA-1, D301树脂

CLC Number:

TQ457.2
X786

ZHOU Cairong, GAO Yuguo, LI Guopeng. Technology of recovery effective components in wastewater from glyphosate production by dynamic adsorption method[J]. CIESC Journal, 2013, 64(4): 1453-1458.

周彩荣, 高玉国, 李国鹏. 动态吸附法从草甘膦生产废水中回收有效成分的工艺[J]. 化工学报, 2013, 64(4): 1453-1458.

References 18

[1]	Barrett K A, McBride M B.Phosphate and glyphosate mobility in soil columns amended with roundup[J].Soil Science,2007,172(1):17-26
[2]	Prankl E P, Meggitt W F, Penner D.Adsorption, mobility, and microbial degradation of glyphosate in soil[J].Weed Science,1975,23(3):229 - 234
[3]	Wang Jiaming(汪家铭).Development survey and market prospect of glyphosate[J].Guangdong Chemical Industry(广州化工), 2008, 36(2):18-23
[4]	Zhang Xiaohong(张小宏), Zhang Haibin(张海滨), Fan Xinhua(范新华),et al.Treatment for the glyphosate mother liquid[J].Fine Chemical Intermediates(精细化工中间体), 2010, 40(6):785-789
[5]	Guo Jianmin(郭建敏), Lai Huqin(来虎钦), Ding Chengrong(丁成荣), et al.A new process for synthesis of N-(phosphonomethyl)glycine[J].Journal of Zhejiang University of Technology(浙江工业大学学报), 2009, 37(3):277-279
[6]	John E Franz.Process for producing N-phosphonomethyl glycine[P]:US,3954848.1976-05-04
[7]	Chou S K.Amine oxidation using carbon catalyst having oxides removed from surface[P]:US, 4696772.1987-09-29
[8]	Nakano K, Sayama S, Hirayama Y, et al.Process for producing N-phosphonomethyl glycine[P]:US, 5948938. 1999-09-07
[9]	Xia Ming(夏明), Zhu Hongjun(朱红军), Liu Shan(刘山).The synthesis and development of glyphosate[J].Zhejiang Chemical Industry(浙江化工),2009,40(9):6-10
[10]	Cheng Di(程迪).Study on the technology for treating glyphosate wastewater[J].Agrochemicals Today(今日农药), 2009(4):26-28
[11]	Li Guopeng(李国鹏), Zhou Cairong(周彩荣), Yang Jinjin(杨金金), Shi Xiaohua(石晓华).Analysing the amount of glyphosate and glycine in the wastewater of glyphosate produced by spectrophotometry[J].Journal of Zhengzhou University:Natural Science Edition(郑州大学学报:理学版),2012,44(2):81-84
[12]	Chen Yiliang(陈一良), Pan Bingcai(潘丙才), Zhang Quanxing(张全兴).Treatment of wastewater from benzyl alcohol production with resin adsorption[J].Journal of Chemical Industry and Engineering(China)(化工学报), 2007, 58(5):1220-1224
[13]	Xie Yanxin, Hou Lili, Yang Qian, Jiang Denggao.Adsorptive thermodynamic properties and kinetics of trans-1,2-cyclohexandiol onto AB-8 resin[J].Chinese Journal of Chemical Engineering, 2012, 20(2):277-283
[14]	Lu Xianghong, Xu Zhichao, Ji Jianbing.Effects of pulse ultrasound on adsorption of geniposide on resin 1300 in a fixed bed[J].Chinese Journal of Chemical Engineering, 2011, 19(6):1060-1065
[15]	Chen Feixiong, Zhou Cairong, Li Guopeng.Study on thermal decomposition and the non-isoththermal decomposition kinetics of glyphosate[J].Journal of Thermal Analysis and Calorimetry, 2012,109(3):1457-1462
[16]	Chen Feixiong, Zhou Cairong, Li Guopeng, Peng Feifei. Thermodynamics and kinetics of glyphosate adsorption on resin D301M[J].Arabian Journal of Chemistry,2012,dx.doi.org/10.1016/j. arabjc
[17]	Chen Feixiong(陈飞雄),Li Guopeng(李国鹏),Zhou Cairong(周彩荣), Peng Feifei(彭飞飞).Study on thermodynamics and kinetics of resin D301M adsorbing glyphosate[J].Transactions of Beijing Institute of Technology(北京理工大学学报),2012,32(6):650-654
[18]	Li Guopeng(李国鹏).Study on the recovery and treatment of useful components from glyphosate wastewater[D].Zhengzhou:Zhengzhou University, 2012

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Technology of recovery effective components in wastewater from glyphosate production by dynamic adsorption method

动态吸附法从草甘膦生产废水中回收有效成分的工艺

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