Preparation of ultrathin Cu3(BTC)2 film by heat treatment of layer-by-layer deposition

doi:10.3969/j.issn.0438-1157.2013.11.050

›› 2013, Vol. 64 ›› Issue (11): 4255-4261.DOI: 10.3969/j.issn.0438-1157.2013.11.050

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Preparation of ultrathin Cu₃(BTC)₂ film by heat treatment of layer-by-layer deposition

QIU Longyun, LI Licheng, FENG Xin, FU Shuangqin, ZHANG Suoying, LU Xiaohua, YANG Zhuhong

State Key Laboratory of Materials-Oriented Chemical Engineering, School of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, Jiangsu, China

Received:2013-04-01 Revised:2013-07-27 Online:2013-11-05 Published:2013-11-05
Supported by:
supported by the National Basic Research Program of China(2013CB733503),the National Natural Science Foundation of China(21136001,21136004)and the High-tech Research and Development Program of China(2006AA03Z455).

层层沉积热处理法制备超薄Cu₃(BTC)₂膜

仇龙云, 李力成, 冯新, 付双钦, 张所瀛, 陆小华, 杨祝红

南京工业大学化学化工学院, 材料化学工程国家重点实验室, 江苏南京 210009

通讯作者: 杨祝红
作者简介:仇龙云(1988-),女,硕士研究生。
基金资助:
国家重点基础研究发展计划项目(2013CB733503);国家自然科学基金项目(21136001,21136004);国家高技术研究发展计划项目(2006AA03Z455)。

Abstract

Abstract: Based on layer-by-layer deposition,heat treatment was introduced to prepare continuous and defect-free Cu₃(BTC)₂ film on glass substrate.The effects of some parameters including heat treatment temperature,assembly time and solvent were investigated with field emission scanning electron microscopy(FESEM).The results showed that film thickness was only about 200 nm which was much thinner than those previously reported.Heat treatment was fantastically beneficial for high crystallinity Cu₃(BTC)₂ film formation and no crack was found in the film even at a high heat treatment temperature. At the assembly time about 5 min or 10 min,small crystal particles with uniform size were obtained. However,at a longer assembly time of 20 min,particle size became non-uniform,leading to film unevenness. Moreover,by changing the assembly solvent environment,films with different dimensions were formed.

Key words: metal-organic frameworks, Cu₃(BTC)₂, film, layer-by-layer deposition, heat treatment, surface, polymer

摘要： 基于层层沉积法,引入简单易控的热处理方式在玻璃基底表面制备出高结晶度且致密无裂缝的Cu₃(BTC)₂膜,并详细探讨热处理温度、组装时间和组装溶剂对Cu₃(BTC)₂成膜的影响。FESEM分析结果显示:膜层的厚度仅为200 nm;热处理有利于获得完整的晶体结构,且高温下膜层不会产生裂纹;组装时间为5 min或10 min,Cu₃(BTC)₂ 颗粒尺寸小且均一。然而,当组装时间延长至20 min,尺寸变得不均一,膜层表面变粗糙;通过改变组装溶剂环境,可以制备出不同维数的晶体膜。

关键词: 金属有机骨架材料, Cu₃(BTC)₂, 膜, 层层沉积法, 热处理, 表面, 聚合物

CLC Number:

O647

QIU Longyun, LI Licheng, FENG Xin, FU Shuangqin, ZHANG Suoying, LU Xiaohua, YANG Zhuhong. Preparation of ultrathin Cu₃(BTC)₂ film by heat treatment of layer-by-layer deposition[J]. , 2013, 64(11): 4255-4261.

仇龙云, 李力成, 冯新, 付双钦, 张所瀛, 陆小华, 杨祝红. 层层沉积热处理法制备超薄Cu₃(BTC)₂膜[J]. CIESC Journal, 2013, 64(11): 4255-4261.

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Preparation of ultrathin Cu₃(BTC)₂ film by heat treatment of layer-by-layer deposition

层层沉积热处理法制备超薄Cu₃(BTC)₂膜

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