Properties of biphenyl A epoxy resin modified by choromethyl polyhedral silsesquioxane

doi:10.3969/j.issn.0438-1157.2013.11.052

CIESC Journal ›› 2013, Vol. 64 ›› Issue (11): 4269-4273.DOI: 10.3969/j.issn.0438-1157.2013.11.052

Properties of biphenyl A epoxy resin modified by choromethyl polyhedral silsesquioxane

TAN Jun¹, WANG Huajin², SHA Baoxiang^1,3, WEI Xiaoyan¹, YU Qiang³

1. School of Biological and Chemical Engineering, Jiaxing University, Jiaxing 314001, Zhejiang, China;
2. School of Materials and Textile Engineering, Jiaxing University, Jiaxing 314001, Zhejiang, China;
3. School of Materials Science and Engineering, Changzhou University, Changzhou 213164, Jiangsu, China

Received:2013-05-06 Revised:2013-07-21 Online:2013-11-05 Published:2013-11-05
Supported by:
supported by the Science and Technology Project Foundation of Jiaxing City(2009AY2003,2012AY1025)and the National Natural Science Foundation of China(20906038).

氯甲基笼型倍半硅氧烷改性双酚A环氧树脂性能

谭军¹, 王华金², 沙宝祥^1,3, 韦晓燕¹, 俞强³

1. 嘉兴学院生物与化学工程学院, 浙江嘉兴 314001;
2. 嘉兴学院材料与纺织工程学院, 浙江嘉兴 314001;
3. 常州大学材料科学与工程学院, 江苏常州 213164

通讯作者: 谭军
作者简介:谭军(1979-),男,博士,副教授。
基金资助:
嘉兴市科技计划项目(2009AY2003,2012AY1025);国家自然科学基金项目(20906038)。

Abstract

Abstract: Hybrid epoxy resin composite materials were prepared from choromethyl polyhedral silsesquioxane(CM-POSS),bisphenol epoxy(E-51),MeTHPA and TEA.The curing reaction of hybrid epoxy,and mechanical and thermal properties of the cured epoxy were characterized by Fourier transform infrared spectroscopy(FT-IR),differential scanning calorimetry(DSC),thermogravimetric analysis(TGA)and heat distortion temperature tester.CM-POSS was connected in cross-linked epoxy resin system by chemical reaction in the curing reaction process.Thermal properties,tensile,bending and impact strengthes of the cured hybrid resin were improved with increased content of CM-POSS.Addition of CM-POSS could make the T_g and rigidity of epoxy resin increase but had little effect on tenacity.

Key words: chloromethyl polyhedral silsesquioxane, epoxy resin, curing reaction, thermal properties, mechanical properties

关键词: 氯甲基倍半硅氧烷, 环氧树脂, 固化反应, 热性能, 力学性能

CLC Number:

TAN Jun, WANG Huajin, SHA Baoxiang, WEI Xiaoyan, YU Qiang. Properties of biphenyl A epoxy resin modified by choromethyl polyhedral silsesquioxane[J]. CIESC Journal, 2013, 64(11): 4269-4273.

谭军, 王华金, 沙宝祥, 韦晓燕, 俞强. 氯甲基笼型倍半硅氧烷改性双酚A环氧树脂性能[J]. 化工学报, 2013, 64(11): 4269-4273.

References 18

[1]	Ho T H,Hwang H J,Shieh J Y,et al.Thermal and physical properties of flame-retardant epoxy resins containing 4-napthalenediol and cured with dicyanate ester[J].Polymer Degradation and Stability,2008,93(12):2077-2083
[2]	Sponton M,Mercado L A,Ronda J C,et al.Preparation thermal properties and flame retardancy of phosphorus-and silicon-containing epoxy resins[J].Polymer Degradation and Stability,2008,93(11):2025-2031
[3]	Zhou Hongjun(周红军),Yin Guoqiang(尹国强),Lin Xuan(林轩),et al.Curing kinetics of epoxy/activated nano-Al2O3 composites[J].CIESC Journal(化工学报),2011,62(6):1749-1755
[4]	Huang Huoyang(黄活阳),Ha Chengyong(哈成勇),Li Yinwen(李因文),et al.Preparation of brominated maleic rosin epoxy resin and its fire-retardant property[J].CIESC Journal(化工学报),2009,60(2):514-518
[5]	Deng Lianli(邓莲丽),Shen Minmin(沈敏敏),Yu Jing(于静),et al.Preparation and flame retardancy of siloxane modified epoxy resins based on acrylic acid rosin[J].CIESC Journal(化工学报),2012,63(1):307-313
[6]	Zhang Juan(张娟),Li Qifang(李齐方),Geng Haiping(耿海萍).Synthesis and characterization of bis-phenyl heptasilsesquioxane[J].Journal of Chemical Industry and Engineering(China)(化工学报),2005,56(10):1982-1986
[7]	Ni Guifeng(倪贵峰),Zhao Jun(赵军),Liu Lihua(刘礼华),et al.Epoxy resin modified by inorganic/organic hybrid material with silsesquioxanes cage[J].Paint Industry(涂料工业),2009,39(8):27-30
[8]	Ni Yong,Zheng Sixun,Nie Kangming.Morphology and thermal properties of inorganic-organic hybrids involving epoxy resin and polyhedral oligomeric silsesquioxanes[J].Polymer,2004,45(16):156-164
[9]	David B,Paul D.Recent development in the chemistry of cubic polyhedral oligosilsesquioxanes[J].Chemical Reviews,2010,110(1):2081-2173
[10]	Wu Qiang,Zhang Chuck,Liang Richard,et al. Combustion and thermal properties of epoxy/phenyltrisilanol polyhedral oligomeric silsesquioxane nanocomposites[J].J. Therm. Anal. Calorim.,2010,100:1009-1015
[11]	Su Chung-Hwei,Chiu Yi-Pang,Teng Chih-Chun,et al. Preparation,characterization and thermal properties of organic-inorganic composites involving epoxy and polyhedral oligomeric silsesquioxane(POSS)[J].J. Polym. Res.,2010,17:673-681
[12]	Shree Meenakshi K,Pradeep Jaya Sudhan E,Ananda Kumar S,et al.Development of siloxane based tetraglycidyl epoxy nanocomposites for high performance applications-study of the mechanical,thermal,water absorption and flame retardant behaviour[J].Silicon,2011,3:45-52
[13]	Jiang Chaojie(蒋超杰),Gao Jungang(高俊刚),Zhang XueJian(张学建).Synthesis and characterization of silsesquioxanes cage epoxy resin[J].Thermosetting Resin(热固性树脂),2007,22(1):5-8
[14]	Kong Dejuan(孔德娟).Studies on thermal properties and curing kinetics of epoxy resin modified by epoxy-POSS and NH2-POSS[D].Baoding:Hebei University,2009
[15]	Liu Wenyan(刘文艳),Sun Jianzhong(孙建中),Zhou Qiyun(周其云).Synthesis and characterization of silane modified waterborne epoxy[J].J. Chem. Eng. Chinese Univs.(高校化学工程学报),2007,21(6):1044-1048
[16]	Wang Pin(王品),He Mingyang(何明阳),Zhang Yifeng(张益峰),et al.Synthesis and application of anion exchange resin with organic silicone-containing dendrimers[J].J. Chem. Eng.Chinese Univs.(高校化学工程学报),2007,21(6):1002-1007
[17]	Agaskar P A.New synthetic route to the hydridospherosiloxanes Oh-H8SiO12 and D5h-H10Si10O15[J].Inorganic Chemistry,1991,30(1):2707-2708
[18]	Sha Baoxiang(沙宝祥),Tan Jun(谭军),Yu Qiang(俞强).Synthesis and characterization of octa(chlormethhyl)silsesquioxane[J].New Chemical Materials(化工新型材料),2012,40(8):88-90

Properties of biphenyl A epoxy resin modified by choromethyl polyhedral silsesquioxane

氯甲基笼型倍半硅氧烷改性双酚A环氧树脂性能

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References 18

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Jie LIU, Lisheng WU, Jinjin LI, Zhenghong LUO, Yinning ZHOU. Preparation and properties of polyether-based vinylogous urethane reversible crosslinked polymers [J]. CIESC Journal, 2023, 74(7): 3051-3057.
[2]	Jing ZHAO, Chengwen GU, Xigao JIAN, Zhihuan WENG. Preparation and performance evaluation of magnolol-based epoxy resin anti-corrosion coatings [J]. CIESC Journal, 2023, 74(7): 3010-3017.
[3]	Qin YANG, Chuanjian QIN, Mingzi LI, Wenjing YANG, Weijie ZHAO, Hu LIU. Fabrication and properties of dual shape memory MXene based hydrogels for flexible sensor [J]. CIESC Journal, 2023, 74(6): 2699-2707.
[4]	Shuai WANG, Fukai YANG, Xinyu XU. Preparation and characterization of flame retardant bio-based polyols polyurethane foam [J]. CIESC Journal, 2023, 74(3): 1399-1408.
[5]	Jieyuan ZHENG, Xianwei ZHANG, Jintao WAN, Hong FAN. Synthesis and curing kinetic analysis of eugenol-based siloxane epoxy resin [J]. CIESC Journal, 2023, 74(2): 924-932.
[6]	Yajing ZHAO, Jijiang HU, Suyun JIE, Bo-Geng LI. Modification of unsaturated polyester resin by HTPB: effect of introducing method of the rubber [J]. CIESC Journal, 2023, 74(2): 883-892.
[7]	Shaojie ZHENG, Jianbin WANG, Jijiang HU, Bo-Geng LI, Wenbo YUAN, Zong WANG, Zhen YAO. Regulation of structure and mechanical properties of poly(propylene-butene) alloys by monomer composition switching [J]. CIESC Journal, 2023, 74(2): 904-915.
[8]	Jian WANG, Zixuan LEI, Jiayu YAO, Jian LI, Yuhong LIU. Synthesis and curing kinetics of terephthalaldehyde phenolic resin [J]. CIESC Journal, 2022, 73(3): 1403-1415.
[9]	Zhe WANG, Yuan ZU, Fangyuan HU, Xigao JIAN. Kinetic analysis of curing of epoxy resin containing phthalazinone structure [J]. CIESC Journal, 2022, 73(2): 681-688.
[10]	Lixia WANG, Zhaojie BI, Miaolei SHI, Chen WANG, Dongfang WANG, Qian LI. Effect of blending mode and ratio of UHMWPE/PEG on the entanglement behavior and properties of UHMWPE [J]. CIESC Journal, 2022, 73(2): 933-940.
[11]	Huan XU, Lyu KE, Shenghui ZHANG, Zilin ZHANG, Guangdong HAN, Jinsheng CUI, Daoyuan TANG, Donghui HUANG, Jiefeng GAO, Xinjian HE. Upgrading dispersion and interfacial morphologies for thermally conductive polypropylene composites by in situ growth of carbon nanotubes at graphene oxide [J]. CIESC Journal, 2022, 73(11): 5150-5157.
[12]	HAO Gangwei, LIU Ye, YAN Gang, YU Jianlin. Performance optimization of a frost-free air cooled refrigerator with series-parallel refrigeration cycle [J]. CIESC Journal, 2021, 72(S1): 178-183.
[13]	JI Rongbin, CHEN Ting, PENG Chaohua, XIA Long, CHEN Guorong, LUO Wei'ang, ZENG Birong, XU Yiting, YUAN Conghui, DAI Lizong. Flame retardant epoxy resin composites modified with organophosphorus and boron hybrid molecules [J]. CIESC Journal, 2021, 72(7): 3856-3868.
[14]	CUI Jin,SHI Chuan,ZHAO Jinbao. Research progress on the effect of mechanical pressure on the performance of lithium batteries [J]. CIESC Journal, 2021, 72(7): 3511-3523.
[15]	YU Chengming, PENG Xudong, JIANG Jinbo, MA Yi, WANG Yuming. Investigation on accelerated aging behavior and mechanism of fluoroether rubber under wide temperature range [J]. CIESC Journal, 2021, 72(6): 3399-3410.