CIESC Journal ›› 2023, Vol. 74 ›› Issue (2): 924-932.DOI: 10.11949/0438-1157.20221001
• Material science and engineering, nanotechnology • Previous Articles Next Articles
Jieyuan ZHENG1(), Xianwei ZHANG2, Jintao WAN3(), Hong FAN1()
Received:
2022-08-10
Revised:
2022-09-30
Online:
2023-03-21
Published:
2023-02-05
Contact:
Jintao WAN, Hong FAN
通讯作者:
万金涛,范宏
作者简介:
郑杰元(1995—),男,博士研究生,jieyuanzheng@zju.edu.cn
基金资助:
CLC Number:
Jieyuan ZHENG, Xianwei ZHANG, Jintao WAN, Hong FAN. Synthesis and curing kinetic analysis of eugenol-based siloxane epoxy resin[J]. CIESC Journal, 2023, 74(2): 924-932.
郑杰元, 张先伟, 万金涛, 范宏. 丁香酚环氧有机硅树脂的制备及其固化动力学研究[J]. 化工学报, 2023, 74(2): 924-932.
β/(℃/min) | ΔH/(J/g) | Ti/℃ | Tp/℃ |
---|---|---|---|
3.0 | 240.5 | 135.2 | 162.6 |
4.5 | 241.8 | 139.7 | 175.3 |
6.7 | 244.6 | 145.8 | 186.3 |
10.0 | 246.9 | 151.4 | 198.6 |
Table 1 Characteristic parameters for curing systems
β/(℃/min) | ΔH/(J/g) | Ti/℃ | Tp/℃ |
---|---|---|---|
3.0 | 240.5 | 135.2 | 162.6 |
4.5 | 241.8 | 139.7 | 175.3 |
6.7 | 244.6 | 145.8 | 186.3 |
10.0 | 246.9 | 151.4 | 198.6 |
β/(℃/min) | αp | αM | α |
---|---|---|---|
3.0 | 0.367 | 0.233 | 0.398 |
4.5 | 0.377 | 0.222 | 0.400 |
6.7 | 0.385 | 0.237 | 0.424 |
10.0 | 0.409 | 0.231 | 0.442 |
Table 2 Characteristic peak conversion values αp, αM and αp∞ at various heating rates
β/(℃/min) | αp | αM | α |
---|---|---|---|
3.0 | 0.367 | 0.233 | 0.398 |
4.5 | 0.377 | 0.222 | 0.400 |
6.7 | 0.385 | 0.237 | 0.424 |
10.0 | 0.409 | 0.231 | 0.442 |
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